Synthesis of methyl acrylate graft copolymers by the combination of a polynorbornene containing pendant vinylbenzene groups by using coordination and reverse atom transfer polymerization

Rui Ma; Zhongying Song; Yubang Hou; Juan Feng; Bin Xing; Feng Bao

doi:10.1002/aoc.1399

journal article Apr 25, 2008

Synthesis of methyl acrylate graft copolymers by the combination of a polynorbornene containing pendant vinylbenzene groups by using coordination and reverse atom transfer polymerization

Rui Ma

Zhongying Song Yubang Hou Juan Feng

Bin Xing

Feng Bao

Applied Organometallic Chemistry Vol. 22 No. 6 pp. 346-351 · Wiley

View at Publisher Save 10.1002/aoc.1399

Abstract

AbstractCopolymerization of norbornene and 1,4‐divinylbenzene was successfully performed using a β‐ketoamine chelate nickel complex–methylaluminoxane, yielding random copolymer of norbornene and 1,4‐divinylbenzene containing a few pendant styrene groups. With the initiation of copper dichloride and 2,2′‐azobisisobutyronitrile, the pendant styrene groups were quantitatively polymerized with methyl acrylates, which allowed the successful synthesis of polynorbornene‐based graft copolymers by reverse atom transfer radical polymerization mechanism. The analyses of the product by 1H NMR and gel permeation chromatography gave the verification of ‘true’ copolymer. The thermal property of the graft copolymer was controlled by varying the monomer feed ratio. Copyright © 2008 John Wiley & Sons, Ltd.

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Details

Published: Apr 25, 2008
Vol/Issue: 22(6)
Pages: 346-351
License: View

Authors

R

Rui Ma

Electric Power Research Institute

Cite This Article

Rui Ma, Zhongying Song, Yubang Hou, et al. (2008). Synthesis of methyl acrylate graft copolymers by the combination of a polynorbornene containing pendant vinylbenzene groups by using coordination and reverse atom transfer polymerization. Applied Organometallic Chemistry, 22(6), 346-351. https://doi.org/10.1002/aoc.1399

Synthesis of methyl acrylate graft copolymers by the combination of a polynorbornene containing pendant vinylbenzene groups by using coordination and reverse atom transfer polymerization

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