Defluorination of Per- and Polyfluoroalkyl Substances (PFASs) with Hydrated Electrons: Structural Dependence and Implications to PFAS Remediation and Management

Vermont Department of Health. Health Department Updates Health Advisory for PFAS. http://www.healthvermont.gov/media/newsroom/updated-pfas-health-advisory-july-10-2018.

[6]

Massachusetts Department of Environmental Protection. MassDEP ORS Guideline for PFAS. https://www.mass.gov/files/documents/2018/06/11/orsg-pfas-20180608.pdf.

[7]

New Jersey Drinking Water Quality Institute. Maximum Contaminant Level Recommendations for Perfluorononanoic Acid in Drinking Water: Basis and Background. https://www.nj.gov/dep/watersupply/pdf/pfna-recommend-final.pdf.

[8]

North Carolina Department of Environmental Quality and North Carolina Department of Health and Human Services. Secretaries’ Science Advisory Board Review of the North Carolina Drinking Water Provisional Health Goal for GenX. https://files.nc.gov/ncdeq/GenX/SAB/SAB-GenX-Report-draft-08-29-2018.pdf.

[9]

10.1016/j.cej.2017.10.153

[10]

10.1089/ees.2016.0233

[11]

10.1016/j.watres.2013.10.045

[12]

Sorption of Poly- and Perfluoroalkyl Substances (PFASs) Relevant to Aqueous Film-Forming Foam (AFFF)-Impacted Groundwater by Biochars and Activated Carbon

Xin Xiao, Bridget A. Ulrich, Baoliang Chen et al.

Environmental Science & Technology 10.1021/acs.est.7b00970

[13]

10.1021/acs.est.8b01040

[14]

Efficient Electrochemical Oxidation of Perfluorooctanoate Using a Ti/SnO2-Sb-Bi Anode

Qiongfang Zhuo, Shubo Deng, Bo Yang et al.

Environmental Science & Technology 10.1021/es1024542

[15]

Electrochemical treatment of perfluorooctanoic acid and perfluorooctane sulfonate: Insights into mechanisms and application to groundwater treatment

Charles E. Schaefer, Christina Andaya, Aniela Burant et al.

Chemical Engineering Journal 10.1016/j.cej.2017.02.107

[16]

10.1021/acs.est.8b02726

[17]

Highly Efficient and Mild Electrochemical Mineralization of Long-Chain Perfluorocarboxylic Acids (C9–C10) by Ti/SnO2–Sb–Ce, Ti/SnO2–Sb/Ce–PbO2, and Ti/BDD Electrodes

Hui Lin, Junfeng Niu, Jiale Xu et al.

Environmental Science & Technology 10.1021/es4034414

[18]

10.1021/es040342v

[19]

10.1021/es902444r

[20]

10.1016/j.seppur.2017.11.009

[21]

10.1021/acs.estlett.8b00395

[22]

10.1021/es204279u

[23]

10.1021/ie1017496

[24]

10.1021/es400346n

[25]

10.1038/s41598-017-17515-7

[26]

10.1021/acs.est.6b04215

[27]

10.1038/srep07418

[28]

10.1002/rem.21555

[29]

10.1021/acs.est.6b05843

[30]

10.1021/acs.est.7b03994

[31]

10.1021/es403729e

[32]

10.1021/acs.est.7b02488

[33]

10.1021/acs.est.7b06657

[34]

10.1021/acs.est.8b03030

[35]

10.1021/acs.est.8b00544

[36]

10.1021/acs.estlett.5b00049

[37]

10.1021/acs.est.5b06237

[38]

10.1021/es302148z

[39]

10.1021/jp903003w

[40]

10.1021/jp807116q

[41]

10.1021/acs.est.8b02172

[42]

10.1021/acs.estlett.8b00122

[43]

10.1021/acs.est.7b03744

[44]

10.1021/acs.est.7b05960

[45]

10.1126/science.141.3583.805

[46]

10.1021/jp953236b

[47]

10.1016/j.jhazmat.2013.08.059

[48]

10.1038/srep32949

[49]

10.1021/acs.est.7b05912

[50]

10.1021/acs.est.6b03261

Showing 50 of 63 references

Cited By

550

Recent Advances in Photocatalytic Removal of Per- and Polyfluoroalkyl Substances Using Ceramic-based Materials

Ryung Gyo Kang, In-Young Jung · 2026

Ceramist

A stack capacitive deionization-resin hybrid system for the enrichment and sequential degradation of PFAS during groundwater desalination

Fuhao Zhou, Zhengheng Yang · 2026

Chemical Engineering Journal

Copper-Doped Zinc Sulfide Nanocrystals for Near-Ultraviolet and Visible-Light Driven Decomposition of Perfluoroalkyl Compounds

Yuto Toyota, Yusuke Sanada · 2026

ACS Applied Nano Materials

Enhanced photoreduction of perfluorooctane sulfonate via a confined nitrilotriacetic acid system augmented by CTAB

Zhenyu Zhai, Yunmeng Zhao · 2026

Journal of Hazardous Materials

PFAS Destruction and Near-Complete Defluorination of Undiluted Aqueous Film-Forming Foams at Ambient Conditions by Piezoelectric Ball Milling

Nanyang Yang, Yunqiao Guan · 2025

Environmental Science & Technol...

PFAS in the textile industry: Sources, fate, detection, and pathways toward sustainable remediation and regulation

Md. Nahid Pervez, Aswin Kumar Ilango · 2025

Chemical Engineering Journal

PFAS in landfill leachate: Practical considerations for treatment and characterization

Fabrizio Sabba, Christian Kassar · 2025

Journal of Hazardous Materials

Low-temperature, ambient-pressure and rapid mineralization of per- and polyfluoroalkyl substances by molten alkali

Huan Zhang, Timothy J. Strathmann · 2025

Journal of Hazardous Materials

Photocatalytic defluorination of perfluoroalkyl substances by surface-engineered ZnO nanocrystals

Shuhei Kanao, Mai Yamaguchi · 2025

Chemical Science

Perfluorobutanesulfonate (PFBS) Treatment by Electrical Discharge Plasma: Reaction Mechanisms and Degradation Pathways

Diana Aranzales, Osakpolo Isowamwen · 2025

ACS Omega

Optimization and Testing of an SPE-LC/q-TOF Analytical Method for the Detection of PFAS Degradation Products in Water Treatment Processes

Giulia Tomei, Elena Piva · 2025

Environmental Science & Technol...

Fluorine Substitution and CO2 Production in the Treatment of Perfluorooctanoic Acid in a Radial Plasma Discharge Reactor

Giulia Tomei, Mubbshir Saleem · 2025

Plasma Chemistry and Plasma Process...

Near-complete destruction of PFAS in aqueous film-forming foam by integrated photo-electrochemical processes

Yunqiao Guan, Zekun Liu · 2024

Nature Water

Overview of Per- and Polyfluoroalkyl Substances (PFAS), Their Applications, Sources, and Potential Impacts on Human Health

Zunaira Habib, Minkyung Song · 2024

Pollutants

Removal of per- and polyfluoroalkyl substances from water by plasma treatment: Insights into structural effects and underlying mechanisms

Han Zhang, Luxiang Zhu · 2024

Water Research

Current state of knowledge of environmental occurrence, toxic effects, and advanced treatment of PFOS and PFOA

Maria Antonopoulou, Alexandra Spyrou · 2024

Science of The Total Environment

Aerobic or anaerobic? Microbial degradation of per- and polyfluoroalkyl substances: A review

Qiuqi Niu, Xinrong Lin · 2024

Journal of Hazardous Materials

The untold story of PFAS alternatives: Insights into the occurrence, ecotoxicological impacts, and removal strategies in the aquatic environment

Naima Hamid, Muhammad Junaid · 2024

Water Research

Electrostatic Field in Contact‐Electro‐Catalysis Driven C−F Bond Cleavage of Perfluoroalkyl Substances

YANFENG WANG, Jing Zhang · 2024

Angewandte Chemie International Edi...

Aerobic Biotransformation and Defluorination of Fluoroalkylether Substances (ether PFAS): Substrate Specificity, Pathways, and Applications

Bosen Jin, Yiwen Zhu · 2023

Environmental Science & Technol...

Metrics

550

Citations

63

References

Details

Published: Mar 15, 2019
Vol/Issue: 53(7)
Pages: 3718-3728
License: View

Authors

M

Michael J. Bentel

Department of Chemical & Environmental Engineering and ‡Materials Science & Engineering Program, University of California, Riverside, California 92521, United States

Y

Yaochun Yu

Department of Civil & Environmental Engineering, ∥Metabolomics Lab of Roy J. Carver Biotechnology Center, and ⊥Institute for Genomic Biology, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States

L

Lihua Xu

Department of Chemical & Environmental Engineering and ‡Materials Science & Engineering Program, University of California, Riverside, California 92521, United States

Z

Zhong Li

DuPont Pharmaceuticals Company, Experimental Station, Wilmington, DE 19880-0500; and Structural Bioinformatics, 10929 Technology Place, San Diego, CA 92127

B

Bryan M. Wong

Department of Chemical & Environmental Engineering and ‡Materials Science & Engineering Program, University of California, Riverside, California 92521, United States

Y

Yujie Men

Department of Civil & Environmental Engineering, ∥Metabolomics Lab of Roy J. Carver Biotechnology Center, and ⊥Institute for Genomic Biology, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States

J

Jinyong Liu

Department of Chemical & Environmental Engineering and ‡Materials Science & Engineering Program, University of California, Riverside, California 92521, United States

Funding

National Science Foundation

Division of Chemistry Award: CHE-1709286

University of California, Riverside

Strategic Environmental Research and Development Program Award: ER-1497

Cite This Article

Michael J. Bentel, Yaochun Yu, Lihua Xu, et al. (2019). Defluorination of Per- and Polyfluoroalkyl Substances (PFASs) with Hydrated Electrons: Structural Dependence and Implications to PFAS Remediation and Management. Environmental Science & Technology, 53(7), 3718-3728. https://doi.org/10.1021/acs.est.8b06648

Defluorination of Per- and Polyfluoroalkyl Substances (PFASs) with Hydrated Electrons: Structural Dependence and Implications to PFAS Remediation and Management

You May Also Like