Another application of (NH4)42[MoVI72MoV60O372(CH3COO)30(H2O)72] as a highly efficient recyclable catalyst for the synthesis of dihydropyrano[3,2‐c]chromenes

Marziyeh Rohaniyan; Abolghasem Davoodnia; Ahmad Nakhaei

doi:10.1002/aoc.3479

journal article Apr 12, 2016

Another application of (NH4)42[MoVI72MoV60O372(CH3COO)30(H2O)72] as a highly efficient recyclable catalyst for the synthesis of dihydropyrano[3,2‐c]chromenes

Marziyeh Rohaniyan Abolghasem Davoodnia

Ahmad Nakhaei

Applied Organometallic Chemistry Vol. 30 No. 8 pp. 626-629 · Wiley

View at Publisher Save 10.1002/aoc.3479

Abstract

In continuation of our previous works on the application of (NH4)42[MoVI72MoV60O372(CH3COO)30(H2O)72], a Keplerate‐type giant‐ball nanoporous isopolyoxomolybdate, as a catalyst for the synthesis of heterocyclic compounds, in this paper, we report another application of this attractive catalyst in the synthesis of 2‐amino‐5‐oxo‐4,5‐dihydropyrano[3,2‐c]chromene‐3‐carbonitriles via a one‐pot three‐component reaction of 4‐hydroxycoumarin, aldehydes and malononitrile. The reactions occur in ethanol–water as solvent at room temperature and the process is operative with various aldehydes, giving the corresponding products in high yields. Other beneficial features of this protocol include short reaction times, simple work‐up and the recyclability and reusability of the catalyst for up to five consecutive runs. Copyright © 2016 John Wiley & Sons, Ltd.

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Details

Published: Apr 12, 2016
Vol/Issue: 30(8)
Pages: 626-629
License: View

Authors

M

Marziyeh Rohaniyan

Department of Chemistry, Mashhad Branch Islamic Azad University Mashhad Iran

A

Abolghasem Davoodnia

Department of Chemistry, Mashhad Branch Islamic Azad University Mashhad Iran

A

Ahmad Nakhaei

Department of Chemistry, Mashhad Branch Islamic Azad University Mashhad Iran

Cite This Article

Marziyeh Rohaniyan, Abolghasem Davoodnia, Ahmad Nakhaei (2016). Another application of (NH4)42[MoVI72MoV60O372(CH3COO)30(H2O)72] as a highly efficient recyclable catalyst for the synthesis of dihydropyrano[3,2‐c]chromenes. Applied Organometallic Chemistry, 30(8), 626-629. https://doi.org/10.1002/aoc.3479

Another application of (NH4)42[MoVI72MoV60O372(CH3COO)30(H2O)72] as a highly efficient recyclable catalyst for the synthesis of dihydropyrano[3,2‐c]chromenes

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