Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering

Meiling Xiao; Yongting Chen; Liqin Gao; Jin Zhao; Junjie Ge; Zheng Jiang; Shengli Chen; Wei Xing

doi:10.1021/jacs.9b08362

journal article Oct 11, 2019

Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering

Meiling Xiao

Yongting Chen Liqin Gao Jin Zhao

Journal of the American Chemical Society Vol. 141 No. 44 pp. 17763-17770 · American Chemical Society (ACS)

View at Publisher Save 10.1021/jacs.9b08362

Topics

No keywords indexed for this article. Browse by subject →

References

51

[1]

Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells

Michel Lefèvre, Eric Proietti, Frédéric Jaouen et al.

Science 10.1126/science.1170051

[2]

10.1126/science.1200832

[3]

10.1126/science.1172083

[4]

10.1016/j.electacta.2008.02.012

[5]

10.1021/ja504696r

[6]

10.1039/c8ee01169a

[7]

10.1002/adma.201801732

[8]

10.1038/s41929-018-0164-8

[9]

10.1016/j.jelechem.2010.10.004

[10]

10.1021/jp047349j

[11]

10.1039/c1cp21228a

[12]

10.1002/anie.201604311

[13]

10.1016/j.carbon.2019.02.067

[14]

10.1016/0022-0728(92)80442-7

[15]

10.1016/s0013-4686(98)00257-6

[16]

Towards a unified way of comparing the electrocatalytic activity MN4 macrocyclic metal catalysts for O2 reduction on the basis of the reversible potential of the reaction

José H. Zagal, F. Javier Recio, Cristian A. Gutierrez et al.

Electrochemistry Communications 10.1016/j.elecom.2014.01.009

[17]

10.1016/j.elecom.2019.04.005

[18]

10.1021/jacs.6b11072

[19]

10.1016/b978-0-08-092394-9.50004-x

[20]

10.2116/analsci.21.309

[21]

10.1021/ja405149m

[22]

10.1039/c8ee01481g

[23]

10.1021/acscatal.8b00138

[24]

10.1021/jacs.7b10385

[25]

10.1038/srep09286

[26]

10.1016/j.nanoen.2018.02.025

[27]

Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst

Hoon T. Chung, David A. Cullen, Drew Higgins et al.

Science 10.1126/science.aan2255

[28]

10.1016/j.electacta.2016.12.005

[29]

10.1002/anie.201406695

[30]

10.1021/jp503266h

[31]

10.1039/c3cp55331k

[32]

Linking structure to function: The search for active sites in non-platinum group metal oxygen reduction reaction catalysts

Edward F. Holby, Piotr Zelenay

Nano Energy 10.1016/j.nanoen.2016.05.025

[33]

10.1038/376238a0

[34]

10.1146/annurev.physchem.53.100301.131630

[35]

10.1002/anie.200462127

[36]

10.1006/jcat.1999.2724

[37]

10.1002/ange.200504386

[38]

10.1016/j.carbon.2018.12.007

[39]

Wavelet analysis of extended x-ray absorption fine structure data

H. Funke, A. C. Scheinost, M. Chukalina

Physical Review B 10.1103/physrevb.71.094110

[40]

10.1021/jp500781v

[41]

10.1002/adma.201706758

[42]

10.1038/s41557-018-0100-1

[43]

10.1038/s41467-018-06279-x

[44]

10.1039/c8ee01855c

[45]

10.1021/acs.chemrev.7b00335

[46]

10.1038/ncomms8343

[47]

Isolated Single Iron Atoms Anchored on N‐Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction

Yuanjun Chen, Shufang Ji, Yanggang Wang et al.

Angewandte Chemie International Edition 10.1002/anie.201702473

[48]

10.1021/ja511759u

[49]

10.1021/jacs.6b00757

[50]

10.1016/j.carbon.2016.08.078

Showing 50 of 51 references

Cited By

607

Low-nuclearity metal clusters for energy electrocatalysis

Ruirui Li, Mingzhe Fu · 2026

Coordination Chemistry Reviews

Reinforcing Oxygen Activation of Spinel Oxide via Mn─O Covalency Engineering for VOCs Oxidation

Gan Li, Ruochen Zhou · 2026

Advanced Science

Asymmetric‐Charge‐Distributed Co─Mn Diatomic Catalyst Enables Efficient Oxygen Reduction Reaction

Yue Zhao, Zhonghui Gao · 2025

Advanced Functional Materials

Transforming Adsorbate Surface Dynamics in Aqueous Electrocatalysis: Pathways to Unconstrained Performance

Viet‐Hung Do, Jong‐Min Lee · 2025

Advanced Materials

Janus effect of FeCo dual atom catalyst with Co as active center in acidic oxygen reduction reaction

Long-Ji Yuan, Zhen-Yu Miao · 2025

Nature Communications

Low‐Temperature Pyrolysis: A Universal Route to High‐Loading Single‐Atom Catalysts for Fuel Cells

Xiaoyang Cheng, Shuhu Yin · 2025

Advanced Materials

Impeding Thermal Atomization Enables Synthesizing Fe 2 N Cluster Liganded Single Fe‐Atom Catalyst for Highly Efficient Oxygen Reduction Reaction

Fei‐Xiang Ma, Xiongyi Liang · 2025

Angewandte Chemie International Edi...

Do we achieve “1 + 1 > 2” in dual-atom or dual-single-atom catalysts?

Xue Yang, Linyao Xu · 2024

Coordination Chemistry Reviews

Electronic structure regulation of the Fe-based single-atom catalysts for oxygen electrocatalysis

Xiaochen Wang, Zhiwen Kang · 2024

Nano Energy

Dual‐Shelled Hollow Leafy Carbon Support with Atomically Dispersed (N,S)‐Bridged Hydroxy‐Coordinated Asymmetric Fe Sites for Oxygen Reduction

Min Yuan, Yang Liu · 2024

Advanced Functional Materials

General Synthesis of a Diatomic Catalyst Library via a Macrocyclic Precursor-Mediated Approach

Yu-Xiao Zhang, Shengbo Zhang · 2023

Journal of the American Chemical So...

Dual‐Active‐Sites Single‐Atom Catalysts for Advanced Applications

Shaolong Zhang, Minchen Hou · 2023

Small

Double‐Confinement Construction of Atomically‐Dispersed‐Fe Bifunctional Oxygen Electrocatalyst for High‐Performance Zinc‐Air Battery

Xue Zhao, Mengshan Chen · 2023

Small

Structurally Ordered PtNi Intermetallic Nanoparticles as Efficient and Stable Cathode Catalysts for Proton Exchange Membrane Fuel Cells

Lubing Li, Lei Zhang · 2023

Chemistry – A European Journal

Bimetallic Sites for Catalysis: From Binuclear Metal Sites to Bimetallic Nanoclusters and Nanoparticles

Lichen Liu, Avelino Corma · 2023

Chemical Reviews

Modulating the electronic structures derived by neighbouring hetero-diatomic FeCoN6-Gra for prominent electrocatalysis of arsenious acid

Yong-Yu Li, Zong-Yin Song · 2023

Applied Catalysis B: Environmental

OH spectator at IrMo intermetallic narrowing activity gap between alkaline and acidic hydrogen evolution reaction

Jiaxi Zhang, Longhai Zhang · 2022

Nature Communications

Regulating the FeN4 Moiety by Constructing Fe–Mo Dual-Metal Atom Sites for Efficient Electrochemical Oxygen Reduction

Peng Zhu, Xiang Xiong · 2022

Nano Letters

Implanting Single Zn Atoms Coupled with Metallic Co Nanoparticles into Porous Carbon Nanosheets Grafted with Carbon Nanotubes for High‐Performance Lithium‐Sulfur Batteries

Ruirui Wang, Renbing Wu · 2022

Advanced Functional Materials

Understanding the inter-site distance effect in single-atom catalysts for oxygen electroreduction

Zhaoyu Jin, Panpan Li · 2021

Nature Catalysis

Metrics

607

Citations

51

References

Details

Published: Oct 11, 2019
Vol/Issue: 141(44)
Pages: 17763-17770
License: View

Authors

M

Meiling Xiao

State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, China

Y

Yongting Chen

Hubei Electrochemical Power Sources Key Laboratory, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China

L

Liqin Gao

State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, China

J

Jin Zhao

State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, China

J

Junjie Ge

State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, China

Z

Zheng Jiang

Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China; Shanghai Synchrotron Radiation Facility, Zhangjiang National Lab, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201204, China

S

Shengli Chen

Hubei Electrochemical Power Sources Key Laboratory, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China

W

Wei Xing

State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, China

Funding

National Natural Science Foundation of China Award: U1601211

Chinese Academy of Sciences

Central Committee of the Communist Party of China Award: WQ20122200077

People's Government of Jilin Province Award: 20150101066JC

Ministry of Science and Technology of the People's Republic of China Award: 2017YFB0102900

Cite This Article

Meiling Xiao, Yongting Chen, Liqin Gao, et al. (2019). Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering. Journal of the American Chemical Society, 141(44), 17763-17770. https://doi.org/10.1021/jacs.9b08362

Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering

You May Also Like