Modeling Mercury Porosimetry Using Statistical Mechanics

F. Porcheron; P. A. Monson; M. Thommes

doi:10.1021/la049939e

journal article Jun 16, 2004

Modeling Mercury Porosimetry Using Statistical Mechanics

F. Porcheron P. A. Monson M. Thommes

Langmuir Vol. 20 No. 15 pp. 6482-6489 · American Chemical Society (ACS)

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It is worth noting that to build a detailed off-lattice model of mercury porosimetry, an intermolecular potential capable of modeling the small ratio of triple point temperature to critical temperature for mercury would be necessary. In particular, the reduced temperatureT/Tc= 0.17 lies below the triple point temperature for the Lennard-Jones 12-6 potential, so this potential would not be suitable. The lattice model does not present this problem since there is no solid-phase intervening at low temperatures.

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Details

Published: Jun 16, 2004
Vol/Issue: 20(15)
Pages: 6482-6489

Authors

F

F. Porcheron

Department of Chemical Engineering, University of Massachusetts, Amherst, Massachusetts 01003-9303

P

P. A. Monson

Department of Chemical Engineering, University of Massachusetts, Amherst, Massachusetts 01003-9303

M

M. Thommes

Quantachrome Instruments, 1900 Corporate Drive, Boynton Beach, Florida 33426

Cite This Article

F. Porcheron, P. A. Monson, M. Thommes (2004). Modeling Mercury Porosimetry Using Statistical Mechanics. Langmuir, 20(15), 6482-6489. https://doi.org/10.1021/la049939e

Modeling Mercury Porosimetry Using Statistical Mechanics

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