Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes

Daniel V. Golubenko; Bart Van der Bruggen; Andrey B. Yaroslavtsev

doi:10.1002/app.48656

journal article Nov 01, 2019

Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes

Daniel V. Golubenko Bart Van der Bruggen

Andrey B. Yaroslavtsev

Journal of Applied Polymer Science Vol. 137 No. 19 · Wiley

View at Publisher Save 10.1002/app.48656

Abstract

ABSTRACTA novel anion‐exchange membrane has been manufactured by chloromethylation and subsequent quaternization of polystyrene within a graft copolymer films based on UV‐oxidized polymethylpentene. Particular attention is given to the kinetics of chloromethylation and the influence of the reaction conditions on the properties of the anion‐exchange membranes. By means of variation of the polystyrene content and its crosslinking degree we have obtained membranes that have an ion‐exchange capacity from 1.1 to 2.9 mmole g−1, anion transport numbers between 91.0 and 95.5% and specific ionic conductivities ( ranging from 2 to 25 mS cm−1. The developed membranes due to their low thickness and high conductivities have a remarkably low surface ionic resistance of around 0.6 Ω cm2. It was calculated that the use of the developed materials will increase the efficiency of reverse electrodialysis energy production by 8–10% compared to the state of the art membranes. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48656.

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References

Details

Published: Nov 01, 2019
Vol/Issue: 137(19)
License: View

Authors

D

Daniel V. Golubenko

Russian Academy of Sciences N.S. Kurnakov Institute of General and Inorganic Chemistry 31 Leninsky prospect, Moscow 119991 Russian Federation; Russian Academy of Sciences Institute of Problems of Chemical Physics Academician Semenov Avenue 1, Chernogolovka 142432 Moscow Region Russian Federation

B

Bart Van der Bruggen

Department of Chemical Engineering KU Leuven Celestijnenlaan 200F, B‐3001 Leuven Belgium; Faculty of Engineering and the Built Environment Tshwane University of Technology Private Bag X680 Pretoria 0001 South Africa

A

Andrey B. Yaroslavtsev

Russian Academy of Sciences N.S. Kurnakov Institute of General and Inorganic Chemistry 31 Leninsky prospect, Moscow 119991 Russian Federation; Russian Academy of Sciences Institute of Problems of Chemical Physics Academician Semenov Avenue 1, Chernogolovka 142432 Moscow Region Russian Federation

Funding

Russian Science Foundation Award: 17‐79‐30 054

Cite This Article

Daniel V. Golubenko, Bart Van der Bruggen, Andrey B. Yaroslavtsev (2019). Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes. Journal of Applied Polymer Science, 137(19). https://doi.org/10.1002/app.48656

Novel anion exchange membrane with low ionic resistance based on chloromethylated/quaternized‐grafted polystyrene for energy efficient electromembrane processes

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