journal article Dec 30, 2010

The Hydrogen Issue

ChemSusChem Vol. 4 No. 1 pp. 21-36 · Wiley
View at Publisher Save 10.1002/cssc.201000182
Abstract
AbstractHydrogen is often proposed as the fuel of the future, but the transformation from the present fossil fuel economy to a hydrogen economy will need the solution of numerous complex scientific and technological issues, which will require several decades to be accomplished. Hydrogen is not an alternative fuel, but an energy carrier that has to be produced by using energy, starting from hydrogen‐rich compounds. Production from gasoline or natural gas does not offer any advantage over the direct use of such fuels. Production from coal by gasification techniques with capture and sequestration of CO2 could be an interim solution. Water splitting by artificial photosynthesis, photobiological methods based on algae, and high temperatures obtained by nuclear or concentrated solar power plants are promising approaches, but still far from practical applications. In the next decades, the development of the hydrogen economy will most likely rely on water electrolysis by using enormous amounts of electric power, which in its turn has to be generated. Producing electricity by burning fossil fuels, of course, cannot be a rational solution. Hydroelectric power can give but a very modest contribution. Therefore, it will be necessary to generate large amounts of electric power by nuclear energy of by renewable energies. A hydrogen economy based on nuclear electricity would imply the construction of thousands of fission reactors, thereby magnifying all the problems related to the use of nuclear energy (e.g., safe disposal of radioactive waste, nuclear proliferation, plant decommissioning, uranium shortage). In principle, wind, photovoltaic, and concentrated solar power have the potential to produce enormous amounts of electric power, but, except for wind, such technologies are too underdeveloped and expensive to tackle such a big task in a short period of time. A full development of a hydrogen economy needs also improvement in hydrogen storage, transportation and distribution. Hydrogen and electricity can be easily interconverted by electrolysis and fuel cells, and which of these two energy carriers will prevail, particularly in the crucial field of road vehicle powering, will depend on the solutions found for their peculiar drawbacks, namely storage for electricity and transportation and distribution for hydrogen. There is little doubt that power production by renewable energies, energy storage by hydrogen, and electric power transportation and distribution by smart electric grids will play an essential role in phasing out fossil fuels.
Topics

No keywords indexed for this article. Browse by subject →

References
98
[1]
Armaroli N. (2011)
[6]
Rifkin J. (2003)
[8]
Rand D. A. J. (2008)
[9]
(2008)
[10]
Congressional Research Service (CRS) Hydrogen and Fuel Cell Vehicle R&D: FreedomCAR and the President’s Hydrogen Fuel Initiative 2007. Available fromhttp://ncseonline.org/NLE/CRSreports/07May/RS21442.pdf(accessed November 2010) .
[12]
The Fuel Cell and Hydrogen Joint Technology Initiative. Available fromhttp://ec.europa.eu/research/fch/index_en.cfm(accessed November 2010).
[16]
Smil V. (2008)
[17]
Wilson J. R. (2008)
[18]
Olah G. A. (2006)
[20]
US DOE Hydrogen Posture Plan. An Integrated Research Development and Demonstration Plan 2006. Available fromhttp://hydrogen.energy.gov/(accessed November 2010).
[21]
Neville A. Power (2009)
[23]
Trager R. Chem. World (2009)
[30]
Hydrogen Production Reactions from Carbon Feedstocks:  Fossil Fuels and Biomass

R. M. Navarro, M. A. Peña, J. L. G. Fierro

Chemical Reviews 10.1021/cr0501994
[34]
J. A. Turner M. C. Williams K. Rajeshwar The Electrochemical Society Interface 2004(Fall) p. 24. 10.1149/2.f04043if
[38]
WEC 2010 Survey of Energy Resources Interim 2010. Available fromhttp://www.worldenergy.org/(accessed November 2010).
[40]
Key World Energy Statistics 2009. Available fromhttp://www.iea.org/(accessed November 2010).
[42]
Kohl H. (2008)
[45]
European Wind Energy Association Global Statistics. Available fromhttp://www.ewea.org/(accessed November 2010).
[46]
European Wind Energy Association Pure Power ‐ Wind Energy Targets for 2020 and 2030 2009. Available fromhttp://www.ewea.org/(accessed November 2010).

Showing 50 of 98 references

Cited By
965
Sustainable Energy & Fuels
E3S Web of Conferences
International Journal of Hydrogen E...
International Journal of Hydrogen E...
Formic Acid as a Hydrogen Energy Carrier

Jörg Eppinger, Kuo-Wei Huang · 2016

ACS Energy Letters
Metrics
965
Citations
98
References
Details
Published
Dec 30, 2010
Vol/Issue
4(1)
Pages
21-36
License
View
Cite This Article
Nicola Armaroli, Vincenzo Balzani (2010). The Hydrogen Issue. ChemSusChem, 4(1), 21-36. https://doi.org/10.1002/cssc.201000182
Related

You May Also Like