Advances in regulating the electron spin effect toward electrocatalysis applications

Liu Lin; Peiyuan Su; Yiting Han; Yunming Xu; Qiao Ni; Xinyue Zhang; Peixun Xiong; Zemin Sun; Genban Sun

doi:10.1016/j.esci.2024.100264

journal article Open Access Jan 01, 2025

Advances in regulating the electron spin effect toward electrocatalysis applications

Liu Lin

Peiyuan Su Yiting Han Yunming Xu Qiao Ni

eScience Vol. 5 No. 1 pp. 100264 · Elsevier BV

View at Publisher Save 10.1016/j.esci.2024.100264

Topics

No keywords indexed for this article. Browse by subject →

References

136

[1]

Goldthau "Energy crisis: five questions that must be answered in 2023" Nature (2022) 10.1038/d41586-022-04467-w

[2]

Zhu "Continuous carbon capture in an electrochemical solid-electrolyte reactor" Nature (2023) 10.1038/s41586-023-06060-1

[3]

Wu "Nitrogen-rich carbonaceous materials for advanced oxygen electrocatalysis: synthesis, characterization, and activity of nitrogen sites" Adv. Funct. Mater. (2022) 10.1002/adfm.202204137

[4]

Zhao "An efficient direct ammonia fuel cell for affordable carbon-neutral transportation" Joule (2019) 10.1016/j.joule.2019.07.005

[5]

Huang "Highly efficient oxygen evolution reaction enabled by phosphorus doping of the Fe electronic structure in iron-nickel selenide nanosheets" Adv. Sci. (2021) 10.1002/advs.202101775

[6]

Kamat "Acid anion electrolyte effects on platinum for oxygen and hydrogen electrocatalysis" Commun. Chem. (2022) 10.1038/s42004-022-00635-1

[7]

Li "Metalloporphyrins as catalytic models for studying hydrogen and oxygen evolution and oxygen reduction reactions" Acc. Chem. Res. (2022) 10.1021/acs.accounts.1c00753

[8]

Quílez-Bermejo "Advanced design of metal nanoclusters and single atoms embedded in C1N1-derived carbon materials for ORR, HER, and OER" Adv. Funct. Mater. (2023) 10.1002/adfm.202300405

[9]

Lei "High-entropy single-atom activated carbon catalysts for sustainable oxygen electrocatalysis" Nat. Sustain. (2023) 10.1038/s41893-023-01101-z

[10]

Ni "Regulating electrocatalytic oxygen reduction activity of a metal coordination polymer via d-π conjugation" Angew. Chem. Int. Ed. (2021) 10.1002/anie.202104494

[11]

Wang "Electronic structure regulation of noble metal-free materials toward alkaline oxygen electrocatalysis" eScience (2023) 10.1016/j.esci.2023.100141

[12]

Huang "Electronic structure regulation and polysulfide bonding of Co-doped (Ni, Fe)1+xS enable highly efficient and stable electrocatalytic overall water splitting" Chem. Eng. J. (2022) 10.1016/j.cej.2022.136121

[13]

Jiang "Boosting the stability of oxygen vacancies in α-Co(OH)2 nanosheets with coordination polyhedrons as rivets for high-performance alkaline hydrogen evolution electrocatalyst" Adv. Energy Mater. (2022) 10.1002/aenm.202202351

[14]

Chandrasekaran "Mutual self-regulation of d-electrons of single atoms and adjacent nanoparticles for bifunctional oxygen electrocatalysis and rechargeable zinc-air batteries" Nano-Micro Lett. (2023) 10.1007/s40820-023-01022-8

[15]

Wu "Coadsorption of NRR and HER intermediates determines the performance of Ru–N4 toward electrocatalytic N2 reduction" ACS Catal. (2022) 10.1021/acscatal.1c05820

[16]

Kim "Alloy nanocatalysts for the electrochemical oxygen reduction (ORR) and the direct electrochemical carbon dioxide reduction reaction (CO2RR)" Adv. Mater. (2019)

[17]

Zhu "Application of in situ techniques for the characterization of NiFe-based oxygen evolution reaction (OER) electrocatalysts" Angew. Chem. Int. Ed. (2019) 10.1002/anie.201802923

[18]

Li "Surface carbon layer controllable Ni3Fe particles confined in hierarchical N-doped carbon framework boosting oxygen evolution reaction" Adv. Powder Mater. (2022)

[19]

Huan "Disordered rocksalts with lattice oxygen activation as efficient oxygen evolution electrocatalysts" Trans. Tianjin Univ. (2023) 10.1007/s12209-023-00363-0

[20]

Huang "Precisely engineering the electronic structure of active sites boosts the activity of iron-nickel selenide on nickel foam for highly efficient and stable overall water splitting" Appl. Catal. B Environ. (2021) 10.1016/j.apcatb.2021.120678

[21]

Huang "Electronic structure regulation and surface reconstruction of iron diselenide for enhanced oxygen evolution activity" Small (2023) 10.1002/smll.202302970

[22]

Yin "Revealing the in situ evolution of tetrahedral NiMoO4 micropillar array for energy-efficient alkaline hydrogen production assisted by urea electrolysis" Small Struct. (2023) 10.1002/sstr.202300028

[23]

Mei "Mechanistic and kinetic implications on the ORR on a Au(100) electrode: pH, temperature and H-D kinetic isotope effects" Phys. Chem. Chem. Phys. (2014) 10.1039/c4cp00257a

[24]

Masa "Ultrathin high surface area nickel boride (NixB) nanosheets as highly efficient electrocatalyst for oxygen evolution" Adv. Energy Mater. (2017) 10.1002/aenm.201700381

[25]

Bie "Challenges for photocatalytic overall water splitting" Chem (2022) 10.1016/j.chempr.2022.04.013

[26]

Sun "Regulating the spin state of Fe(III) enhances the magnetic effect of the molecular catalysis mechanism" J. Am. Chem. Soc. (2022) 10.1021/jacs.2c01153

[27]

Orbital Occupancy and Spin Polarization: From Mechanistic Study to Rational Design of Transition Metal-Based Electrocatalysts toward Energy Applications

Viet-Hung Do

ACS Nano 2022 10.1021/acsnano.2c08919

[28]

Khavryuchenko "Spin catalysts: a quantum trigger for chemical reactions" Chin. J. Catal. (2015) 10.1016/s1872-2067(15)60948-2

[29]

Lustig "The life and times of Werner Heisenberg" Phys. Perspect. (2010) 10.1007/s00016-010-0034-5

[30]

Sreenivasan "Luminescent nanoparticles and their applications in the life sciences" J. Phys. Condens. Matter (2013) 10.1088/0953-8984/25/19/194101

[31]

Mondal "Long-range spin-selective transport in chiral metal-organic crystals with temperature-activated magnetization" ACS Nano (2020) 10.1021/acsnano.0c07569

[32]

Lampe "Spin physics and polarized structure functions" Phys. Rep. (2000) 10.1016/s0370-1573(99)00100-3

[33]

Franzoni "Long-lived 1H singlet spin states originating from para-hydrogen in Cs-symmetric molecules stored for minutes in high magnetic fields" J. Am. Chem. Soc. (2012) 10.1021/ja304285s

[34]

Ge "Ferromagnetic-antiferromagnetic coupling core-shell nanoparticles with spin conservation for water oxidation" Adv. Mater. (2021) 10.1002/adma.202101091

[35]

Wang "Tuning Fe spin moment in Fe–N–C catalysts to climb the activity volcano via a local geometric distortion strategy" Adv. Sci. (2022)

[36]

Liu "Tuning the spin state of the iron center by bridge-bonded Fe–O–Ti ligands for enhanced oxygen reduction" Angew. Chem. Int. Ed. (2022)

[37]

Liu "Regulating the charge and spin ordering of two-dimensional ultrathin solids for electrocatalytic water splitting" Chem (2018) 10.1016/j.chempr.2018.02.006

[38]

Zhang "Surface spintronics enhanced photo-catalytic hydrogen evolution: mechanisms, strategies, challenges and future" Appl. Surf. Sci. (2018) 10.1016/j.apsusc.2017.10.228

[39]

Zhou "Discovery of quantitative electronic structure-OER activity relationship in metal-organic framework electrocatalysts using an integrated theoretical-experimental approach" Adv. Funct. Mater. (2021) 10.1002/adfm.202102066

[40]

Zhang "Regulating spin states in oxygen electrocatalysis" Angew. Chem. Int. Ed. (2023)

[41]

Li "Function of electron spin effect in electrocatalysts" Acta Phys. Chim. Sin. (2023)

[42]

Wang "Boosting nitrogen reduction to ammonia on FeN4 sites by atomic spin regulation" Adv. Sci. (2021) 10.1002/advs.202102915

[43]

Liu "Heterogeneous spin states in ultrathin nanosheets induce subtle lattice distortion to trigger efficient hydrogen evolution" J. Am. Chem. Soc. (2016) 10.1021/jacs.6b00858

[44]

Spin-Polarized Photocatalytic CO2 Reduction of Mn-Doped Perovskite Nanoplates

Cheng-Chieh Lin, Ting-Ran Liu, Sin-Rong Lin et al.

Journal of the American Chemical Society 2022 10.1021/jacs.2c06060

[45]

Sun "Engineering high-spin state cobalt cations in spinel zinc cobalt oxide for spin channel propagation and active site enhancement in water oxidation" Angew. Chem. Int. Ed. (2021) 10.1002/anie.202102452

[46]

Zhang "High spin polarization ultrafine Rh nanoparticles on CNT for efficient electrochemical N2 fixation to ammonia" Appl. Catal. B Environ. (2021) 10.1016/j.apcatb.2021.120592

[47]

Lin "Revealing spin magnetic effect of iron-group layered double hydroxides with enhanced oxygen catalysis" ACS Catal. (2023) 10.1021/acscatal.2c04983

[48]

Tuning the Spin Density of Cobalt Single-Atom Catalysts for Efficient Oxygen Evolution

Zejun Li, Zeyu Wang, Shibo Xi et al.

ACS Nano 2021 10.1021/acsnano.1c00251

[49]

Li "A durable half-metallic diatomic catalyst for efficient oxygen reduction" Energy Environ. Sci. (2022) 10.1039/d1ee03194e

[50]

Sun "Spin-related electron transfer and orbital interactions in oxygen electrocatalysis" Adv. Mater. (2020) 10.1002/adma.202003297

Showing 50 of 136 references

Cited By

76

d-orbital hybridization in transition metal electrocatalysts: Correlating electronic structure with catalytic performance

Xinyu Wang, Sichen Huo · 2026

Materials Science and Engineering:...

Fe2O3/V-TiO2 catalyst with high spin state Fe3+ for enhanced selective oxidation of glycerol to glycolic acid

Yaqian Li, Mingyue Zhao · 2026

Chemical Engineering Science

Magnetic Field‐Driven Spin State Transformation in Promoting the Catalytic Activity of Doped Single‐Atom for Hydrogen Evolution Reaction

Chenjing Wang, Yuquan Yang · 2025

Advanced Materials

Spin‐State Regulation of Single‐Atom Catalysts: From Quantum Mechanisms to Multidimensional Dynamic Regulation Strategies

Fei Wang, Qidi Su · 2025

Advanced Functional Materials

Metrics

76

Citations

136

References

Details

Published: Jan 01, 2025
Vol/Issue: 5(1)
Pages: 100264
License: View

Authors

L

Liu Lin

Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Renewable Energy Conversion and Storage Center (RECAST) College of Chemistry Nankai University Tianjin 300071 China

Inorganic Chemistry I, Technische Universität Dresden, Bergstrasse 66, 01069 Dresden, Germany

Cite This Article

Liu Lin, Peiyuan Su, Yiting Han, et al. (2025). Advances in regulating the electron spin effect toward electrocatalysis applications. eScience, 5(1), 100264. https://doi.org/10.1016/j.esci.2024.100264

Advances in regulating the electron spin effect toward electrocatalysis applications

You May Also Like