Notable catalytic activity of Al–Cu–Fe–Ni–Cr high entropy alloy nanoparticles for hydrogen sorption in MgH2

Yogesh Kumar Yadav; Mohammad Abu Shaz; Thakur Prasad Yadav

doi:10.1016/j.ijhydene.2025.02.361

journal article Jun 01, 2025

Notable catalytic activity of Al–Cu–Fe–Ni–Cr high entropy alloy nanoparticles for hydrogen sorption in MgH2

Yogesh Kumar Yadav

Mohammad Abu Shaz Thakur Prasad Yadav

International Journal of Hydrogen Energy Vol. 141 pp. 935-945 · Elsevier BV

View at Publisher Save 10.1016/j.ijhydene.2025.02.361

Topics

No keywords indexed for this article. Browse by subject →

References

62

[1]

Climate Extremes and Compound Hazards in a Warming World

Amir AghaKouchak, Felicia Chiang, Laurie S. Huning et al.

Annual Review of Earth and Planetary Sciences 2020 10.1146/annurev-earth-071719-055228

[2]

Crok (2023)

[3]

Debebe "An overview of climate change mitigation, mitigation strategies, and technologies to reduce atmospheric greenhouse gas concentrations: a review" Envi Scie Res & Rev (2023)

[4]

Attfield "Global warming, air pollution, Health and medical education" Center for Ecology and Ecophilosophy (2024)

[5]

Winter "A historical perspective review of the environmental pollution" Science Insights (2024) 10.15354/si.24.re916

[6]

Aravindan "Fuelling the future: a review of non-renewable hydrogen production and storage techniques" Renew Sustain Energy Rev (2023)

[7]

Yadav "Storage of hydrogen in solid-state materials, book; hydrogen energy" (2024)

[8]

Srivastava "Hydrogen energy in India: storage to application" Proc Indian Natl Sci Acad (2015) 10.16943/ptinsa/2015/v81i4/48303

[9]

Verma "Enhanced hydrogen absorption and desorption properties of MgH2 with graphene and vanadium disulfide" Int J Hydrogen Energy (2023) 10.1016/j.ijhydene.2021.12.269

[10]

Pandey "Catalytic characteristics of titanium‐(IV)‐isopropoxide (TTIP) on de/re‐hydrogenation of wet ball‐milled MgH2/Mg" Int J Energy Res (2022) 10.1002/er.8427

[11]

Liang "Catalytic effect of transition metals on hydrogen sorption in nanocrystalline ball milled MgH2–Tm (Tm= Ti, V, Mn, Fe and Ni) systems" J Alloys Compd (1999) 10.1016/s0925-8388(99)00442-9

[12]

Zhou "Effect of Ti intermetallic catalysts on hydrogen storage properties of magnesium hydride" J Phys Chem C (2013) 10.1021/jp402770p

[13]

Cermak "Catalytic effect of Ni, Mg2Ni and Mg2NiH4 upon hydrogen desorption from MgH2" Int J Hydrogen Energy (2011) 10.1016/j.ijhydene.2011.07.133

[14]

Berezovets "Effect of Ti-based nanosized additives on the hydrogen storage properties of MgH2" Int J Hydrogen Energy (2022) 10.1016/j.ijhydene.2021.03.019

[15]

Pandey "Curious catalytic characteristics of Al–Cu–Fe quasicrystal for de/rehydrogenation of MgH2" J Phys Chem C (2017) 10.1021/acs.jpcc.7b07336

[16]

Gupta "Enhanced hydrogen storage in Mg catalysed by Cu–Ni–Co–Fe quaternary multi-component alloy" Int J Hydrogen Energy (2024) 10.1016/j.ijhydene.2023.08.243

[17]

Kumar "Hydrogen storage in high entropy alloys" (2024)

[18]

Yang "Recent progress on the development of high entropy alloys (HEAs) for solid hydrogen storage: a review" Int J Hydrogen Energy (2022) 10.1016/j.ijhydene.2022.01.141

[19]

Nanostructured High‐Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes

J.‐W. Yeh, S.‐K. Chen, S.‐J. Lin et al.

Advanced Engineering Materials 2004 10.1002/adem.200300567

[20]

Microstructural development in equiatomic multicomponent alloys

B. Cantor, I.T.H. Chang, P. Knight et al.

Materials Science and Engineering: A 2004 10.1016/j.msea.2003.10.257

[21]

Zhang "Microstructures and properties of high-entropy alloys" Prog Mater Sci (2014) 10.1016/j.pmatsci.2013.10.001

[22]

Murty (2014)

[23]

Ranganathan "Alloyed pleasures: multimetallic cocktails" Curr Sci (2003)

[24]

Wang "An effective PtPdAuCuFe/C high-entropy-alloy applied to direct ethylene glycol fuel cells" J Taiwan Inst Chem Eng (2023) 10.1016/j.jtice.2023.104714

[25]

Edalati "Reversible room temperature hydrogen storage in high-entropy alloy TiZrCrMnFeNi" Scr Mater (2020) 10.1016/j.scriptamat.2019.12.009

[26]

Floriano "Hydrogen storage properties of new A3B2-type TiZrNbCrFe high-entropy alloy" Int J Hydrogen Energy (2021) 10.1016/j.ijhydene.2021.04.181

[27]

Kumar "Notable hydrogen storage in Ti–Zr–V–Cr–Ni high entropy alloy" Int J Hydrogen Energy (2022) 10.1016/j.ijhydene.2022.05.107

[28]

Wei "(TiVZrNb) 83Cr17 high-entropy alloy as catalyst for hydrogen storage in MgH2" Chem Eng J (2023) 10.1016/j.cej.2023.146639

[29]

Wan "Enhancing hydrogen storage properties of MgH2 using FeCoNiCrMn high entropy alloy catalysts" J Mater Sci Technol (2023) 10.1016/j.jmst.2022.11.033

[30]

Verma "Superior catalytic action of high-entropy alloy on hydrogen sorption properties of MgH2" Int J Hydrogen Energy (2024) 10.1016/j.ijhydene.2023.08.127

[31]

Zhong "FeCoNiCrMo high entropy alloy nanosheets catalyzed magnesium hydride for solid-state hydrogen storage" Int J Miner Metall Mater (2023) 10.1007/s12613-023-2669-7

[32]

Song "Optimizing FeCoNiCrTi high-entropy alloy with hydrogen pumping effect to boost de/hydrogenation performance of magnesium hydride" Rare Met (2024)

[33]

Yadav "Nanocrystalline intermetallics in Al-Cu-Fe-Cr decagonal quasicrystalline alloy" Mater Manuf Process (2012) 10.1080/10426914.2011.593246

[34]

Agarwal "Dielectric response and alternating current conductivity in (Co,Ni)Al2O4 nano-spinel" Ceram Int (2017) 10.1016/j.ceramint.2017.09.106

[35]

Mishra "Synthesis and characterization of hexanary Ti–Zr–V–Cr–Ni–Fe high-entropy Laves phase" J Mater Res (2019) 10.1557/jmr.2018.502

[36]

Yadav "Liquid exfoliation of icosahedral quasicrystals" Adv Funct Mater (2018) 10.1002/adfm.201801181

[37]

Yadav "Extraction of two-dimensional aluminum alloys from decagonal quasicrystals" ACS Nano (2020) 10.1021/acsnano.0c03081

[38]

Soroka "Cuprous hydroxide in a solid form: does it exist?" Dalton Trans (2013) 10.1039/c3dt50351h

[39]

Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn

Mark C. Biesinger, Leo W.M. Lau, Andrea R. Gerson et al.

Applied Surface Science 2010 10.1016/j.apsusc.2010.07.086

[40]

Poreddy "Copper oxide as efficient catalyst for oxidative dehydrogenation of alcohols with air" Catal Sci Technol (2015) 10.1039/c4cy01622j

[41]

Wang "Study of the surface oxides and corrosion behaviour of an equiatomic CoCrFeMnNi high entropy alloy by XPS and ToF-SIMS" Corros Sci (2020) 10.1016/j.corsci.2020.108507

[42]

Dai "Novel and promising electrocatalyst for oxygen evolution reaction based on MnFeCoNi high entropy alloy" J Power Sources (2019) 10.1016/j.jpowsour.2019.05.030

[43]

Yao "Nanoporous surface high‐entropy alloys as highly efficient multisite electrocatalysts for nonacidic hydrogen evolution reaction" Adv Funct Mater (2021) 10.1002/adfm.202009613

[44]

Zhang "Investigation on the activation mechanism of hydrogen absorption in TiZrNbTa high entropy alloy" J Alloys Compd (2019) 10.1016/j.jallcom.2018.12.120

[45]

Jia "DIET-like and MIET-like mutualism of S. oneidensis MR-1 and metal-reducing function microflora boosts Cr (VI) reduction" J Hazard Mater (2024) 10.1016/j.jhazmat.2023.133401

[46]

Wu "On the electronic structure and hydrogen evolution reaction activity of platinum group metal-based high-entropy-alloy nanoparticles" Chem Sci (2020) 10.1039/d0sc02351e

[47]

Feng "CoNiCuMgZn high entropy alloy nanoparticles embedded onto graphene sheets via anchoring and alloying strategy as efficient electrocatalysts for hydrogen evolution reaction" Chem Eng J (2022) 10.1016/j.cej.2021.132883

[48]

Pandey "Curious catalytic characteristics of Al–Cu–Fe quasicrystal for de/rehydrogenation of MgH2" J Phys Chem C (2017) 10.1021/acs.jpcc.7b07336

[49]

Verma "Introducing 2D layered WS2 and MoS2 as an active catalyst to enhance the hydrogen storage properties of MgH2" Int J Hydrogen Energy (2024) 10.1016/j.ijhydene.2024.09.094

[50]

Zhu "Thermodynamic tuning of Mg-based hydrogen storage alloys: a review" Materials (2013) 10.3390/ma6104654

Showing 50 of 62 references

Cited By

29

Detailed microstructural analysis and hydrogenation performance of ball-milled nanocrystalline MgH2 powders co-catalyzed by FeTiH2 and GO

Roman Paramonov, Gábor Ribárik · 2026

Journal of Alloys and Compounds

Metrics

29

Citations

62

References

Details

Published: Jun 01, 2025
Vol/Issue: 141
Pages: 935-945
License: View

Authors

Funding

University Grants Commission

Council of Science and Technology, U.P. Award: CST /d-833

Cite This Article

Yogesh Kumar Yadav, Mohammad Abu Shaz, Thakur Prasad Yadav (2025). Notable catalytic activity of Al–Cu–Fe–Ni–Cr high entropy alloy nanoparticles for hydrogen sorption in MgH2. International Journal of Hydrogen Energy, 141, 935-945. https://doi.org/10.1016/j.ijhydene.2025.02.361

Notable catalytic activity of Al–Cu–Fe–Ni–Cr high entropy alloy nanoparticles for hydrogen sorption in MgH2

You May Also Like