In Situ Generation of Molybdate‐Modulated Nickel‐Iron Oxide Electrodes with High Corrosion Resistance for Efficient Seawater Electrolysis

Li Shao; Xindi Han; Lei Shi; Tongzhou Wang; Yusheng Zhang; Zhiqi Jiang; Zexiang Yin; Xuerong Zheng; Jihong Li; Xiaopeng Han; Yida Deng

doi:10.1002/aenm.202303261

journal article Dec 06, 2023

In Situ Generation of Molybdate‐Modulated Nickel‐Iron Oxide Electrodes with High Corrosion Resistance for Efficient Seawater Electrolysis

Li Shao

Xindi Han Lei Shi

Tongzhou Wang Yusheng Zhang

Zhiqi Jiang Zexiang Yin Xuerong Zheng Jihong Li

Xiaopeng Han

Yida Deng

Advanced Energy Materials Vol. 14 No. 4 · Wiley

View at Publisher Save 10.1002/aenm.202303261

Abstract

AbstractThe realization of seawater electrolysis requires the development of electrode materials that can meet the requirements of high activity, high selectivity, and corrosion resistance. Herein, this work successfully prepares a molybdate (MoO42−)‐modulated nickel‐iron oxide electrode for seawater electrolysis via a quick and easy thermal shock method, with high activity and extraordinary durability in oxygen evolution reaction (OER) for seawater electrolysis. The experimental analyses and theoretical calculations reveal that the in situ generated MoO42− on the surface of electrode can modulate and stabilize the catalytic active phase γ‐(Ni, Fe)OOH, improving the OER activity, as well as play a critical role in protecting electrode from chloride ions (Cl−) corrosion for extended service life. This catalyst thus displays an evidently slow degradation rate of 20 µV h−1 during a long‐term operation (>1500 h) at 100 mA cm−2. This work provides a new viewpoint for the design of oxyanion‐modified catalysts and can be widely used to address the challenges in seawater electrolysis.

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References

63

[1]

Sustainable Hydrogen Production

John A. Turner

Science 10.1126/science.1103197

[2]

10.1038/nmat4410

[3]

10.1039/c9ee00197b

[4]

10.1002/adma.201602270

[5]

10.1002/adfm.201703158

[6]

10.1002/adfm.201704083

[7]

High-performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting

Fang Yu, Haiqing Zhou, Yufeng Huang et al.

Nature Communications 10.1038/s41467-018-04746-z

[8]

10.1038/s41467-018-07790-x

[9]

10.1016/j.apcatb.2022.122145

[10]

Liang X. J. Electrochem. (2022)

[11]

Direct Electrolytic Splitting of Seawater: Opportunities and Challenges

Sören Dresp, Fabio Dionigi, Malte Klingenhof et al.

ACS Energy Letters 10.1021/acsenergylett.9b00220

[12]

10.1016/j.ijhydene.2019.01.120

[13]

10.1021/jacs.8b05382

[14]

10.1002/adma.201707261

[15]

Solar-driven, highly sustained splitting of seawater into hydrogen and oxygen fuels

Yun Kuang, Michael J. Kenney, Yongtao Meng et al.

Proceedings of the National Academy of Sciences 10.1073/pnas.1900556116

[16]

Design Criteria, Operating Conditions, and Nickel–Iron Hydroxide Catalyst Materials for Selective Seawater Electrolysis

Fabio Dionigi, Tobias Reier, Zarina Pawolek et al.

ChemSusChem 10.1002/cssc.201501581

[17]

Electrolysis of low-grade and saline surface water

Wenming Tong, Mark Forster, Fabio Dionigi et al.

Nature Energy 10.1038/s41560-020-0550-8

[18]

10.1002/aenm.202103275

[19]

10.1016/j.esci.2021.09.002

[20]

10.1039/d1nr05209h

[21]

10.1021/acscatal.3c00113

[22]

10.1007/s12274-021-3839-4

[23]

10.1007/s12274-022-4912-3

[24]

10.1021/acs.energyfuels.1c02056

[25]

10.1016/j.trechm.2021.03.003

[26]

Nanostructured Metal Chalcogenides for Energy Storage and Electrocatalysis

Yu Zhang, Qian Zhou, Jixin Zhu et al.

Advanced Functional Materials 10.1002/adfm.201702317

[27]

10.1002/anie.202110355

[28]

10.1016/j.jechem.2022.04.004

[29]

10.1002/ange.202207279

[30]

10.1016/j.cossms.2019.03.002

[31]

10.1016/j.cej.2022.136524

[32]

10.1016/j.energy.2016.06.060

[33]

10.1016/j.corsci.2011.08.049

[34]

10.1038/s41929-020-00525-6

[35]

10.1002/aenm.202202351

[36]

Non-noble metal-nitride based electrocatalysts for high-performance alkaline seawater electrolysis

Luo Yu, Qing Zhu, Shaowei Song et al.

Nature Communications 10.1038/s41467-019-13092-7

[37]

10.1002/ange.201909939

[38]

10.1016/j.electacta.2020.137040

[39]

10.1039/d1ta09245f

[40]

In Situ Observation of Active Oxygen Species in Fe-Containing Ni-Based Oxygen Evolution Catalysts: The Effect of pH on Electrochemical Activity

Bartek J. Trześniewski, Oscar Diaz-Morales, David A. Vermaas et al.

Journal of the American Chemical Society 10.1021/jacs.5b06814

[41]

10.1088/1742-6596/93/1/012039

[42]

Cosynergistic Molybdate Oxo‐Anionic Modification of FeNi‐Based Electrocatalysts for Efficient Oxygen Evolution Reaction

Kamran Dastafkan, Shuhao Wang, Chengli Rong et al.

Advanced Functional Materials 10.1002/adfm.202107342

[43]

10.1016/0020-0891(87)90072-8

[44]

10.1002/smll.201804764

[45]

NiMoFe and NiMoFeP as Complementary Electrocatalysts for Efficient Overall Water Splitting and Their Application in PV‐Electrolysis with STH 12.3%

Minki Baek, Guan‐Woo Kim, Taiho Park et al.

Small 10.1002/smll.201905501

[46]

10.1016/j.apcatb.2022.121150

[47]

10.1016/j.cej.2020.128240

[48]

10.1002/advs.201902034

[49]

Atomic-level insight into super-efficient electrocatalytic oxygen evolution on iron and vanadium co-doped nickel (oxy)hydroxide

Jian Jiang, Fanfei Sun, Si Zhou et al.

Nature Communications 10.1038/s41467-018-05341-y

[50]

10.1039/d0ta00691b

Showing 50 of 63 references

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Details

Published: Dec 06, 2023
Vol/Issue: 14(4)
License: View

Authors

L

Li Shao

State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan University Haikou 570228 China

X

Xindi Han

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University Changchun 130012 P. R. China

L

Lei Shi

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University Changchun 130012 P. R. China

T

Tongzhou Wang

State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan University Haikou 570228 China; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Nankai University Tianjin 300071 China

Y

Yusheng Zhang

State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan University Haikou 570228 China

Z

Zhiqi Jiang

State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan University Haikou 570228 China

Z

Zexiang Yin

State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan University Haikou 570228 China

X

Xuerong Zheng

State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan University Haikou 570228 China

J

Jihong Li

State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan University Haikou 570228 China; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Nankai University Tianjin 300071 China

X

Xiaopeng Han

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University Changchun 130012 P. R. China; School of Materials Science and Engineering Tianjin Key Laboratory of Composite and Functional Materials and Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education Tianjin University Tianjin 300072 P. R. China

Y

Yida Deng

State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan University Haikou 570228 China

Funding

National Natural Science Foundation of China Award: 52231008

Natural Science Foundation of Hainan Province Award: 223RC401

Education Department of Hainan Province Award: Hnky2023ZD‐2

Cite This Article

Li Shao, Xindi Han, Lei Shi, et al. (2023). In Situ Generation of Molybdate‐Modulated Nickel‐Iron Oxide Electrodes with High Corrosion Resistance for Efficient Seawater Electrolysis. Advanced Energy Materials, 14(4). https://doi.org/10.1002/aenm.202303261

In Situ Generation of Molybdate‐Modulated Nickel‐Iron Oxide Electrodes with High Corrosion Resistance for Efficient Seawater Electrolysis

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