Synthesis of a New Stable β-Sulfinyl Nitroxide and the Corresponding Alkoxyamine for Living/Controlled Radical Polymerization of Styrene:  Kinetic and ESR Studies

Eric Drockenmuller; Jean-Marie Catala

doi:10.1021/ma011063k

journal article Feb 22, 2002

Synthesis of a New Stable β-Sulfinyl Nitroxide and the Corresponding Alkoxyamine for Living/Controlled Radical Polymerization of Styrene: Kinetic and ESR Studies

Eric Drockenmuller

Jean-Marie Catala

Macromolecules Vol. 35 No. 7 pp. 2461-2466 · American Chemical Society (ACS)

View at Publisher Save 10.1021/ma011063k

Topics

No keywords indexed for this article. Browse by subject →

References

26

[1]

Solomon D. H. (1986)

[2]

Fischer H. J. Polym. Sci., Polym. Chem. (1999) 10.1002/(sici)1099-0518(19990701)37:13<1885::aid-pola1>3.0.co;2-1

[3]

Fukuda T. Macromol. Rapid Commun. (2000) 10.1002/(sici)1521-3927(200003)21:4<151::aid-marc151>3.0.co;2-3

[4]

Hawker C. J. Chem. Rev. (2001) 10.1021/cr990119u

[5]

Veregin R. P. N. Macromolecules (1993) 10.1021/ma00072a007

[6]

Chong Y. K. Macromolecules (1999) 10.1021/ma9904868

[7]

Catala J.-M. Macromolecules (1995) 10.1021/ma00128a069

[8]

Fukuda T. Chem. Lett. (1993)

[9]

Grimaldi S. (1996)

[10]

Le Mercier C. Polym. Prepr. (1999)

[11]

Benoit D. J. Am. Chem. Soc. (2000) 10.1021/ja991735a

[12]

Dyer J. C. J. Org. Chem. (1982) 10.1021/jo00140a014

[13]

Bartlett P. D. J. Am. Chem. Soc. (1960) 10.1021/ja01492a055

[14]

Greene F. D. J. Org. Chem. (1969) 10.1021/jo01260a007

[15]

Chang Z. Y. J. Org. Chem. (1990) 10.1021/jo00298a018

[16]

Miura Y. Macromolecules (1999) 10.1021/ma9907542

[17]

Hammouch S. O. Macromol. Rapid Commun. (1996) 10.1002/marc.1996.030171003

[18]

Buback M. Macromol. Chem. Phys. (1995) 10.1002/macp.1995.021961016

[19]

Fukuda T. Macromolecules (1996) 10.1021/ma960552v

[20]

Kothe T. J. Chem. Soc., Perkin Trans. (1998) 10.1039/a802773k

[21]

Marque S. J. Org. Chem. (2001) 10.1021/jo001190z

[22]

Marque S. Macromolecules (2000) 10.1021/ma9918452

[23]

The equilibrium constantKwas evaluated, in our laboratory, from ESR and kinetic studies of the bulk polymerization of styrene at 90 °C, in the presence of the alkoxyamine releasing di-tert-butyl nitroxide and 2-phenylethyl radical;K= 5.2 × 10-11mol L-1. Fromkd90= 6.4 × 10-4s-1,20it was foundkc90= 1.2 × 107L mol-1s-1.

[24]

Alkoxyamine-Initiated Living Radical Polymerization: Factors Affecting Alkoxyamine Homolysis Rates

Graeme Moad, Ezio Rizzardo

Macromolecules 1995 10.1021/ma00130a003

[25]

Russell K. B. J. Am. Chem. Soc. (1953) 10.1021/ja01116a048

[26]

Jousset S. Macromolecules (2000) 10.1021/ma9920902

Metrics

61

Citations

26

References

Details

Published: Feb 22, 2002
Vol/Issue: 35(7)
Pages: 2461-2466

Authors

E

Eric Drockenmuller

Institut Charles Sadron, CNRS-ULP, 6 rue Boussingault, 67083 Strasbourg Cedex, France

J

Jean-Marie Catala

Institut Charles Sadron, CNRS-ULP, 6 rue Boussingault, 67083 Strasbourg Cedex, France

Cite This Article

Eric Drockenmuller, Jean-Marie Catala (2002). Synthesis of a New Stable β-Sulfinyl Nitroxide and the Corresponding Alkoxyamine for Living/Controlled Radical Polymerization of Styrene: Kinetic and ESR Studies. Macromolecules, 35(7), 2461-2466. https://doi.org/10.1021/ma011063k

Synthesis of a New Stable β-Sulfinyl Nitroxide and the Corresponding Alkoxyamine for Living/Controlled Radical Polymerization of Styrene: Kinetic and ESR Studies

You May Also Like