Magnetically recoverable lanthanum hydroxide as an efficient catalyst for Aerobic Oxidative Conversions of primary alcohols to the nitriles

Fariborz Ziaee; Mostafa Gholizadeh; Seyed Mohammad Seyedi

doi:10.1002/aoc.4253

journal article Mar 06, 2018

Magnetically recoverable lanthanum hydroxide as an efficient catalyst for Aerobic Oxidative Conversions of primary alcohols to the nitriles

Fariborz Ziaee Mostafa Gholizadeh

Seyed Mohammad Seyedi

Applied Organometallic Chemistry Vol. 32 No. 4 · Wiley

View at Publisher Save 10.1002/aoc.4253

Abstract

Herein we report a novel magnetically recoverable lanthanum hydroxide nanoparticles for oxidative synthesis of nitriles directly from corresponding alcohols with ammonia as nitrogen source. The procedure for the preparation and characterization of La(OH)3/Fe3O4 magnetic nanoparticles were investigated and the scope and generality of the method was explored for a series of structurally diverse primary alcohols with electron‐donating and electron‐withdrawing groups. The best result was observed when 5 mol% of La with respect to the benzyl alcohol was used at reflux condition under O2 atmosphere. The La(OH)3/Fe3O4 magnetic nanoparticles could be easily isolated from the reaction mixture with an external magnet and reused at least 5 times without significant loss in activity.

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References

Details

Published: Mar 06, 2018
Vol/Issue: 32(4)
License: View

Authors

F

Fariborz Ziaee

Department of Chemistry, Faculty of Science Ferdowsi University of Mashhad Mashhad 91775‐1436 I.R. Iran

M

Mostafa Gholizadeh

Department of Chemistry, Faculty of Science Ferdowsi University of Mashhad Mashhad 91775‐1436 I.R. Iran

S

Seyed Mohammad Seyedi

Department of Chemistry, Faculty of Science Ferdowsi University of Mashhad Mashhad 91775‐1436 I.R. Iran

Funding

Research Council of Ferdowsi University of Mashhad Award: 3/41313

Cite This Article

Fariborz Ziaee, Mostafa Gholizadeh, Seyed Mohammad Seyedi (2018). Magnetically recoverable lanthanum hydroxide as an efficient catalyst for Aerobic Oxidative Conversions of primary alcohols to the nitriles. Applied Organometallic Chemistry, 32(4). https://doi.org/10.1002/aoc.4253

Magnetically recoverable lanthanum hydroxide as an efficient catalyst for Aerobic Oxidative Conversions of primary alcohols to the nitriles

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