Semicrystalline Macromolecular Design by Nitroxide‐Mediated Polymerization

Khaled Karaky; Gérald Clisson; Günter Reiter; Laurent Billon

doi:10.1002/macp.200700578

journal article Mar 31, 2008

Semicrystalline Macromolecular Design by Nitroxide‐Mediated Polymerization

Khaled Karaky Gérald Clisson Günter Reiter

Laurent Billon

Macromolecular Chemistry and Physics Vol. 209 No. 7 pp. 715-722 · Wiley

View at Publisher Save 10.1002/macp.200700578

Abstract

AbstractThe syntheses of PODA‐b‐PMA and PODA‐grad‐PMA copolymers using NMP are reported for the first time. The gradient copolymerization of ODA and MA was performed in a semi‐batch system with a continuous addition of MA during ODA polymerization. The results showed that the semi‐batch NMP proceeded in a living fashion, producing well‐defined copolymers with narrow polydispersities and controlled molecular weights. The potentially semicrystalline copolymers were characterized by techniques such as 1H NMR, SEC and DSC. Their surface crystallization has also been studied by AFM.magnified image

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Citations

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References

Details

Published: Mar 31, 2008
Vol/Issue: 209(7)
Pages: 715-722
License: View

Authors

Bio‐inspired Materials Group: Functionalities & Self‐assembly Institut des Sciences Analytiques et Physico‐chimie pour l'environnement et les matériaux Universite de Pau et des Pays de l’Adour 64000 Pau France

Funding

FEDER

FNADT

CG Pyrénées Atlantiques

Association “2PSM”

Cite This Article

Khaled Karaky, Gérald Clisson, Günter Reiter, et al. (2008). Semicrystalline Macromolecular Design by Nitroxide‐Mediated Polymerization. Macromolecular Chemistry and Physics, 209(7), 715-722. https://doi.org/10.1002/macp.200700578

Semicrystalline Macromolecular Design by Nitroxide‐Mediated Polymerization

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