Anodic Stability of New Sulfone‐Based Electrolytes for Lithium‐Ion Batteries

Benjamin Flamme; Mansour Haddad; Phannarath Phansavath; Virginie Ratovelomanana‐Vidal; Alexandre Chagnes

doi:10.1002/celc.201701343

journal article May 30, 2018

Anodic Stability of New Sulfone‐Based Electrolytes for Lithium‐Ion Batteries

Benjamin Flamme Mansour Haddad Phannarath Phansavath Virginie Ratovelomanana‐Vidal Alexandre Chagnes

ChemElectroChem Vol. 5 No. 16 pp. 2279-2287 · Wiley

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Abstract

AbstractTwenty‐two new bifunctional sulfones containing ester, ether and carbonate moieties have been synthesized in the present work. Their physicochemical properties [dynamic viscosity, ionic conductivity in the presence of lithium bis‐trifluoromethanesulfonimidate (LiTFSI), boiling and melting points] and their anodic stability have been investigated. Major drawbacks for the use of these sulfones in lithium‐ion batteries (LiBs) are their high viscosities and high melting points. Nevertheless, these solvents exhibit high anodic stability at platinum, glassy carbon, and NMC (LiNi1/3Mn1/3Co1/3) electrodes and their ionic conductivities in the presence of LiTFSI remain high enough to envisage their use in LiBs despite their high viscosities. In particular, 3‐methoxytetrahydrothiophene 1,1‐dioxide (MESL) is the most interesting among the 22 synthesized sulfones, because MESL exhibits an oxidation potential at a NMC cathode in the presence of LiTFSI of 4.9 V vs. Li/Li+, an ionic conductivity equal to 1 mS cm−1, and a low melting point as well as a high boiling point.

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Details

Published: May 30, 2018
Vol/Issue: 5(16)
Pages: 2279-2287
License: View

Authors

B

Benjamin Flamme

PSL Research University Chimie ParisTech-CNRS Institut de Recherche de Chimie Paris 11 rue Pierre et Marie Curie 75005 Paris France

M

Mansour Haddad

PSL Research University Chimie ParisTech-CNRS Institut de Recherche de Chimie Paris 11 rue Pierre et Marie Curie 75005 Paris France

P

Phannarath Phansavath

PSL Research University Chimie ParisTech-CNRS Institut de Recherche de Chimie Paris 11 rue Pierre et Marie Curie 75005 Paris France

V

Virginie Ratovelomanana‐Vidal

PSL Research University Chimie ParisTech-CNRS Institut de Recherche de Chimie Paris 11 rue Pierre et Marie Curie 75005 Paris France

A

Alexandre Chagnes

GéoRessources – UMR CNRS 7359-CREGU Université de Lorraine 2 Rue du Doyen Roubault 54500 BP 10162 Vandoeuvre-les-Nancy Cedex France

Funding

Agence Nationale de la Recherche Award: ANR DEVEGA

Cite This Article

Benjamin Flamme, Mansour Haddad, Phannarath Phansavath, et al. (2018). Anodic Stability of New Sulfone‐Based Electrolytes for Lithium‐Ion Batteries. ChemElectroChem, 5(16), 2279-2287. https://doi.org/10.1002/celc.201701343

Anodic Stability of New Sulfone‐Based Electrolytes for Lithium‐Ion Batteries

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