High‐Temperature and High‐Energy‐Density Dipolar Glass Polymers Based on Sulfonylated Poly(2,6‐dimethyl‐1,4‐phenylene oxide)

Zhongbo Zhang; David H. Wang; Morton H. Litt; Loon‐Seng Tan; Lei Zhu

doi:10.1002/anie.201710474

journal article Jan 16, 2018

High‐Temperature and High‐Energy‐Density Dipolar Glass Polymers Based on Sulfonylated Poly(2,6‐dimethyl‐1,4‐phenylene oxide)

Zhongbo Zhang

David H. Wang Morton H. Litt

Loon‐Seng Tan Lei Zhu

Angewandte Chemie International Edition Vol. 57 No. 6 pp. 1528-1531 · Wiley

View at Publisher Save 10.1002/anie.201710474

Abstract

AbstractA new class of high‐temperature dipolar polymers based on sulfonylated poly(2,6‐dimethyl‐1,4‐phenylene oxide) (SO2‐PPO) was synthesized by post‐polymer functionalization. Owing to the efficient rotation of highly polar methylsulfonyl side groups below the glass transition temperature (Tg≈220 °C), the dipolar polarization of these SO2‐PPOs was enhanced, and thus the dielectric constant was high. Consequently, the discharge energy density reached up to 22 J cm−3. Owing to its high Tg , the SO2‐PPO25 sample also exhibited a low dielectric loss. For example, the dissipation factor (tan δ) was 0.003, and the discharge efficiency at 800 MV m−1 was 92 %. Therefore, these dipolar glass polymers are promising for high‐temperature, high‐energy‐density, and low‐loss electrical energy storage applications.

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Metrics

162

Citations

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References

Details

Published: Jan 16, 2018
Vol/Issue: 57(6)
Pages: 1528-1531
License: View

Authors

Z

Zhongbo Zhang

Department of Macromolecular Science and Engineering and Department of Chemistry Case Western Reserve University 2100 Adelbert Road Cleveland OH 44106-7202 USA

D

David H. Wang

Materials and Manufacturing Directorate Soft Matter Materials Branch (AFRL/RXAS) Air Force Research Laboratory Wright-Patterson Air Force Base OH 45433-7750 USA; UES, Inc. 4401 Dayton-Xenia Road Dayton OH 45432-1894 USA

M

Morton H. Litt

Department of Macromolecular Science and Engineering and Department of Chemistry Case Western Reserve University 2100 Adelbert Road Cleveland OH 44106-7202 USA

L

Loon‐Seng Tan

Materials and Manufacturing Directorate Soft Matter Materials Branch (AFRL/RXAS) Air Force Research Laboratory Wright-Patterson Air Force Base OH 45433-7750 USA

L

Lei Zhu

Department of Macromolecular Science and Engineering and Department of Chemistry Case Western Reserve University 2100 Adelbert Road Cleveland OH 44106-7202 USA

Funding

Division of Materials Research Award: 1708990

Air Force Office of Scientific Research Award: 15RXCOR115

China Scholarship Council

Cite This Article

Zhongbo Zhang, David H. Wang, Morton H. Litt, et al. (2018). High‐Temperature and High‐Energy‐Density Dipolar Glass Polymers Based on Sulfonylated Poly(2,6‐dimethyl‐1,4‐phenylene oxide). Angewandte Chemie International Edition, 57(6), 1528-1531. https://doi.org/10.1002/anie.201710474

High‐Temperature and High‐Energy‐Density Dipolar Glass Polymers Based on Sulfonylated Poly(2,6‐dimethyl‐1,4‐phenylene oxide)

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