Converting Poly(Methyl Methacrylate) into a Triple‐Responsive Polymer

Christian Hils; Emma Fuchs; Franziska Eger; Judith Schöbel; Holger Schmalz

doi:10.1002/chem.202000485

journal article Open Access Apr 24, 2020

Converting Poly(Methyl Methacrylate) into a Triple‐Responsive Polymer

Christian Hils Emma Fuchs Franziska Eger Judith Schöbel Holger Schmalz

Chemistry – A European Journal Vol. 26 No. 25 pp. 5611-5614 · Wiley

View at Publisher Save 10.1002/chem.202000485

Abstract

AbstractMultiresponsive polymers that can respond to several external stimuli are promising materials for a manifold of applications. Herein, a facile method for the synthesis of triple‐responsive (pH, temperature, CO2) poly(N,N‐diethylaminoethyl methacrylamide) by a post‐polymerization amidation of poly(methyl methacrylate) (PMMA) is presented. Combined with trivalent counterions ([Fe(CN)6]3−) both an upper and lower critical solution temperature (UCST/LCST)‐type phase behavior can be realized at pH 8 and 9. PMMA and PMMA‐based block copolymers are readily accessible by living anionic and controlled radical polymerization techniques, which opens access to various responsive polymer architectures based on the developed functionalization method. This method can also be applied on melt‐processed bulk PMMA samples to introduce functional, responsive moieties at the PMMA surface.

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Synthesis of functional polyacrylamide (co)polymers by organocatalyzed post-polymerization modification of non-activated esters

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Metrics

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Citations

32

References

Details

Published: Apr 24, 2020
Vol/Issue: 26(25)
Pages: 5611-5614
License: View

Authors

C

Christian Hils

Macromolecular Chemistry II Universität Bayreuth Universitätsstrasse 30 95440 Bayreuth Germany

E

Emma Fuchs

Macromolecular Chemistry II Universität Bayreuth Universitätsstrasse 30 95440 Bayreuth Germany

F

Franziska Eger

Macromolecular Chemistry II Universität Bayreuth Universitätsstrasse 30 95440 Bayreuth Germany

J

Judith Schöbel

Macromolecular Chemistry & New Polymeric Materials Zernike Institute for Advanced Materials University of Groningen Nijenborgh 4 9747 AG Groningen Germany

H

Holger Schmalz

Macromolecular Chemistry II Universität Bayreuth Universitätsstrasse 30 95440 Bayreuth Germany; Keylab Synthesis and Molecular Characterization Bavarian Polymer Institute Universität Bayreuth Universitätsstrasse 30 95440 Bayreuth Germany

Funding

Deutsche Forschungsgemeinschaft Award: SFB 840 TP A2

Cite This Article

Christian Hils, Emma Fuchs, Franziska Eger, et al. (2020). Converting Poly(Methyl Methacrylate) into a Triple‐Responsive Polymer. Chemistry – A European Journal, 26(25), 5611-5614. https://doi.org/10.1002/chem.202000485

Converting Poly(Methyl Methacrylate) into a Triple‐Responsive Polymer

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