Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes

Michela Quaranta; Timo Gehring; Barbara Odell; John M. Brown; Donna G. Blackmond

doi:10.1021/ja103204w

journal article Oct 13, 2010

Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes

Michela Quaranta Timo Gehring Barbara Odell John M. Brown Donna G. Blackmond

Journal of the American Chemical Society Vol. 132 No. 43 pp. 15104-15107 · American Chemical Society (ACS)

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90

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References

Details

Published: Oct 13, 2010
Vol/Issue: 132(43)
Pages: 15104-15107

Authors

M

Michela Quaranta

Department of Chemistry and Department of Chemical Engineering & Chemical Technology, Imperial College London, London SW7 2AZ, United Kingdom, Institut für Organische Chemie, Karlsruher Institut für Technologie (KIT), 76131 Karlsruhe, Germany, and Chemistry Research Laboratory, Oxford University, Oxford OX1 3TA, United Kingdom

T

Timo Gehring

Department of Chemistry and Department of Chemical Engineering & Chemical Technology, Imperial College London, London SW7 2AZ, United Kingdom, Institut für Organische Chemie, Karlsruher Institut für Technologie (KIT), 76131 Karlsruhe, Germany, and Chemistry Research Laboratory, Oxford University, Oxford OX1 3TA, United Kingdom

B

Barbara Odell

Department of Chemistry and Department of Chemical Engineering & Chemical Technology, Imperial College London, London SW7 2AZ, United Kingdom, Institut für Organische Chemie, Karlsruher Institut für Technologie (KIT), 76131 Karlsruhe, Germany, and Chemistry Research Laboratory, Oxford University, Oxford OX1 3TA, United Kingdom

J

John M. Brown

Department of Chemistry and Department of Chemical Engineering & Chemical Technology, Imperial College London, London SW7 2AZ, United Kingdom, Institut für Organische Chemie, Karlsruher Institut für Technologie (KIT), 76131 Karlsruhe, Germany, and Chemistry Research Laboratory, Oxford University, Oxford OX1 3TA, United Kingdom

D

Donna G. Blackmond

Department of Chemistry and Department of Chemical Engineering & Chemical Technology, Imperial College London, London SW7 2AZ, United Kingdom, Institut für Organische Chemie, Karlsruher Institut für Technologie (KIT), 76131 Karlsruhe, Germany, and Chemistry Research Laboratory, Oxford University, Oxford OX1 3TA, United Kingdom

Cite This Article

Michela Quaranta, Timo Gehring, Barbara Odell, et al. (2010). Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes. Journal of the American Chemical Society, 132(43), 15104-15107. https://doi.org/10.1021/ja103204w

Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes

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