Intermolecular Buchwald–Hartwig Reactions for Enantioselective Synthesis of Diverse Atropisomers: Rerouting the C–N Forming Mechanism to Substrate Oxygen-Assisted Reductive Elimination

Wei Wang; Mingwei Jiang; Junwei Li; Fen Wang; Xiao-Xi Li; Jing Zhao; Xingwei Li

doi:10.1021/jacs.4c03342

journal article Jun 07, 2024

Intermolecular Buchwald–Hartwig Reactions for Enantioselective Synthesis of Diverse Atropisomers: Rerouting the C–N Forming Mechanism to Substrate Oxygen-Assisted Reductive Elimination

Wei Wang

Journal of the American Chemical Society Vol. 146 No. 24 pp. 16567-16580 · American Chemical Society (ACS)

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Details

Published: Jun 07, 2024
Vol/Issue: 146(24)
Pages: 16567-16580
License: View

Authors

W

Wei Wang

School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710062, China

M

Mingwei Jiang

School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710062, China

J

Junwei Li

School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710062, China

F

Fen Wang

School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710062, China

X

Xiao-Xi Li

Institute of Frontier Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Qingdao 266237, China

J

Jing Zhao

School of Chemistry and Chemical Engineering and Shenzhen Research Institute, Nanjing University, Nanjing 210093, China

X

Xingwei Li

School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710062, China; Institute of Frontier Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Qingdao 266237, China

Funding

National Natural Science Foundation of China Award: 22371175

National Key Research and Development Program of China Award: 2022YFA1503104

SNNU

Cite This Article

Wei Wang, Mingwei Jiang, Junwei Li, et al. (2024). Intermolecular Buchwald–Hartwig Reactions for Enantioselective Synthesis of Diverse Atropisomers: Rerouting the C–N Forming Mechanism to Substrate Oxygen-Assisted Reductive Elimination. Journal of the American Chemical Society, 146(24), 16567-16580. https://doi.org/10.1021/jacs.4c03342

Intermolecular Buchwald–Hartwig Reactions for Enantioselective Synthesis of Diverse Atropisomers: Rerouting the C–N Forming Mechanism to Substrate Oxygen-Assisted Reductive Elimination

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