Continuously Tunable Ion Rectification and Conductance in Submicrochannels Stemming from Thermoresponsive Polymer Self‐Assembly

Yafeng Wu; Guang Yang; Mingchang Lin; Xiangyu Kong; Li Mi; Songqin Liu; Guosong Chen; Ye Tian; Lei Jiang

doi:10.1002/anie.201906360

journal article Aug 01, 2019

Continuously Tunable Ion Rectification and Conductance in Submicrochannels Stemming from Thermoresponsive Polymer Self‐Assembly

Yafeng Wu

Guang Yang

Mingchang Lin Xiangyu Kong

Angewandte Chemie International Edition Vol. 58 No. 36 pp. 12481-12485 · Wiley

View at Publisher Save 10.1002/anie.201906360

Abstract

AbstractA biomimetic conical submicrochannel (tip side ca. 400 nm) with functions of continuously tunable ion rectification and conductance based on thermoresponsive polymer layer‐by‐layer (LbL) self‐assembly is presented. These self‐assembled polymers with different layers exhibited a capability to regulate the effective channel diameter, and different ion rectifications/conductance were achieved. By controlling temperature, the conformation and wettability of the assembled polymers were reversibly transformed, thus the ion rectification/conductance could be further adjusted subtly. Owing to the synergistic effect, the ion conductance could be tuned over a wide range spanning three orders of magnitude. Moreover, the proposed system can be applied for on‐demand on‐off molecule delivery, which was important for disease therapy. This study opens a new door for regulating channel size according to actual demand and sensing big targets with different size with one channel.

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References

48

[1]

[2]

10.1021/ja8086104

[3]

10.1021/ja205773a

[4]

10.1002/adma.201805130

[5]

10.1016/j.nantod.2018.04.006

[6]

10.1021/acsnano.7b07923

[7]

10.1002/adma.201600797

[8]

10.1002/adfm.201403693

[9]

[10]

10.1021/acsnano.6b08727

[11]

10.1002/adma.201603884

[12]

10.1002/anie.201609161

[13]

10.1002/ange.201609161

[14]

[15]

10.1021/ja909876h

[16]

10.1021/ac970551g

[17]

[18]

10.1021/jacs.6b11696

[19]

10.1021/nn9013438

[20]

10.1021/ac3004852

[21]

[22]

10.1126/science.aaa2491

[23]

10.1021/cr400531v

[24]

10.1002/adma.200501268

[25]

10.1021/nn700408z

[26]

10.1038/nmat2430

[27]

[28]

10.1016/j.biomaterials.2007.07.021

[29]

10.1002/adhm.201200204

[30]

10.1039/c7cs00406k

[31]

10.1039/c4cc04735d

[32]

10.1002/adma.200602334

[33]

[34]

10.1002/smll.200901701

[35]

10.1021/jacs.7b11472

[36]

10.1002/smll.201400658

[37]

[38]

10.1021/ac202672x

[39]

10.1021/ac303398b

[40]

10.1039/b812642a

[41]

Bard A. J. (2001)

[42]

Poly(N-isopropylacrylamide): experiment, theory and application

H.G. Schild

Progress in Polymer Science 10.1016/0079-6700(92)90023-r

[43]

[44]

10.1038/373049a0

[45]

10.1002/anie.200352565

[46]

10.1002/ange.200352565

[47]

10.1021/ja047895q

[48]

10.1002/adfm.201000989

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Details

Published: Aug 01, 2019
Vol/Issue: 58(36)
Pages: 12481-12485
License: View

Authors

Y

Yafeng Wu

School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 China

G

Guang Yang

Fudan University State Key Lab Mol Engn Polymers Shanghai 200433 P. R. China

M

Mingchang Lin

Fudan University State Key Lab Mol Engn Polymers Shanghai 200433 P. R. China

X

Xiangyu Kong

Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences Beijing 100190 P. R. China

L

Li Mi

School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 China

S

Songqin Liu

School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 China

G

Guosong Chen

Fudan University State Key Lab Mol Engn Polymers Shanghai 200433 P. R. China

Y

Ye Tian

Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences Beijing 100190 P. R. China

L

Lei Jiang

Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences Beijing 100190 P. R. China

Funding

Higher Education Discipline Innovation Project Award: B14009

Cite This Article

Yafeng Wu, Guang Yang, Mingchang Lin, et al. (2019). Continuously Tunable Ion Rectification and Conductance in Submicrochannels Stemming from Thermoresponsive Polymer Self‐Assembly. Angewandte Chemie International Edition, 58(36), 12481-12485. https://doi.org/10.1002/anie.201906360

Continuously Tunable Ion Rectification and Conductance in Submicrochannels Stemming from Thermoresponsive Polymer Self‐Assembly

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