journal article Oct 30, 2014

Perovskite Solar Cells: From Materials to Devices

Small Vol. 11 No. 1 pp. 10-25 · Wiley
View at Publisher Save 10.1002/smll.201402767
Abstract
Perovskite solar cells based on organometal halide light absorbers have been considered a promising photovoltaic technology due to their superb power conversion efficiency (PCE) along with very low material costs. Since the first report on a long‐term durable solid‐state perovskite solar cell with a PCE of 9.7% in 2012, a PCE as high as 19.3% was demonstrated in 2014, and a certified PCE of 17.9% was shown in 2014. Such a high photovoltaic performance is attributed to optically high absorption characteristics and balanced charge transport properties with long diffusion lengths. Nevertheless, there are lots of puzzles to unravel the basis for such high photovoltaic performances. The working principle of perovskite solar cells has not been well established by far, which is the most important thing for understanding perovksite solar cells. In this review, basic fundamentals of perovskite materials including opto‐electronic and dielectric properties are described to give a better understanding and insight into high‐performing perovskite solar cells. In addition, various fabrication techniques and device structures are described toward the further improvement of perovskite solar cells.
Topics

No keywords indexed for this article. Browse by subject →

References
101
[3]
Conducting tin halides with a layered organic-based perovskite structure

D. B. Mitzi, C. A. Feild, W. T. A. Harrison et al.

Nature 10.1038/369467a0
[4]
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

Akihiro Kojima, Kenjiro Teshima, Yasuo Shirai et al.

Journal of the American Chemical Society 10.1021/ja809598r
[5]
Dye-Sensitized Solar Cells

Anders Hagfeldt, Gerrit Boschloo, Licheng Sun et al.

Chemical Reviews 10.1021/cr900356p
[7]
6.5% efficient perovskite quantum-dot-sensitized solar cell

Jeong-Hyeok Im, Chang-Ryul Lee, Jeong Yong Lee et al.

Nanoscale 10.1039/c1nr10867k
[8]
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%

Hui-Seon Kim, Chang-Ryul Lee, Jeong-Hyeok Im et al.

Scientific Reports 10.1038/srep00591
[12]
Hench L. L. (1990)
[13]
Relationship Between Bond Ionicity, Lattice Energy, and Microwave Dielectric Properties of Zn ( Ta 1− x Nb x ) 2 O 6 Ceramics

Wang‐Suo Xia, Ling‐Xia Li, Ping‐Fan Ning et al.

Journal of the American Ceramic Society 10.1111/j.1551-2916.2012.05231.x
[15]
Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy

A. Poglitsch, D. Weber

The Journal of Chemical Physics 10.1063/1.453467
[16]
Onoda‐Yamamura N. (1990)
[18]
Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance

Stefaan De Wolf, Jakub Holovsky, Soo-Jin Moon et al.

The Journal of Physical Chemistry Letters 10.1021/jz500279b
[19]
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties

Constantinos C. Stoumpos, Christos D. Malliakas, Mercouri G. Kanatzidis

Inorganic Chemistry 10.1021/ic401215x
[20]
Anomalous Band Gap Behavior in Mixed Sn and Pb Perovskites Enables Broadening of Absorption Spectrum in Solar Cells

Feng Hao, Constantinos C. Stoumpos, Robert P. H. Chang et al.

Journal of the American Chemical Society 10.1021/ja5033259
[23]
Relativistic GW calculations on CH3NH3PbI3 and CH3NH3SnI3 Perovskites for Solar Cell Applications

Paolo Umari, Edoardo Mosconi, Filippo De Angelis

Scientific Reports 10.1038/srep04467
[27]
(1990)
[28]
127I-NQR, 119 Sn Mössbauer Effect, and Electrical Conductivity of MSnI3 (M = K, NH4 , Rb, Cs, and CH3NH3 )

Koji Yamada, Takashi Matsui, Tomoko Tsuritani et al.

Zeitschrift für Naturforschung A 10.1515/zna-1990-3-416
[30]
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3

Guichuan Xing, Nripan Mathews, Shikuan Sun et al.

Science 10.1126/science.1243167
[31]
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber

Samuel D. Stranks, Giles E. Eperon, Giulia Grancini et al.

Science 10.1126/science.1243982
[36]
Gonzalez‐Pedro V. Nano Lett. (2014)
[40]
Low-Temperature Processed Electron Collection Layers of Graphene/TiO2 Nanocomposites in Thin Film Perovskite Solar Cells

Jacob Tse-Wei Wang, James M. Ball, Eva M. Barea et al.

Nano Letters 10.1021/nl403997a
[48]
CH3NH3PbI3 Perovskite/Fullerene Planar‐Heterojunction Hybrid Solar Cells

Jun‐Yuan Jeng, Yi‐Fang Chiang, Mu‐Huan Lee et al.

Advanced Materials 10.1002/adma.201301327

Showing 50 of 101 references

Cited By
1,451
Solar Energy
International Journal of Photoenerg...
Nature Reviews Materials
Journal of Materials Chemistry A
Metrics
1,451
Citations
101
References
Details
Published
Oct 30, 2014
Vol/Issue
11(1)
Pages
10-25
License
View
Cite This Article
Hyun Suk Jung (2014). Perovskite Solar Cells: From Materials to Devices. Small, 11(1), 10-25. https://doi.org/10.1002/smll.201402767
Related

You May Also Like

Effect of Surface Properties on Nanoparticle–Cell Interactions

Ayush Verma, Francesco Stellacci · 2009

2,320 citations

Optical Properties of ZnO Nanostructures

Aleksandra B. Djurišić, Yu Hang Leung · 2006

1,765 citations

Chemically Functionalized Carbon Nanotubes

Kannan Balasubramanian, Marko Burghard · 2004

1,562 citations

Nanoscale Forces and Their Uses in Self‐Assembly

Kyle J. M. Bishop, Christopher E. Wilmer · 2009

1,416 citations