Enantioselective Synthesis of (E)-δ-Stannyl Homoallylic Alcohols via Aldehyde Allylboration Using α-Stannylallylboranes Generated by Allene Hydroboration Followed by a Highly Diastereoselective 1,3-Boratropic Shift

Ming Chen; Daniel H. Ess; William R. Roush

doi:10.1021/ja103041u

journal article May 24, 2010

Enantioselective Synthesis of (E)-δ-Stannyl Homoallylic Alcohols via Aldehyde Allylboration Using α-Stannylallylboranes Generated by Allene Hydroboration Followed by a Highly Diastereoselective 1,3-Boratropic Shift

Ming Chen

Daniel H. Ess

William R. Roush

Journal of the American Chemical Society Vol. 132 No. 23 pp. 7881-7883 · American Chemical Society (ACS)

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Details

Published: May 24, 2010
Vol/Issue: 132(23)
Pages: 7881-7883

Authors

M

Ming Chen

Department of Chemistry, Scripps Florida, Jupiter, Florida 33458

D

Daniel H. Ess

Department of Chemistry, Scripps Florida, Jupiter, Florida 33458

W

William R. Roush

Department of Chemistry, Scripps Florida, Jupiter, Florida 33458

Cite This Article

Ming Chen, Daniel H. Ess, William R. Roush (2010). Enantioselective Synthesis of (E)-δ-Stannyl Homoallylic Alcohols via Aldehyde Allylboration Using α-Stannylallylboranes Generated by Allene Hydroboration Followed by a Highly Diastereoselective 1,3-Boratropic Shift. Journal of the American Chemical Society, 132(23), 7881-7883. https://doi.org/10.1021/ja103041u

Enantioselective Synthesis of (E)-δ-Stannyl Homoallylic Alcohols via Aldehyde Allylboration Using α-Stannylallylboranes Generated by Allene Hydroboration Followed by a Highly Diastereoselective 1,3-Boratropic Shift

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