Generalized Structural Description of Calcium–Sodium Aluminosilicate Hydrate Gels: The Cross-Linked Substituted Tobermorite Model

Rupert J. Myers; Susan A. Bernal; Rackel San Nicolas; John L. Provis

doi:10.1021/la4000473

journal article Apr 15, 2013

Generalized Structural Description of Calcium–Sodium Aluminosilicate Hydrate Gels: The Cross-Linked Substituted Tobermorite Model

Rupert J. Myers

Susan A. Bernal

Rackel San Nicolas John L. Provis

Langmuir Vol. 29 No. 17 pp. 5294-5306 · American Chemical Society (ACS)

View at Publisher Save 10.1021/la4000473

Topics

No keywords indexed for this article. Browse by subject →

References

58

[1]

Moir G. (2003)

[2]

Taylor H. F. W. (1997) 10.1680/cc.25929

[3]

Richardson I. G. Cem. Concr. Res. (2008) 10.1016/j.cemconres.2007.11.005

[4]

Advances in alternative cementitious binders

M.C.G. Juenger, F. Winnefeld, J.L. Provis et al.

Cement and Concrete Research 2011 10.1016/j.cemconres.2010.11.012

[5]

Supplementary cementitious materials

Barbara Lothenbach, Karen Scrivener, R.D. Hooton

Cement and Concrete Research 2011 10.1016/j.cemconres.2010.12.001

[6]

Wang S.-D. Adv. Cem. Res. (1995) 10.1680/adcr.1995.7.27.93

[7]

Shi C. (2006) 10.4324/9780203390672

[8]

10.111/jace.12247

[9]

Skibsted J. J. Am. Ceram. Soc. (2013) 10.1111/jace.12024

[10]

Chen W. J. Mater. Sci. (2007) 10.1007/s10853-006-0873-2

[11]

Richardson I. G. Cem. Concr. Res. (2004) 10.1016/j.cemconres.2004.05.034

[12]

Sun G. K. Cem. Concr. Res. (2006) 10.1016/j.cemconres.2005.03.002

[13]

Pardal X. Cem. Concr. Res. (2009) 10.1016/j.cemconres.2009.05.001

[14]

Richardson I. G. Cem. Concr. Res. (1994) 10.1016/0008-8846(94)90002-7

[15]

Schneider J. Cem. Concr. Res. (2001) 10.1016/s0008-8846(01)00530-0

[16]

Ben Haha M. Cem. Concr. Res. (2011) 10.1016/j.cemconres.2010.11.016

[17]

Ben Haha M. Cem. Concr. Res. (2011) 10.1016/j.cemconres.2010.11.016

[18]

Ben Haha M. Cem. Concr. Res. (2012) 10.1016/j.cemconres.2011.08.005

[19]

Brough A. R. Cem. Concr. Res. (2002) 10.1016/s0008-8846(02)00717-2

[20]

Faucon P. J. Phys. Chem. B (1999) 10.1021/jp990609q

[21]

Bonk F. J. Am. Ceram. Soc. (2003) 10.1111/j.1151-2916.2003.tb03545.x

[22]

Andersen M. D. Cem. Concr. Res. (2006) 10.1016/j.cemconres.2005.04.010

[23]

Bernal S. A. Cem. Concr. Compos. (2011) 10.1016/j.cemconcomp.2010.09.004

[24]

Bernal, S. A.; Provis, J. L.; Walkley, B.; San Nicolas, R.; Gehman, J. D.; Brice, D. G.; Kilcullen, A.; Duxson, P.; van Deventer, J. S. J.Gel structure in akali-activated binders based on slag and fly ash, and effects of accelerated carbonation.Cem. Concr. Res. 2013, in press. 10.1016/j.cemconres.2013.06.007

[25]

Bonaccorsi E. J. Am. Ceram. Soc. (2005) 10.1111/j.1551-2916.2005.00116.x

[26]

McConnell J. D. C. Mineral. Mag. (1954)

[27]

Merlino S. Eur. J. Mineral. (2001) 10.1127/0935-1221/2001/0013-0577

[28]

Merlino S. Am. Mineral. (1999) 10.2138/am-1999-1015

[29]

Merlino S. Eur. J. Mineral. (2000) 10.1127/0935-1221/2000/0012-0411

[30]

Manzano H. Acta Mater. (2009) 10.1016/j.actamat.2008.12.007

[31]

Oh J. E. Cem. Concr. Res. (2012) 10.1016/j.cemconres.2011.11.004

[32]

Richardson I. G. Cem. Concr. Res. (1993) 10.1016/0008-8846(93)90143-w

[33]

Kulik D. A. Cem. Concr. Res. (2011) 10.1016/j.cemconres.2011.01.012

[34]

Richardson I. G. Cem. Concr. Res. (1999) 10.1016/s0008-8846(99)00168-4

[35]

García Lodeiro I. Cem. Concr. Res. (2010) 10.1016/j.cemconres.2009.08.004

[36]

Thomas J. J. Cem. Concr. Res. (2012) 10.1016/j.cemconres.2011.11.003

[37]

Puertas F. J. Eur. Ceram. Soc. (2011) 10.1016/j.jeurceramsoc.2011.04.036

[38]

Pardal X. Inorg. Chem. (2012) 10.1021/ic202124x

[39]

Loewenstein W. Am. Mineral. (1954)

[40]

Tossell J. A. Am. Mineral. (1993)

[41]

Richardson I. G. J. Am. Ceram. Soc. (1993) 10.1111/j.1151-2916.1993.tb07765.x

[42]

Bernal S. A. Cem. Concr. Res. (2012) 10.1016/j.cemconres.2012.07.002

[43]

Rawal A. J. Am. Ceram. Soc. (2010)

[44]

Abdolhosseini Qomi M. J. J. Am. Ceram. Soc. (2012) 10.1111/j.1551-2916.2011.05058.x

[45]

Stade H. Cem. Concr. Res. (1987) 10.1016/0008-8846(87)90128-1

[46]

Hydration products of alkali activated slag cement

Shao-Dong Wang, Karen L. Scrivener

Cement and Concrete Research 1995 10.1016/0008-8846(95)00045-e

[47]

Schilling P. J. J. Mater. Res. (1994) 10.1557/jmr.1994.0188

[48]

Harris R. K. Zeolites (1997) 10.1016/s0144-2449(97)00060-2

[49]

Le Saoût G. J. Am. Ceram. Soc. (2011) 10.1111/j.1551-2916.2011.04828.x

[50]

Provis J. L. Chem. Mater. (2005) 10.1021/cm050219i

Showing 50 of 58 references

Cited By

510

Reactive MgO enhanced carbonation resistance in Alkali-Activated Materials: Insights into Mg-bearing phase evolution and possible M-S-H formation

Shaswat Kumar Das, Yuya Suda · 2026

Cement and Concrete Composites

Development of cement-free strain-hardening slag composites: Impact of calcium hydroxide activation and dosage on microstructural and mechanical properties

Seong Yun Woo, Taekgeun Oh · 2026

Cement and Concrete Research

Carbonation curing of ultra-high-performance concrete produced with Portland cement of varying belite content

Joonho Seo, G.M. Kim · 2026

Case Studies in Construction Materi...

Development of cementless ultra-high-performance concrete activated by a novel calcium-based alkali activator

Taekgeun Oh, Seong Yun Woo · 2026

Cement and Concrete Composites

Mix design optimization of cement-free ultra-high-performance concrete based on calcium-activated slag considering binder content and particle packing

Taekgeun Oh, Seong Yun Woo · 2026

Construction and Building Materials

Critical Review of Nanomechanical Properties of Calcium (Alumino) Silicate Hydrates: Test Methods, Influencing Factors, and Enhancing Strategies

Jiawei Wang, Stuart McElhany · 2025

Engineering

Structural evolution of calcium sodium aluminosilicate hydrate (C-(N-)A-S-H) gels induced by water exposure: The impact of Na leaching

Chen Liu, Zhenming Li · 2024

Cement and Concrete Research

The effects of calcium carbonate on sodium metasilicate-activated metakaolin-based geopolymer pastes

Jie Ren, B. Cansu Acarturk · 2024

Construction and Building Materials

Preparation and performance assessment of calcium carbide slag alkali-activated red mud-based cementitious material

Zihao Dai, Jiusu Li · 2024

Materials Today Communications

Experimental and analytical studies on residual flexural behaviour of reinforced alkali-activated slag-based concrete beams after exposure to fire

Yuzhong Liu, Panwei Du · 2024

Engineering Structures

Cold sintering: A promising in situ resource utilisation strategy to densify lunar regolith simulants for construction applications

Zhen Liu, Jinping Li · 2024

Materials & Design

Deterioration and mitigation of efflorescence of alkali-activated phosphorus slag

Ruiquan Jia, Qiang Wang · 2023

Construction and Building Materials

In-situ solidification of alkali-activated lunar regolith: Insights into the chemical and physical origins

Zifan Geng, Lizhi Zhang · 2023

Journal of Cleaner Production

Effects of elevated temperatures on properties of hybrid alkaline-belite cement with high level of fly ash

Bo Qu, A. Martin · 2022

Journal of Materials Research and T...

The influence of curing temperature on the strength and phase assemblage of hybrid cements based on GGBFS/FA blends

Ricky Henning, Patrick Sturm · 2022

Frontiers in Materials

Durability properties of sustainable alkali-activated cementitious materials as marine engineering material: A review

G. Yang, J. Zhao · 2022

Materials Today Sustainability

Endowing strength to calcium silicate hydrate (C-S-H) powder by high pressure mechanical compaction

Zhe Zhang, Yu Yan · 2022

Cement and Concrete Research

Strategy for preventing explosive spalling and enhancing material efficiency of lightweight ultra high-performance concrete

Jian-Xin Lu, Peiliang Shen · 2022

Cement and Concrete Research

Robust layer interface in cement additive manufacturing via silicate penetration and precipitation

Zifan Geng, Peipei Wu · 2022

Materials & Design

The Effect of Various Si/Al, Na/Al Molar Ratios and Free Water on Micromorphology and Macro-Strength of Metakaolin-Based Geopolymer

Hongguang Wang, Hao Wu · 2021

Materials

Metrics

510

Citations

58

References

Details

Published: Apr 15, 2013
Vol/Issue: 29(17)
Pages: 5294-5306

Authors

R

Rupert J. Myers

Department of Materials Science and Engineering, Sir Robert Hadfield Building, Mappin St., University of Sheffield, Sheffield S1 3JD, U.K.; Department of Chemical & Biomolecular Engineering, University of Melbourne, Victoria 3010, Australia

S

Susan A. Bernal

Department of Materials Science and Engineering, Sir Robert Hadfield Building, Mappin St., University of Sheffield, Sheffield S1 3JD, U.K.; Department of Chemical & Biomolecular Engineering, University of Melbourne, Victoria 3010, Australia

R

Rackel San Nicolas

Department of Chemical & Biomolecular Engineering, University of Melbourne, Victoria 3010, Australia

J

John L. Provis

Department of Materials Science and Engineering, Sir Robert Hadfield Building, Mappin St., University of Sheffield, Sheffield S1 3JD, U.K.; Department of Chemical & Biomolecular Engineering, University of Melbourne, Victoria 3010, Australia

Cite This Article

Rupert J. Myers, Susan A. Bernal, Rackel San Nicolas, et al. (2013). Generalized Structural Description of Calcium–Sodium Aluminosilicate Hydrate Gels: The Cross-Linked Substituted Tobermorite Model. Langmuir, 29(17), 5294-5306. https://doi.org/10.1021/la4000473

Generalized Structural Description of Calcium–Sodium Aluminosilicate Hydrate Gels: The Cross-Linked Substituted Tobermorite Model

You May Also Like