Lignin–phenol–formaldehyde resin adhesives prepared with biorefinery technical lignins

Sheng Yang; Yue Zhang; Tong‐Qi Yuan; Run‐Cang Sun

doi:10.1002/app.42493

journal article Jun 06, 2015

Lignin–phenol–formaldehyde resin adhesives prepared with biorefinery technical lignins

Sheng Yang

Yue Zhang

Tong‐Qi Yuan Run‐Cang Sun

Journal of Applied Polymer Science Vol. 132 No. 36 · Wiley

View at Publisher Save 10.1002/app.42493

Abstract

ABSTRACTIn this study, four biorefinery technical lignins were used to synthesize lignin–phenol–formaldehyde (LPF) resin adhesives with a proposed formulation that was designed based on accurate analysis of the active sites in lignin with 31P nuclear magnetic resonance (NMR). The properties of the LPF resin adhesives and the plywoods prepared with them were tested. The structural features and curing behavior of the LPF resin adhesives were thoroughly investigated by solution‐ and solid‐state 13C NMR. Results indicated that the proposed formulation exhibited favorable adaptability for all four of these technical lignins for synthesis of LPF resin adhesives. High‐performance plywood with low emissions of formaldehyde could be successfully prepared with the synthesized LPF resin adhesives. All the LPF resin adhesives exhibited similar structure and curing behavior with the commercial phenol–formaldehyde (CPF) resin adhesive. However, the LPF resin adhesives showed relatively higher curing temperatures as compared with the CPF resin adhesive. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42493.

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Metrics

99

Citations

37

References

Details

Published: Jun 06, 2015
Vol/Issue: 132(36)
License: View

Authors

S

Sheng Yang

Beijing Key Laboratory of Lignocellulosic Chemistry Beijing Forestry University Beijing 100083 China

Y

Yue Zhang

Beijing Key Laboratory of Lignocellulosic Chemistry Beijing Forestry University Beijing 100083 China

T

Tong‐Qi Yuan

Beijing Key Laboratory of Lignocellulosic Chemistry Beijing Forestry University Beijing 100083 China

R

Run‐Cang Sun

Beijing Key Laboratory of Lignocellulosic Chemistry Beijing Forestry University Beijing 100083 China

Funding

Beijing Municipal Commission of Education Award: 20131002201

National Science Foundation of China Award: 31110103902

the open fund project of State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, China Award: 201364

Cite This Article

Sheng Yang, Yue Zhang, Tong‐Qi Yuan, et al. (2015). Lignin–phenol–formaldehyde resin adhesives prepared with biorefinery technical lignins. Journal of Applied Polymer Science, 132(36). https://doi.org/10.1002/app.42493

Lignin–phenol–formaldehyde resin adhesives prepared with biorefinery technical lignins

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