journal article Nov 01, 2024

Lithium in drinking water: Review of chemistry, analytical methods, and treatment technologies

View at Publisher Save 10.1002/aws2.70009
Abstract
AbstractLithium was included in the fifth Unregulated Contaminants Monitoring Rule, signaling the Environmental Protection Agency's interest in regulating lithium. Many questions regarding occurrence, health effects, and treatability of lithium exist. This review primarily focuses on the relationship between lithium chemistry and treatability. Sampling indicates nationwide lithium occurrence in drinking water. Yet, lithium is not included in the Integrated Risk Information System, reflecting a lack of censuses regarding its health effects. Aqueous lithium is a monovalent cation with size, charge density, and solubility properties that present treatment challenges. Lithium's growing economic value is stimulating new extraction and isolation technologies, but these may not be transferable to drinking water treatment. Currently, reverse osmosis is the only full‐scale drinking water treatment technology that can reliably remove significant levels (>50%) of lithium. Focusing future research efforts on electrodialysis and inorganic ion sieves may yield significant gains in effectiveness and readiness for the drinking water industry.
Topics

No keywords indexed for this article. Browse by subject →

References
172
[5]
Ali U.(2020).Are mining companies jumping the gun on lithium?Mining Technology.https://www.mining-technology.com/features/are-mining-companies-jumping-the-gun-on-lithium/. Accessed June 18 2024
[7]
American Water Works Association (2011)
[8]
American Water Works Association. (n.d.).Resource topics: Membrane processes.https://www.awwa.org/Resources-Tools/Resource-Topics/Membrane-Processes. Accessed July 3 2024
[9]
APHA WEF 2005. Standard Methods for the Examination of Water and Wastewater 21st Edition. American Public Health Association.
[11]
ASTM. (2017).Standard test method for determination of dissolved alkali and alkaline earth cations and ammonium in water and wastewater by ion chromatography. ASTM Method D6919‐17.
[12]
ASTM. (2021).Test method for lithium potassium and sodium ions in brackish water seawater and brines by atomic absorption spectrophotometry. ASTM Method D3561‐16.
[13]
AWWA (2022)
[14]
Ayotte J. D. Gronberg J. A. M. &Apodaca L. E.(2011).Trace elements and radon in groundwater across the United States 1992–2003. (Report No. 2011–5059) Scientific Investigations Report. Reston VA. 10.3133/sir20115059
[19]
Bradley D. Stillings L. L. Jaskula B. W. Munk L. &McCauley A. D.(2017).Lithium (Report No. 1802K) Critical mineral resources of the United States—Economic and environmental geology and prospects for future supply: U.S. Geological Survey Professional Paper 1802. Reston VA.
[28]
Creed J. T. Brockhoff C. A. &Martin T. D.(1994).EPA method 200.8: Determination of trace elements in waters and wastes by inductively coupled plasma ‐ mass spectrometry.
[30]
Davis T. A. (1990)
[33]
ECOLAB. (2024).Purification systems of a primary circuit treatment for a PWR.https://www.purolite.com/index/core-technologies/industry/power/nuclear-power/pressurized-water-reactors/purification-systems-of-a-primary-circuit-treatment-pwr. Accessed November 9 2024
[39]
Fishman M. J. (1989)
[40]
Garbarino J. R.(1999).Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory—Determination of dissolved arsenic boron lithium selenium strontium thallium and vanadium using inductively coupled plasma–mass spectrometry. USGS Open‐File Report 99–093. 10.3133/ofr9993
[41]
Garbarino J. R. &Struzeski T. M.(1998).Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory—Determination of elements in whole‐water digests using inductively coupled plasma–optical emission spectrometry and inductively coupled plasma–mass spectrometry. USGS Open‐File Report 98‐165 1–114. 10.3133/ofr98165
[42]
Garg D. &Clifford D.(1992).Removing radium from water by plain and treated activated alumina. EPA report EPA/600/SR‐92/048.
[46]
Goodwill J. (2006)
[48]
Gustafsson J.(2024).Visual MINTEQ Ver. 4.05.

Showing 50 of 172 references

Metrics
6
Citations
172
References
Details
Published
Nov 01, 2024
Vol/Issue
6(6)
License
View
Cite This Article
Julie A. Korak, Philip J. Brandhuber, Joseph E. Goodwill (2024). Lithium in drinking water: Review of chemistry, analytical methods, and treatment technologies. AWWA Water Science, 6(6). https://doi.org/10.1002/aws2.70009