Research on the direct amination of benzene to aniline by NiAlPO4–5 catalyst

Wei Wang; Yan Yang

doi:10.1002/aoc.4828

journal article Feb 08, 2019

Research on the direct amination of benzene to aniline by NiAlPO4–5 catalyst

Wei Wang

Yan Yang

Applied Organometallic Chemistry Vol. 33 No. 4 · Wiley

View at Publisher Save 10.1002/aoc.4828

Abstract

A series of NiAlPO4–5 molecular sieves have been hydrothermally synthesized and shown high and stable activity in the direct amination of benzene to aniline with hydroxylamine hydrochloride as aminating agent. The as‐synthesized and calcined samples were investigated with XRD, SEM, TG, BET, NH3‐TPD and FT‐IR to explore the crystalline, coordination and location of the incorporated transition metal ions. The results indicated that nickel ions were incorporated into the framework of AlPO4–5 and the as‐synthesized catalysts were highly crystalline, and possessed good thermal stability. Among them, Ni(0.3)AlPO4–5 showed the highest catalytic activity for the direct amination of benzene with the highest aniline yield of 73.2% and 100.0% selectivity to aniline. After the catalyst was reused for 5 times, the activity remained little change.

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Citations

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References

Details

Published: Feb 08, 2019
Vol/Issue: 33(4)
License: View

Authors

W

Wei Wang

Jilin Provincial Engineering Laboratory for the Complex Utilization of Petro‐resources and Biomass, School of Chemical Engineering Changchun University of Technology Changchun 130012 People's Republic of China

Y

Yan Yang

Jilin Provincial Engineering Laboratory for the Complex Utilization of Petro‐resources and Biomass, School of Chemical Engineering Changchun University of Technology Changchun 130012 People's Republic of China

Funding

Changchun University of Science and Technology

Cite This Article

Wei Wang, Yan Yang (2019). Research on the direct amination of benzene to aniline by NiAlPO4–5 catalyst. Applied Organometallic Chemistry, 33(4). https://doi.org/10.1002/aoc.4828

Research on the direct amination of benzene to aniline by NiAlPO4–5 catalyst

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