Optimization of CdTe thin‐film solar cell efficiency using a sputtered, oxygenated CdS window layer

Jason M. Kephart; Russell M. Geisthardt; W. S. Sampath

doi:10.1002/pip.2578

journal article Jan 21, 2015

Optimization of CdTe thin‐film solar cell efficiency using a sputtered, oxygenated CdS window layer

Jason M. Kephart Russell M. Geisthardt W. S. Sampath

Progress in Photovoltaics: Research and Applications Vol. 23 No. 11 pp. 1484-1492 · Wiley

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Abstract

AbstractA major source of loss in cadmium sulfide/cadmium telluride (CdS/CdTe) solar cells results from light absorbed in the CdS window layer, which is not converted to electrical current. This film can be made more transparent by oxygen incorporation during sputter deposition at ambient temperature. Prior to this work, this material has not produced high‐efficiency devices on tin oxide‐coated soda‐lime‐glass substrates used industrially. Numerous devices were fabricated over a variety of process conditions to produce an optimized device. Although the material does not show a consistent increase in band gap with oxygenation, absorption in this layer can be virtually eliminated over the relevant spectrum, leading to an increase in short‐circuit current. Meanwhile, fill factor is maintained, and open‐circuit voltage increases relative to baseline devices with sublimated CdS. The trend of device parameters with oxygenation and thickness is consistent with an increasing conduction band offset at the window/CdTe interface. Optimization considering both initial efficiency and stability resulted in a National Renewable Energy Laboratory verified 15.2%‐efficient cell on 3.2‐mm soda‐lime glass. This window material was shown to be compatible with SnO2‐based transparent conducting oxide and high resistance transparent coated substrates using in‐line compatible processes. Copyright © 2015 John Wiley & Sons, Ltd

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References

Details

Published: Jan 21, 2015
Vol/Issue: 23(11)
Pages: 1484-1492
License: View

Authors

J

Jason M. Kephart

Colorado State University Mechanical Engineering Fort Collins CO USA

R

Russell M. Geisthardt

Colorado State University Physics Fort Collins CO USA

W

W. S. Sampath

Colorado State University Mechanical Engineering Fort Collins CO USA

Funding

U.S. Department of Energy

Cite This Article

Jason M. Kephart, Russell M. Geisthardt, W. S. Sampath (2015). Optimization of CdTe thin‐film solar cell efficiency using a sputtered, oxygenated CdS window layer. Progress in Photovoltaics: Research and Applications, 23(11), 1484-1492. https://doi.org/10.1002/pip.2578

Optimization of CdTe thin‐film solar cell efficiency using a sputtered, oxygenated CdS window layer

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