Synthesis and characterization of styrene/maleimide copolymer with 4‐[N‐ethyl‐N‐(2‐hydroxyethyl) amino]‐4′‐nitroazobenzene as side chain

Hongting Pu; Lu Liu; WeiChun Jiang; Xinwan Li; Jianping Chen

doi:10.1002/app.27809

journal article Jan 23, 2008

Synthesis and characterization of styrene/maleimide copolymer with 4‐[N‐ethyl‐N‐(2‐hydroxyethyl) amino]‐4′‐nitroazobenzene as side chain

Hongting Pu Lu Liu

WeiChun Jiang Xinwan Li Jianping Chen

Journal of Applied Polymer Science Vol. 108 No. 3 pp. 1378-1384 · Wiley

View at Publisher Save 10.1002/app.27809

Abstract

AbstractRelatively low thermal stability of second‐order nonlinear optical (NLO) coefficient due to the relaxation of dipole orientation is a major problem limiting the practical application of these NLO polymers. NLO polymers with suitable Tg are always important for optical devices. In the present work a synthetic approach to styrene‐(N‐(4‐hydroxyphenyl) maleimide) copolymer (SHMI) with 4‐[N‐ethyl‐N‐(2‐hydroxyethyl) amino]‐4′‐nitroazobenzene (DR1) as side chain and chromophores has made it possible to efficiently prepare a NLO polymer. The copolymer with high Tg of 202°C has low relaxation of dipole orientation. The maximum optical loss at the optical communication wavelength is less than 0.9 dB. NLO coefficient r33 is 8.2 pm/V (1550 nm) and its maximum relaxation at room temperature is 18%. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008

Topics

No keywords indexed for this article. Browse by subject →

References

29

[1]

10.1126/science.288.5463.119

[2]

10.1126/science.1077446

[3]

10.1021/ja028897i

[4]

10.1126/science.282.5390.913

[5]

10.1038/42190

[6]

10.1021/cm020438t

[7]

10.1002/1521-3773(20020916)41:18<3363::aid-anie3363>3.0.co;2-v

[8]

10.1007/3-540-45642-2_1

[9]

10.1063/1.360779

[10]

10.1002/adma.200305202

[11]

10.1126/science.268.5217.1604

[12]

10.1063/1.120751

[13]

10.1002/(sici)1099-0518(19980130)36:2<301::aid-pola13>3.0.co;2-s

[14]

10.1016/s0032-3861(01)00405-0

[15]

10.1021/ma970530o

[16]

10.1021/cm970739g

[17]

10.1016/s0032-3861(01)00464-5

[18]

10.1002/(sici)1099-0488(199710)35:14<2385::aid-polb16>3.0.co;2-8

[19]

10.1016/s0032-3861(02)00730-9

[20]

10.1002/pat.334

[21]

10.1002/pola.10579

[22]

10.1016/j.optmat.2004.03.004

[23]

10.1016/s0925-3467(99)00043-9

[24]

Nippon Shokubai Co.JP 0 319 226 (1991).

[25]

The Use of Diethyl Azodicarboxylate and Triphenylphosphine in Synthesis and Transformation of Natural Products

Oyo Mitsunobu

Synthesis 10.1055/s-1981-29317

[26]

10.1021/ja01051a068

[27]

Ma C. B. J Optoelectron Laser (1999)

[28]

10.1021/jp962777d

[29]

10.1364/ol.24.001741

Metrics

13

Citations

29

References

Details

Published: Jan 23, 2008
Vol/Issue: 108(3)
Pages: 1378-1384
License: View

Authors

Department of Anesthesiology and Pain Medicine, Jiangnan University Medical Center, Wuxi No.2 People’s Hospital, Wuxi, China

Cite This Article

Hongting Pu, Lu Liu, WeiChun Jiang, et al. (2008). Synthesis and characterization of styrene/maleimide copolymer with 4‐[N‐ethyl‐N‐(2‐hydroxyethyl) amino]‐4′‐nitroazobenzene as side chain. Journal of Applied Polymer Science, 108(3), 1378-1384. https://doi.org/10.1002/app.27809

Synthesis and characterization of styrene/maleimide copolymer with 4‐[N‐ethyl‐N‐(2‐hydroxyethyl) amino]‐4′‐nitroazobenzene as side chain

You May Also Like