Preparation of benzyl alcohol by hydrogenation of benzoic acid catalyzed by a magnesium Oxide‐supported poly‐γ‐aminopropylsiloxane–Ru–Pd–Sn complex

Bao‐Wei Mao; Jin‐Fei Wu; Mei‐Yu Huang; Ying‐Yan Jiang

doi:10.1002/pat.189

journal article Feb 11, 2002

Preparation of benzyl alcohol by hydrogenation of benzoic acid catalyzed by a magnesium Oxide‐supported poly‐γ‐aminopropylsiloxane–Ru–Pd–Sn complex

Bao‐Wei Mao Jin‐Fei Wu Mei‐Yu Huang Ying‐Yan Jiang

Polymers for Advanced Technologies Vol. 13 No. 3-4 pp. 301-304 · Wiley

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Abstract

AbstractBenzyl alcohol in higher than 90% yield was achieved from the hydrogenation of benzoic acid catalyzed by using a magnesium oxide‐supported poly‐γ‐aminopropylsiloxane–ruthenium–palladium–stannum trimetallic complex catalyst (MgO–NH2–Ru–Pd–Sn) in 1,4‐dioxane. The Ru/Pd/Sn mole ratio, reaction temperature, hydrogen gas pressure and reaction time greatly influenced the reaction. The catalyst was stable and could be used repeatedly without any remarkable changes in catalytic activity. Copyright © 2002 John Wiley & Sons, Ltd.

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References

3

[1]

10.1016/0022-328x(83)80240-x

[2]

10.1002/pat.1994.220050925

[3]

10.1002/pat.1994.220050925

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Published: Feb 11, 2002
Vol/Issue: 13(3-4)
Pages: 301-304
License: View

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Cite This Article

Bao‐Wei Mao, Jin‐Fei Wu, Mei‐Yu Huang, et al. (2002). Preparation of benzyl alcohol by hydrogenation of benzoic acid catalyzed by a magnesium Oxide‐supported poly‐γ‐aminopropylsiloxane–Ru–Pd–Sn complex. Polymers for Advanced Technologies, 13(3-4), 301-304. https://doi.org/10.1002/pat.189

Preparation of benzyl alcohol by hydrogenation of benzoic acid catalyzed by a magnesium Oxide‐supported poly‐γ‐aminopropylsiloxane–Ru–Pd–Sn complex

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