Solid Halide Electrolytes with High Lithium‐Ion Conductivity for Application in 4 V Class Bulk‐Type All‐Solid‐State Batteries

Tetsuya Asano; Akihiro Sakai; Satoru Ouchi; Masashi Sakaida; Akinobu Miyazaki; Shinya Hasegawa

doi:10.1002/adma.201803075

journal article Sep 14, 2018

Solid Halide Electrolytes with High Lithium‐Ion Conductivity for Application in 4 V Class Bulk‐Type All‐Solid‐State Batteries

Tetsuya Asano

Akihiro Sakai Satoru Ouchi

Masashi Sakaida Akinobu Miyazaki Shinya Hasegawa

Advanced Materials Vol. 30 No. 44 · Wiley

View at Publisher Save 10.1002/adma.201803075

Abstract

AbstractNew lithium halide solid‐electrolyte materials, Li3YCl6 and Li3YBr6, are found to exhibit high lithium‐ion conductivity, high deformability, and high chemical and electrochemical stability, which are required properties for all‐solid‐state battery (ASSB) applications, particularly for large‐scale deployment. The lithium‐ion conductivities of cold‐pressed powders surpass 1 mS cm−1 at room temperature without additional intergrain or grain boundary resistances. Bulk‐type ASSB cells employing these new halide solid electrolyte materials exhibit coulombic efficiencies as high as 94% with an active cathode material of LiCoO2 without any extra coating. These superior electrochemical characteristics, as well as their material stability, indicate that lithium halide salts are another promising candidate for ASSB solid electrolytes in addition to sulfides or oxides.

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Published: Sep 14, 2018
Vol/Issue: 30(44)
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Authors

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Tetsuya Asano