Outer-Coordination-Sphere Interaction in a Molecular Iron Catalyst Allows Selective Methane Production from Carbon Monoxide

Suman Patra; Sarmistha Bhunia; Soumili Ghosh; Abhishek Dey

doi:10.1021/acscatal.3c06112

journal article Apr 25, 2024

Outer-Coordination-Sphere Interaction in a Molecular Iron Catalyst Allows Selective Methane Production from Carbon Monoxide

Suman Patra

Sarmistha Bhunia Soumili Ghosh Abhishek Dey

ACS Catalysis Vol. 14 No. 10 pp. 7299-7307 · American Chemical Society (ACS)

View at Publisher Save 10.1021/acscatal.3c06112

Topics

No keywords indexed for this article. Browse by subject →

References

61

[1]

10.1016/j.coche.2013.03.005

[2]

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Jinli Qiao, Yuyu Liu, Feng Hong et al.

Chemical Society Reviews 10.1039/c3cs60323g

[3]

10.1038/526628a

[4]

10.1021/acs.accounts.1c00674

[5]

10.1021/ja4030148

[6]

10.1021/acs.accounts.5b00262

[7]

10.1038/ncomms3375

[8]

10.1002/anie.201204995

[9]

10.1021/acs.est.0c08237

[10]

10.1021/acs.est.0c05893

[11]

10.1002/cssc.201900915

[12]

CO2 hydrogenation to high-value products via heterogeneous catalysis

Run-Ping Ye, Jie Ding, Weibo Gong et al.

Nature Communications 10.1038/s41467-019-13638-9

[13]

10.1038/s41929-021-00694-y

[14]

10.1021/ic502675a

[15]

Visible-light-driven methane formation from CO2 with a molecular iron catalyst

Heng Rao, Luciana C. Schmidt, Julien Bonin et al.

Nature 10.1038/nature23016

[16]

Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center

Lingjing Chen, Zhenguo Guo, Xi-Guang Wei et al.

Journal of the American Chemical Society 10.1021/jacs.5b06535

[17]

A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst

Cyrille Costentin, Samuel Drouet, Marc Robert et al.

Science 10.1126/science.1224581

[18]

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

Iban Azcarate, Cyrille Costentin, Marc Robert et al.

Journal of the American Chemical Society 10.1021/jacs.6b07014

[19]

10.1021/jacs.6b06002

[20]

Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes

Kristian E. Dalle, Julien Warnan, Jane J. Leung et al.

Chemical Reviews 10.1021/acs.chemrev.8b00392

[21]

Molecular catalysis of CO2 reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes

E. Boutin, L. Merakeb, B. Boudy et al.

Chemical Society Reviews 10.1039/d0cs00218f

[22]

10.1021/ic3001619

[23]

10.1021/acs.inorgchem.8b00450

[24]

10.1021/jacs.5b12215

[25]

10.1021/acsenergylett.9b02093

[26]

Activating the Fe(I) State of Iron Porphyrinoid with Second-Sphere Proton Transfer Residues for Selective Reduction of CO2 to HCOOH via Fe(III/II)–COOH Intermediate(s)

Sk Amanullah, Paramita Saha, Abhishek Dey

Journal of the American Chemical Society 10.1021/jacs.1c04392

[27]

Molecular Electrochemical Reduction of CO2 beyond Two Electrons

Etienne Boutin, Marc Robert

Trends in Chemistry 10.1016/j.trechm.2021.02.003

[28]

10.1021/ja00544a035

[29]

10.1021/ja954326x

[30]

10.1021/ja508192y

[31]

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

Cyrille Costentin, Guillaume Passard, Marc Robert et al.

Journal of the American Chemical Society 10.1021/ja506193v

[32]

10.1073/pnas.1507063112

[33]

10.1021/jacs.5b05992

[34]

10.1002/cctc.202100625

[35]

10.1021/cs4002404

[36]

10.1038/nature13249

[37]

10.1021/ar50148a004

[38]

10.1021/jacs.9b00937

[39]

10.1021/acs.inorgchem.0c02579

[40]

Integrated molecular systems. Fixation of carbon monoxide on iron(I) in simple and superstructured porphyrins

Alain. Croisy, Doris. Lexa, Michel. Momenteau et al.

Organometallics 10.1021/om00128a016

[41]

Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins. Synergistic Effect of Lewis Acid Cations

Iqbal Bhugun, Doris Lexa, Jean-Michel Savéant

The Journal of Physical Chemistry 10.1021/jp9618486

[42]

10.1021/ja00090a068

[43]

10.1016/j.cattod.2017.02.028

[44]

10.1021/ja4074003

[45]

10.1038/ncomms9177

[46]

10.1021/acssuschemeng.0c02791

[47]

10.1021/ic00087a038

[48]

10.1039/ft9918702567

[49]

10.1021/jacs.8b02983

[50]

10.1021/jacs.6b11474

Showing 50 of 61 references

Metrics

22

Citations

61

References

Details

Published: Apr 25, 2024
Vol/Issue: 14(10)
Pages: 7299-7307
License: View

Authors

S

Suman Patra

School of Chemical Sciences Indian Association for the Cultivation of Science 2A & 2B, Raja SC Mullick Road, Kolkata, WB 700032, India

S

Sarmistha Bhunia

School of Chemical Sciences Indian Association for the Cultivation of Science 2A & 2B, Raja SC Mullick Road, Kolkata, WB 700032, India

S

Soumili Ghosh

School of Chemical Sciences Indian Association for the Cultivation of Science 2A & 2B, Raja SC Mullick Road, Kolkata, WB 700032, India

A

Abhishek Dey

School of Chemical Sciences Indian Association for the Cultivation of Science 2A & 2B, Raja SC Mullick Road, Kolkata, WB 700032, India

Funding

Science and Engineering Research Board Award: CRG/2021/000154

Council of Scientific and Industrial Research, India

Cite This Article

Suman Patra, Sarmistha Bhunia, Soumili Ghosh, et al. (2024). Outer-Coordination-Sphere Interaction in a Molecular Iron Catalyst Allows Selective Methane Production from Carbon Monoxide. ACS Catalysis, 14(10), 7299-7307. https://doi.org/10.1021/acscatal.3c06112

Outer-Coordination-Sphere Interaction in a Molecular Iron Catalyst Allows Selective Methane Production from Carbon Monoxide

You May Also Like