Novel Hydroxylated Cardanol Quaternary Ammonium Salts from Renewable Resource and its Synergistic Vesicles of Binary and Ternary Composite System in Detergent

Xuehua Zhao; Jinge Lv; Limin Wang; Jianwei Han

doi:10.1002/jsde.12449

journal article Jul 28, 2020

Novel Hydroxylated Cardanol Quaternary Ammonium Salts from Renewable Resource and its Synergistic Vesicles of Binary and Ternary Composite System in Detergent

Xuehua Zhao Jinge Lv

Limin Wang

Jianwei Han

Journal of Surfactants and Detergents Vol. 24 No. 1 pp. 15-33 · Wiley

View at Publisher Save 10.1002/jsde.12449

Abstract

AbstractA series of novel hydroxylated cardanol quaternary ammonium salts (HCQAS 3a–3g) with one or two hydroxyl groups, derived from renewable cardanol, a plant‐based and low‐cost material natural cashew nut shell liquid (CNSL), have been rationally designed and investigated as additive in detergent. CMC, γCMC, C20, pC20, and CMC/C20 were employed to exhibit the surface properties of HCQAS, reflecting that the surfactivity were superior to general cationic surfactants. In addition, HCQAS revealed excellent water solubility and wettability by krafft point and contact angle tests. Moreover, emulsifiability and foamability conversions were monitored versus time and volume of foam, respectively. Also, TEM micrographs were taken to provide the aggregation morphologies of HCQAS 3a aqueous solution at different concentration. Furthermore, HCQAS 3a and BGF‐10 binary composite system as well as HCQAS 3a, BGF‐10, and SDBS ternary composite system were investigated by CMC, γCMC, emulsifiability, and foamability to determine the optimum molar ratio (HCQAS 3a: BGF‐10: SDBS = 0.24:0.36:0.4), and then, analysis of morphology by TEM showed that the incorporation of HCQAS 3a, BGF‐10, and SDBS in aqueous solution accelerated the formation of abundant vesicles with large volume and surface area. Finally, a green concentrated detergent was designed and prepared with the filtered ratio, where the presence of vesicles greatly enhanced detergency to promisingly replace the familiar use of petroleum‐based TX‐10 in detergent. This study on the structure and performance of HCQAS may shed some light on the development of novel environmentally friendly surfactant.

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Details

Published: Jul 28, 2020
Vol/Issue: 24(1)
Pages: 15-33
License: View

Authors

X

Xuehua Zhao

Institute of Fine Chemicals, School of Chemistry and Molecular Engineering East China University of Science and Technology No. 130, Meilong Road, Shanghai 200237 China; Shanghai Jahwa United Co., Ltd. No. 2058, Beiying Road, Shanghai 201708 China

J

Jinge Lv

Institute of Fine Chemicals, School of Chemistry and Molecular Engineering East China University of Science and Technology No. 130, Meilong Road, Shanghai 200237 China

L

Limin Wang

Institute of Fine Chemicals, School of Chemistry and Molecular Engineering East China University of Science and Technology No. 130, Meilong Road, Shanghai 200237 China

J

Jianwei Han

Institute of Fine Chemicals, School of Chemistry and Molecular Engineering East China University of Science and Technology No. 130, Meilong Road, Shanghai 200237 China

Funding

National Natural Science Foundation of China Award: 21272069

Fundamental Research Funds for the Central Universities

Cite This Article

Xuehua Zhao, Jinge Lv, Limin Wang, et al. (2020). Novel Hydroxylated Cardanol Quaternary Ammonium Salts from Renewable Resource and its Synergistic Vesicles of Binary and Ternary Composite System in Detergent. Journal of Surfactants and Detergents, 24(1), 15-33. https://doi.org/10.1002/jsde.12449

Novel Hydroxylated Cardanol Quaternary Ammonium Salts from Renewable Resource and its Synergistic Vesicles of Binary and Ternary Composite System in Detergent

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