Coke formation on different metal-modified (Co, Mo and Zr) ZSM-5 in the catalytic pyrolysis of cellulose to light aromatics

Nai-Yu Yao; Jing-Pei Cao; Xiao-Yan Zhao; Xin-Bo Pang; Jing-Ping Zhao; Chen-Xu Chen; Shi-Jie Cai; Xiao-bo FENG; Duc Dung Le

doi:10.1016/j.jaap.2024.106516

journal article May 01, 2024

Coke formation on different metal-modified (Co, Mo and Zr) ZSM-5 in the catalytic pyrolysis of cellulose to light aromatics

Nai-Yu Yao Jing-Pei Cao

Xiao-Yan Zhao

Xin-Bo Pang Jing-Ping Zhao Chen-Xu Chen Shi-Jie Cai Xiao-bo FENG Duc Dung Le

Journal of Analytical and Applied Pyrolysis Vol. 179 pp. 106516 · Elsevier BV

View at Publisher Save 10.1016/j.jaap.2024.106516

Topics

No keywords indexed for this article. Browse by subject →

References

54

[1]

Guo "Enhancing high selectivity production of light aromatics from in-situ catalytic upgrading of cellulose pyrolysis vapors by regulating hierarchical core-shell ZSM-5@MCM-41" J. Anal. Appl. Pyrolysis (2022) 10.1016/j.jaap.2022.105774

[2]

Ren "Catalytic conversion of coal and biomass volatiles: a review" Energy Fuels (2020) 10.1021/acs.energyfuels.0c01432

[3]

Mishra "Catalytic pyrolysis of biomass over zeolites for bio-oil and chemical production: a review on their structure, porosity and acidity co-relation" Bioresour. Technol. (2022) 10.1016/j.biortech.2022.128189

[4]

Wang "Enhancement of light aromatics from catalytic fast pyrolysis of cellulose over bifunctional hierarchical HZSM-5 modified by hydrogen fluoride and nickel/hydrogen fluoride" Bioresour. Technol. (2019) 10.1016/j.biortech.2019.01.059

[5]

Ke "Lignocellulosic biomass pyrolysis for aromatic hydrocarbons production Pre and in-process enhancement methods" Renew. Sustain. Energy Rev. (2022) 10.1016/j.rser.2022.112607

[6]

Zhao "Catalytic reforming of lignite pyrolysis volatiles over sulfated HZSM-5: significance of the introduced extra-framework Al species" Fuel (2020) 10.1016/j.fuel.2020.117789

[7]

Wang "In situ upgrading of cellulose pyrolysis volatiles using hydrofluorinated and platinum-loaded HZSM‑5 for high selectivity production of light aromatics" Ind. Eng. Chem. Res. (2019) 10.1021/acs.iecr.9b04549

[8]

Gu "Catalytic fast pyrolysis of sewage sludge over HZSM-5 a study of light aromatics, coke, and nitrogen migration under different atmospheres" Ind. Eng. Chem. Res. (2020) 10.1021/acs.iecr.0c01170

[9]

Liu "Effect of zeolite structure on light aromatics formation during upgrading of cellulose fast pyrolysis vapor" J. Energy Inst. (2019) 10.1016/j.joei.2018.07.017

[10]

Zhao "Sulfation-acidified HZSM-5 catalyst for in-situ catalytic conversion of lignite pyrolysis volatiles to light aromatic" Fuel (2019) 10.1016/j.fuel.2019.115784

[11]

Iliopoulou "Catalytic upgrading of biomass pyrolysis vapors using transition metal-modified ZSM-5 zeolite" Appl. Catal. B: Environ. (2012) 10.1016/j.apcatb.2012.08.030

[12]

Sun "Catalytic fast pyrolysis of biomass into aromatic hydrocarbons over Mo-modified ZSM-5 catalysts" Catalysts (2020) 10.3390/catal10091051

[13]

Iliopoulou "Pilot-scale validation of Co-ZSM-5 catalyst performance in the catalytic upgrading of biomass pyrolysis vapours" Green. Chem. (2014) 10.1039/c3gc41575a

[14]

Xie "Ex-situ catalytic microwave pyrolysis of lignin over Co/ZSM-5 to upgrade bio-oil" J. Anal. Appl. Pyrolysis (2018) 10.1016/j.jaap.2018.03.003

[15]

Jin "Integrated coal pyrolysis with methane aromatization over Mo/HZSM-5 for improving tar yield" Fuel (2013) 10.1016/j.fuel.2012.01.024

[16]

Li "Improving aromatic hydrocarbons yield from coal pyrolysis volatile products over HZSM-5 and Mo-modified HZSM-5" Fuel (2014) 10.1016/j.fuel.2014.04.027

[17]

Xue "Product regulation and catalyst deactivation during ex-situ catalytic fast pyrolysis of biomass over Nickel-Molybdenum bimetallic modified micro-mesoporous zeolites and clays" Bioresour. Technol. (2022) 10.1016/j.biortech.2022.128081

[18]

Wei "Hierarchical gallium-modified ZSM-5@SBA-15 for the catalytic pyrolysis of biomass into hydrocarbons" Renew. Energy (2022) 10.1016/j.renene.2022.10.047

[19]

Shang "Regulating light olefins or aromatics production in ex-situ catalytic pyrolysis of biomass by engineering the structure of tin modified ZSM-5 catalyst" Bioresour. Technol. (2021) 10.1016/j.biortech.2021.124975

[20]

Mortensen "A review of catalytic upgrading of bio-oil to engine fuels" Appl. Catal. A: Gen. (2011) 10.1016/j.apcata.2011.08.046

[21]

Valle "Deactivating species in the transformation of crude bio-oil with methanol into hydrocarbons on a HZSM-5 catalyst" J. Catal. (2012) 10.1016/j.jcat.2011.10.004

[22]

Du "Coke formation of model compounds relevant to pyrolysis bio-oil over ZSM-5" Appl. Catal. A: Gen. (2016) 10.1016/j.apcata.2015.12.022

[23]

Cheng "Chemistry of furan conversion into aromatics and olefins over HZSM-5: a model biomass conversion reaction, ACS" Catalysis (2011)

[24]

Zhao "Catalytic upgrading of lignite pyrolysis volatiles to aromatics over urea-modified HZSM-5: study on desilication of preserved micropores" Energy Fuels (2023) 10.1021/acs.energyfuels.3c00322

[25]

Yao "Efficient and selective catalytic pyrolysis of cellulose to monocyclic aromatic hydrocarbons over Zn-containing HZSM-5" Fuel (2022) 10.1016/j.fuel.2021.122437

[26]

Ren "Catalytic upgrading of pyrolysis vapors from lignite over mono/bimetal-loaded mesoporous HZSM-5" Fuel (2018) 10.1016/j.fuel.2018.01.017

[27]

Lu "Selective preparation of monocyclic aromatic hydrocarbons from catalytic cracking of biomass fast pyrolysis vapors over Mo2N/HZSM-5 catalyst" Fuel Process. Technol. (2018) 10.1016/j.fuproc.2018.01.017

[28]

Su "Creating mesopores in ZSM-5 zeolite by alkali treatment a new way to enhance the catalytic performance of methane dehydroaromatization on Mo/HZSM-5 catalysts" Catal. Lett. (2003) 10.1023/b:catl.0000007149.48132.5a

[29]

Zhu "Kinetic models for the coke combustion on deactivated ZSM-5/MOR derived from n-heptane cracking" Ind. Eng. Chem. Res. (2010) 10.1021/ie900855y

[30]

Al-Shathr "Experimental and kinetic studies of the advantages of coke accumulation over Beta and Mordenite catalysts according to the pore mouth catalysis hypothesis" Catal. Commun. (2023) 10.1016/j.catcom.2023.106718

[31]

Pu "Highly active Nd-promoted Ni@Al2O3 core-shell catalyst for steam reforming of acetic acid: insights of the remarkable coke resistance" Int. J. Hydrog. Energy (2021) 10.1016/j.ijhydene.2021.08.238

[32]

Valle "Steam reforming of raw bio-oil over Ni/La2O3-αAl2O3: influence of temperature on product yields and catalyst deactivation" Fuel (2018) 10.1016/j.fuel.2017.11.149

[33]

Huang "Catalytic performances of Ni/mesoporous SiO2 catalysts for dry reforming of methane to hydrogen" J. Energy Chem. (2016) 10.1016/j.jechem.2016.03.004

[34]

Liu "Promotional role of water added to methane feed on catalytic performance in the methane dehydroaromatization reaction on Mo/HZSM-5 catalyst" J. Catal. (2003) 10.1016/s0021-9517(03)00236-7

[35]

Li "Structure and acidity of Mo/ZSM-5 synthesized by solid state reaction for methane dehydrogenation and aromatization" Microporous Mesoporous Mater. (2006) 10.1016/j.micromeso.2005.09.016

[36]

Alvarez "Structural changes on deactivation of ZSM-5. A study by X-ray powder diffraction" Mater. Chem. Phys. (1992) 10.1016/0254-0584(92)90269-e

[37]

Nishu "Deactivation mechanism and regeneration effect of bi-metallic Fe-Ni ZSM-5 catalyst during biomass catalytic pyrolysis" Fuel (2022)

[38]

Xu "Deactivation of multilayered MFI nanosheet zeolite during upgrading of biomass pyrolysis vapors" ACS Sustain. Chem. Eng. (2017) 10.1021/acssuschemeng.7b00817

[39]

Hernando "Engineering the acidity and accessibility of the zeolite ZSM-5 for efficient bio-oil upgrading in catalytic pyrolysis of lignocellulose" Green. Chem. (2018) 10.1039/c8gc01722k

[40]

Qiao "Synthesis and physicochemical characterization of hierarchical ZSM-5: effect of organosilanes on the catalyst properties and performance in the catalytic fast pyrolysis of biomass" Microporous Mesoporous Mater. (2019) 10.1016/j.micromeso.2018.07.028

[41]

Zhang "Coking and deactivation of boron modified Al-MCM-41 for vapor-phase Beckmann rearrangement reaction" J. Mol. Catal. A: Chem. (2013) 10.1016/j.molcata.2012.09.021

[42]

Montero "Monitoring Ni0 and coke evolution during the deactivation of a Ni/La2O3-αAl2O3 catalyst in ethanol steam reforming in a fluidized bed" J. Catal. (2015) 10.1016/j.jcat.2015.08.005

[43]

Coke Formation on Pt–Sn/Al2O3 Catalyst for Propane Dehydrogenation

Hai-Zhi Wang, Li-li Sun, Zhi-Jun Sui et al.

Industrial & Engineering Chemistry Research 2018 10.1021/acs.iecr.8b01313

[44]

Vicente "Coke deactivation of Ni and Co catalysts in ethanol steam reforming at mild temperatures in a fluidized bed reactor" Int. J. Hydrog. Energy (2014) 10.1016/j.ijhydene.2014.06.093

[45]

Zhang "Characterization of coke deposition in the catalytic fast pyrolysis of biomass derivates" Energy Fuels (2013) 10.1021/ef401458y

[46]

Ochoa "Role of oxygenates and effect of operating conditions in the deactivation of a Ni supported catalyst during the steam reforming of bio-oil" Green. Chem. (2017) 10.1039/c7gc01432e

[47]

Gou "Coking and deactivation behavior of ZSM-5 during the isomerization of styrene oxide to phenylacetaldehyde" Catal. Commun. (2017) 10.1016/j.catcom.2017.04.035

[48]

FT-Raman spectroscopic study of the evolution of char structure during the pyrolysis of a Victorian brown coal

X Li, J HAYASHI, C LI

Fuel 2006 10.1016/j.fuel.2006.03.008

[49]

Xiong "Evolution of coke structures during the pyrolysis of bio-oil at various temperatures and heating rates" J. Anal. Appl. Pyrolysis (2018) 10.1016/j.jaap.2018.06.023

[50]

Tian "Effect of Ni-Co bimetallic core-shell catalyst for coke resistance in CO2 reforming of biomass Tar" J. Anal. Appl. Pyrolysis (2022) 10.1016/j.jaap.2022.105539

Showing 50 of 54 references

Cited By

23

Synergistic stabilization of nickel nanoparticles on dealuminated β-zeolite for high-efficiency H2-rich syngas production from biomass gasification

Ruiqiang Huo, Mingming Pei · 2026

Journal of the Energy Institute

Metrics

23

Citations

54

References

Details

Published: May 01, 2024
Vol/Issue: 179
Pages: 106516
License: View

Authors

Funding

National Natural Science Foundation of China Award: 22178374

Fundamental Research Funds for the Central Universities Award: 2021YCPY0201

Natural Science Foundation of Jiangsu Province Award: BK20200028

Ministry of Science and Technology Award: CHN/20

Cite This Article

Nai-Yu Yao, Jing-Pei Cao, Xiao-Yan Zhao, et al. (2024). Coke formation on different metal-modified (Co, Mo and Zr) ZSM-5 in the catalytic pyrolysis of cellulose to light aromatics. Journal of Analytical and Applied Pyrolysis, 179, 106516. https://doi.org/10.1016/j.jaap.2024.106516

Coke formation on different metal-modified (Co, Mo and Zr) ZSM-5 in the catalytic pyrolysis of cellulose to light aromatics

You May Also Like