Gradient Solid Electrolyte Interphase and Lithium‐Ion Solvation Regulated by Bisfluoroacetamide for Stable Lithium Metal Batteries

Fang Li; Jian He; Jiandong Liu; Mingguang Wu; Yuyang Hou; Huaping Wang; Shihan Qi; Quanhui Liu; Jiawen Hu; Jianmin Ma

doi:10.1002/anie.202013993

journal article Feb 08, 2021

Gradient Solid Electrolyte Interphase and Lithium‐Ion Solvation Regulated by Bisfluoroacetamide for Stable Lithium Metal Batteries

Fang Li

Jian He

Jiandong Liu Mingguang Wu Yuyang Hou

Huaping Wang

Shihan Qi Quanhui Liu Jiawen Hu

Jianmin Ma

Angewandte Chemie International Edition Vol. 60 No. 12 pp. 6600-6608 · Wiley

View at Publisher Save 10.1002/anie.202013993

Abstract

AbstractThe structures and components of solid electrolyte interphase (SEI) are extremely important to influence the performance of full cells, which is determined by the formulation of electrolyte used. However, it is still challenging to control the formation of high‐quality SEI from structures to components. Herein, we designed bisfluoroacetamide (BFA) as the electrolyte additive for the construction of a gradient solid electrolyte interphase (SEI) structure that consists of a lithophilic surface with C−F bonds to uniformly capture Li ions and a LiF‐rich bottom layer to guide the rapid transportation of Li ions, endowing the homogeneous deposition of Li ions. Moreover, the BFA molecule changes the Li+ solvation structure by reducing free solvents in electrolyte to improve the antioxidant properties of electrolyte and prevent the extensive degradation of electrolyte on the cathode surface, which can make a superior cathode electrolyte interphase (CEI) with high‐content LiF.

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Details

Published: Feb 08, 2021
Vol/Issue: 60(12)
Pages: 6600-6608
License: View

Authors

F

Fang Li