Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO2 Photoreduction with H2O

Meng Lu; Jiang Liu; Qiang Li; Mi Zhang; Ming Liu; Jianbo Wang; Daqiang Yuan; Ya‐Qian Lan

doi:10.1002/anie.201906890

journal article Aug 08, 2019

Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO2 Photoreduction with H2O

Meng Lu

Angewandte Chemie International Edition Vol. 58 No. 36 pp. 12392-12397 · Wiley

View at Publisher Save 10.1002/anie.201906890

Abstract

AbstractSolar energy‐driven conversion of CO2 into fuels with H2O as a sacrificial agent is a challenging research field in photosynthesis. Herein, a series of crystalline porphyrin‐tetrathiafulvalene covalent organic frameworks (COFs) are synthesized and used as photocatalysts for reducing CO2 with H2O, in the absence of additional photosensitizer, sacrificial agents, and noble metal co‐catalysts. The effective photogenerated electrons transfer from tetrathiafulvalene to porphyrin by covalent bonding, resulting in the separated electrons and holes, respectively, for CO2 reduction and H2O oxidation. By adjusting the band structures of TTCOFs, TTCOF‐Zn achieved the highest photocatalytic CO production of 12.33 μmol with circa 100 % selectivity, along with H2O oxidation to O2. Furthermore, DFT calculations combined with a crystal structure model confirmed the structure–function relationship. Our work provides a new sight for designing more efficient artificial crystalline photocatalysts.

Topics

No keywords indexed for this article. Browse by subject →

References

40

[1]

[2]

10.1098/rsif.2012.0984

[3]

10.1126/science.1188566

[4]

[5]

10.1039/c6ee00383d

[6]

10.1002/anie.201600395

[7]

10.1002/ange.201600395

[8]

[9]

10.1021/cs4002089

[10]

10.1002/advs.201500389

[11]

[12]

10.1021/acs.chemrev.6b00439

[13]

10.1002/anie.201710633

[14]

10.1002/ange.201710633

[15]

10.1021/cr5002589

[16]

10.1038/natrevmats.2016.68

[17]

10.1126/science.aac8343

[18]

10.1038/ncomms1542

[19]

10.1021/cm201140r

[20]

[21]

10.1021/jacs.8b09705

[22]

10.1016/j.apcatb.2018.08.004

[23]

[24]

10.1002/anie.200802601

[25]

10.1002/ange.200802601

[26]

10.1021/ja003820k

[27]

[28]

10.1021/jp504087b

[29]

10.1039/c8cs00035b

[30]

10.1021/j100211a031

[31]

10.1002/anie.201811250

[32]

10.1002/ange.201811250

[33]

10.1021/ja206846p

[34]

10.1002/anie.201608597

[35]

10.1002/ange.201608597

[36]

[37]

10.1021/jacs.5b08773

[38]

10.1039/c8ee00415c

[39]

10.1038/s41557-018-0141-5

[40]

10.1039/c5sc04572j

Cited By

535

Steering product selectivity via metallic site-dependent pathways in porphyrin-based covalent organic frameworks for electrocatalytic nitrite reduction

Donghua Li, Hongyin Hu · 2026

Chinese Journal of Catalysis

Charge‐Distribution and Microenvironment Dual Regulation of Covalent Organic Frameworks for Enhancing Photocatalytic H 2 O 2 and H 2 Production

Pei Huang, Yan‐Yu Peng · 2025

Advanced Materials

A versatile strategy for broadening light absorption to ultraviolet–visible region on Zr-based MOF photocatalysts for efficient CO2 reduction

Xin Huang, Zuoyi Wang · 2025

Chemical Engineering Journal

Porphyrin‐Based Covalent Organic Frameworks for CO 2 Photo/Electro‐Reduction

Tingting Sun, Zhi Wang · 2025

Angewandte Chemie International Edi...

Efficient Ammonia Electrosynthesis from Pure Nitrate Reduction via Tuning Bimetallic Sites in Redox‐Active Covalent Organic Frameworks

Miao Wang, Hao‐Ran Xing · 2025

Angewandte Chemie

Self‐Photosensitizing Cobalt Complexes for Photocatalytic CO 2 Reduction Coupled with CH 3 OH Oxidation

Ji‐Hong Zhang, Zhao‐Ming Ge · 2025

Angewandte Chemie

Dual Metallosalen‐Based Covalent Organic Frameworks for Artificial Photosynthetic Diluted CO2 Reduction

Hong Dong, Liang Fang · 2024

Angewandte Chemie International Edi...

Electric Fields in Polymeric Systems

Mark A. Rothermund, Stephen J. Koehler · 2024

Chemical Reviews

Covalent Organic Frameworks for Photocatalysis

Bikash Mishra, Akhtar Alam · 2024

Advanced Materials

Covalent Organic Framework Stabilized Single CoN4Cl2 Site Boosts Photocatalytic CO2 Reduction into Tunable Syngas

Ping Fu, Cailing Chen · 2024

Angewandte Chemie International Edi...

A review on covalent organic frameworks: exploration of their growing potential as porous materials in photocatalytic applications

Kamal Prakash, Rakesh Deka · 2024

Inorganic Chemistry Frontiers

Constructing Photocatalytic Covalent Organic Frameworks with Aliphatic Linkers

Ting Xu, Zhiqiang Wang · 2024

Journal of the American Chemical So...

Three-Dimensional Tetrathiafulvalene-Based covalent organic frameworks for efficient photocatalytic nitrogen fixation

Yunchao Ma, Liaofang Shang · 2024

Chemical Engineering Journal

Rigid covalent organic frameworks with thiazole linkage to boost oxygen activation for photocatalytic water purification

Yanghui Hou, Peng Zhou · 2024

Nature Communications

Superheterojunction covalent organic frameworks: Supramolecular synergetic charge transfer for highly efficient photocatalytic CO2 reduction

Shao–Shuai Zhao, Jun Liang · 2023

Applied Catalysis B: Environmental

Direct CO2 photoreduction from flue gas by synergistic catalysis of a nickel metal–organic framework and a ruthenium polypyridyl complex

Man Dong, Yu Tian · 2023

Inorganic Chemistry Frontiers

Modulated Connection Modes of Redox Units in Molecular Junction Covalent Organic Frameworks for Artificial Photosynthetic Overall Reaction

Qi Li, Jia-Nan Chang · 2023

Journal of the American Chemical So...

Molecular‐Level Regulation Strategies Toward Efficient Charge Separation in Donor−Acceptor Type Conjugated Polymers for Boosted Energy‐Related Photocatalysis

Lu Wang, Linghao Liu · 2023

Advanced Energy Materials

Benzotrithiophene‐based Covalent Organic Framework Photocatalysts with Controlled Conjugation of Building Blocks for Charge Stabilization

Jong‐Pil Jeon, Yu Jin Kim · 2023

Angewandte Chemie International Edi...

A novel cobalt-anchored covalent organic framework for photocatalytic conversion of CO2 into widely adjustable syngas

Jin-Xian Cui, Yao-Mei Fu · 2022

Journal of Materials Chemistry A

Metrics

535

Citations

40

References

Details

Published: Aug 08, 2019
Vol/Issue: 58(36)
Pages: 12392-12397
License: View

Authors

M

Meng Lu

Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University No. 1, Wenyuan Road Nanjing 210023 China

J

Jiang Liu

Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University No. 1, Wenyuan Road Nanjing 210023 China

Q

Qiang Li

School of Physics Southeast University Nanjing 211189 China

M

Mi Zhang

Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University No. 1, Wenyuan Road Nanjing 210023 China

M

Ming Liu

Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University No. 1, Wenyuan Road Nanjing 210023 China

J

Jianbo Wang

School of Physics Southeast University Nanjing 211189 China

D

Daqiang Yuan

State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China

Y

Ya‐Qian Lan

Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University No. 1, Wenyuan Road Nanjing 210023 China

Funding

National Natural Science Foundation of China Award: 21622104

Natural Science Research of Jiangsu Higher Education Institutions of China Award: 17KJB150025

Cite This Article

Meng Lu, Jiang Liu, Qiang Li, et al. (2019). Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO2 Photoreduction with H2O. Angewandte Chemie International Edition, 58(36), 12392-12397. https://doi.org/10.1002/anie.201906890

Rational Design of Crystalline Covalent Organic Frameworks for Efficient CO2 Photoreduction with H2O

You May Also Like