A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries

Liumin Suo; Yong-Sheng Hu; Hong Li; Michel Armand; Liquan Chen

doi:10.1038/ncomms2513

journal article Feb 12, 2013

A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries

Liumin Suo

Nature Communications Vol. 4 No. 1 · Springer Science and Business Media LLC

View at Publisher Save 10.1038/ncomms2513

Topics

No keywords indexed for this article. Browse by subject →

References

60

[1]

Armand M. & Tarascon J. M. . Building better batteries. Nature 451, 652–657 (2008) . 10.1038/451652a

[2]

Goodenough J. B. & Kim Y. . Challenges for rechargeable Li batteries. Chem. Mater. 22, 587–603 (2010) . 10.1021/cm901452z

[3]

Scrosati B., Hassoun J. & Sun Y. K. . Lithium-ion batteries. A look into the future. Energy Environ. Sci. 4, 3287–3295 (2011) . 10.1039/c1ee01388b

[4]

Choi N. S. et al. Challenges facing lithium batteries and electrical double-layer capacitors. Angew. Chem. Int. Ed. 51, 9994–10024 (2012) . 10.1002/anie.201201429

[5]

Zu C. X. & Li H. . Thermodynamic analysis on energy densities of batteries. Energy Environ. Sci. 4, 2614–2624 (2011) . 10.1039/c0ee00777c

[6]

Ji X. & Nazar L. F. . Advances in Li-S batteries. J. Mater. Chem. 20, 9821–9826 (2010) . 10.1039/b925751a

[7]

Bruce P. G., Freunberger S. A., Hardwick L. J. & Tarascon J.-M. . Li-O2 and Li-S batteries with high energy storage. Nat. Mater. 11, 19–29 (2012) . 10.1038/nmat3191

[8]

Evers S. & Nazar L. F. . New approaches for high energy density lithium-sulphur battery cathodes. Acc. Chem. Res. doi:10.1021/ar3001348 (2012) . 10.1021/ar3001348

[9]

Manthiram A., Fu Y. Z. & Su Y. S. . Challenges and prospects of lithium–sulphur batteries. Acc. Chem. Res. doi:10.1021/ar300179v (2012) . 10.1021/ar300179v

[10]

Ji X. L., Lee K. T. & Nazar L. F. . A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries. Nat. Mater. 8, 500–506 (2009) . 10.1038/nmat2460

[11]

Hassoun J. & Scrosati B. . A high-performance polymer tin sulphur lithium ion battery. Angew. Chem. Int. Ed. 49, 2371–2374 (2010) . 10.1002/anie.200907324

[12]

Elazari R., Salitra G., Garsuch A., Panchenko A. & Aurbach D. . Sulfur-impregnated activated carbon fiber cloth as a binder-free cathode for rechargeable Li-S batteries. Adv. Mater. 23, 5641–5644 (2011) . 10.1002/adma.201103274

[13]

Ji X. L., Evers S., Black R. & Nazar L. F. . Stabilizing lithium-sulphur cathodes using polysulphide reservoirs. Nat. Commun. 2, 235–241 (2011) . 10.1038/ncomms1293

[14]

Demir-Cakan R. et al. Cathode composites for Li-S batteries via the use of oxygenated porous architectures. J. Am. Chem. Soc. 133, 16154–16160 (2011) . 10.1021/ja2062659

[15]

Wang H. L. et al. Graphene-wrapped sulphur particles as a rechargeable lithium-sulphur battery cathode material with high capacity and cycling stability. Nano Lett. 11, 2644–2647 (2011) . 10.1021/nl200658a

[16]

Zheng G. Y., Yang Y., Cha J. J., Hong S. S. & Cui Y. . Holow carbon nanofiber-encapsulated sulphur cathodes for high specific capacity rechargeable lihtium batteries. Nano Lett. 11, 4462–4467 (2011) . 10.1021/nl2027684

[17]

Jayaprakash N., Shen J., Moganty S. S., Corona A. & Archer A. . Porous hollow carbon@sulphur composites for high-power lithium-sulphur batteriess. Angew. Chem. Int. Ed. 50, 5904–5908 (2011) . 10.1002/anie.201100637

[18]

Schuster J. et al. Spherical ordered mesoporous carbon nanoparticles with high porosity for lithium-sulphurbatteries. Angew. Chem Int. Ed. 51, 3591–3595 (2012) . 10.1002/anie.201107817

[19]

Schuster J. & Nazar L. F. . Graphene-enveloped sulfur in a one pot reaction: a cathode with good coulombic efficiency and high practical sulfur content. Chem. Commun. 48, 1233–1235 (2012) . 10.1039/c2cc16726c

[20]

Su Y. S. & Manthiram A. . Lithium-sulphur batteries with a microporous carbon paper as a bifunctional interlayer. Nat. Commun. 3, 1166 (2012) . 10.1038/ncomms2163

[21]

Xia L. F. et al. A soft approach to encapsulate sulphur: polyaniline nanotubes for lithium-sulphur batteries with long cycle life. Adv. Mater. 24, 1176–1181 (2012) . 10.1002/adma.201103392

[22]

Yang Y. et al. Improving the performance of lithium-sulphur batteries by conductive polymer coating. ACS Nano 5, 9187–9193 (2011) . 10.1021/nn203436j

[23]

Xu K. . Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. Chem. Rev 104, 4303–4417 (2004) . 10.1021/cr030203g

[24]

Armand M. B., Chabagno J. M. & Duclot M. J. . In : Vashishta P., Mundy J.M., Shenoy G.K. (eds). Fast Ion Transport in Solids Elsevier (1979) pp 131–136.

[25]

Croce F., Appetecchi G. B., Persi L. & Scrosati B. . Nanocomposite polymer electrolytes for lithium batteries. Nature 394, 456–458 (1998) . 10.1038/28818

[26]

Gadjourova Z., Andreev Y. G., Tunstall D. P. & Bruce P. G. . Ionic conductivity in crystalline polymer electrolytes. Nature 412, 520–523 (2001) . 10.1038/35087538

[27]

Robertson A. D., West A. R. & Ritchie A. G. . Review of crystalline lithium-ion conductors suitable for high temperature battery applications. Solid State Ionics 104, 1–11 (1997) . 10.1016/s0167-2738(97)00429-3

[28]

Kondo S., Takada K. & Yamamura Y. . New lithium ion conductors based on Li2S-SiS2 . Solid State Ionics 53, 1183–1186 (1992) . 10.1016/0167-2738(92)90310-l

[29]

Kamaya N. et al. A lithium superionic conductor. Nat. Mater. 10, 682–686 (2011) . 10.1038/nmat3066

[30]

Hayashi A., Ohtomo T., Mizuno F., Tadanaga K. & Tatsumisago M. . All-solid-state Li/S batteries with highly conductive glass-ceramic electrolytes. Electrochem. Commun. 5, 701–705 (2003) . 10.1016/s1388-2481(03)00167-x

[31]

Nagao M., Hayashi A. & Tatsumisago M. . Sulfide-carbon composite electrode for all-solid-state Li/S battery with Li2S-P2S5 solid electrolyte. Electrochim. Acta 56, 6055–6059 (2011) . 10.1016/j.electacta.2011.04.084

[32]

Nagao M., Hayashi A. & Tatsumisago M. . Fabrication of favorable interface between sulfide solid electrolyte and Li metal electrode for bulk-type solid-state Li/S battery. Electrochem. Commun. 22, 177–180 (2012) . 10.1016/j.elecom.2012.06.015

[33]

Angell C. A., Liu C. & Sanchez E. . Rubbery solid electrolytes with dominant cationic transport and high ambient conductivity. Nature 362, 137–139 (1993) . 10.1038/362137a0

[34]

Hu Y. S., Li H., Huang X. J. & Chen L. Q. . Novel room temperature molten salt electrolyte based on LiTFSI and acetamide for lithium batteries. Electrochem. Commun. 6, 28–32 (2004) . 10.1016/j.elecom.2003.10.009

[35]

Henderson W. A. et al. Glyme-lithium bis(trifluoromethanesulfonyl)imide and glyme-lithium bis(perfluoroethanesulfonyl)imide phase behavior and solvate structures. Chem. Mater. 17, 2284–2289 (2005) . 10.1021/cm047881j

[36]

Tachikawa N. et al. Reversibility of electrochemical reactions of sulphur supported on inverse opal carbon in glyme-Li salt molten complex electrolytes. Chem. Commun. 47, 8157–8159 (2011) . 10.1039/c1cc12415c

[37]

Yoshida K. et al. Oxidative-stability enhancement and charge transport mechanism in glyme-lithium salt equimolar complexes. J. Am. Chem. Soc. 133, 13121–13129 (2011) . 10.1021/ja203983r

[38]

Angell C. A. . Electrical conductance of concentrated aqueous solutions and molten salts: correlation through free volume transport model. J. Phys. Chem. 69, 2137 (1965) . 10.1021/j100890a507

[39]

Angell C. A. . A new class of molten slat mixtures the hydrated dipositive ion as an independent cation species. J. Electrochem. Soc. 112, 1224–1227 (1965) . 10.1149/1.2423406

[40]

Kawamura T., Kimura A., Egashira M., Okada S. & Yamaki J. I. . Thermal stability of alkyl carbonate mixed-solvent electrolytes for lithium ion cells. J. Power Sources 104, 260–264 (2002) . 10.1016/s0378-7753(01)00960-0

[41]

Mikhaylik Y. V. & Akridge J. R. . Polysulfide shuttle study in the Li/S battery system. J. Electrochem. Soc. 151, A1969–A1976 (2004) . 10.1149/1.1806394

[42]

Song M. S. et al. Effects of nanosized adsorbing material on electrochemical properties of sulphur cathodes for Li/S secondary batteries. J. Electrochem. Soc. 151, A791–A795 (2004) . 10.1149/1.1710895

[43]

Choi Y. J. et al. Electrochemical properties of sulphur electrode containing nano Al2O3 for lithium/sulphur cell. Phys. Scr. 62, T129 (2007) .

[44]

Mikhaylik Y. A. . Electrolytes for lithium sulphur cells. US Patent no. 0147891 (2005) .

[45]

Aurbach D. et al. On the surface chemical aspects of very high energy density, rechargeable Li–sulphur batteries. J. Electrochem. Soc. 156, A694–A720 (2009) . 10.1149/1.3148721

[46]

Liang X. et al. Improved cycling performances of lithium sulphur batteries with LiNO3-modified electrolyte. J. Power Sources 196, 9839–9843 (2011) . 10.1016/j.jpowsour.2011.08.027

[47]

Steven J. V., Yevgeniy S. N. & Bruce D. K. . Ionically conductive membranes for protection of active metal anodes and battery cells. US Patent no. 0191617 (2004) .

[48]

Lutgard D. J., Yevgeniy S. N. & Steven J. V. . Alleviation of voltage delay in lithium-liquid depolarizer/electrolyte solvent battery cells. US Patent no. 674558 (2010) .

[49]

Shin S. E., Kim K., Oh S. H. & Cho. W. I. . Polysulfide dissolution control: the common ion effect. Chem. Commun. doi:10.1039/c2cc36986a (2012) . 10.1039/c2cc36986a

[50]

Chazalviel J. N. . Electrochemical aspects of the generation of ramified metallic electrodeposits. Phys. Rev. A 42, 7355–7367 (1990) . 10.1103/physreva.42.7355

Showing 50 of 60 references

Cited By

2,171

Electrolyte Solvent‐Ion Configuration Deciphering Lithium Plating/Stripping Chemistry for High‐Performance Lithium Metal Battery

Qian Li, Gang Liu · 2025

Advanced Functional Materials

Small Grain ZnO/SnO2 Heterostructures with Built-In Electric Fields for Stable Lithium Metal Anodes

Ji-Yoon Song, Mihye Wu · 2025

ACS Applied Energy Materials

Hydrogel polymer electrolytes toward better zinc-ion batteries: A comprehensive review

Jianwen Li, Alireza Azizi · 2025

eScience

Revitalizing Li–S batteries: the power of electrolyte additives

Derek Ovc-Okene, Lakshmi Shiva Shankar · 2025

RSC Advances

Advances and future prospects of low-temperature electrolytes for lithium-ion batteries

Mehdi Shanbedi, Hossein Shahali · 2025

EES Batteries

3D Hierarchical Cu Nanowire Scaffolds with Rest‐Free Symmetric Pulsed Plating/Stripping for Stable Lithium‐Metal Anodes

Yongseon Choi, Eunoak Park · 2025

ChemSusChem

Fluorinated electrolytes for lithium–sulfur and beyond-lithium metal–sulfur batteries

Avinash Raulo, Saheed Lateef · 2025

Energy Storage Materials

Polysulfide chemistry in metal–sulfur batteries

Xi-Yao Li, Meng Zhao · 2025

Chemical Society Reviews

Viologen as an Electrolyte Additive for Extreme Fast Charging of Lithium‐Ion Batteries

Murugavel Kathiresan, Abishek Kumar Lakshmi · 2025

Battery Energy

Contemporary Trends in Lithium‐Sulfur Battery Design: A Comparative Review of Liquid, Quasi‐Solid, and All‐Solid‐State Architectures and Mechanisms

Yiheng Shao, Boyi Pang · 2025

Advanced Energy Materials

Stable functional electrode–electrolyte interface formed by multivalent cation additives in lithium-metal anode batteries

Hongyi Li, Daichi Shimizu · 2025

Journal of Materials Chemistry A

A comprehensive review of liquid electrolytes for silicon anodes in lithium-ion batteries

Harim Seo, Dain Kim · 2025

Advances in Industrial and Engineer...

Bipolar Polymeric Protective Layer for Dendrite‐Free and Corrosion‐Resistant Lithium Metal Anode in Ethylene Carbonate Electrolyte

Chenglong Deng, Binbin Yang · 2024

Angewandte Chemie International Edi...

The Role of Hydrogen Bonding in Aqueous Batteries: Correlating Molecular-Scale Interactions with Battery Performance

Zhengnan Tian, Wenyi Guo · 2024

ACS Energy Letters

Methylation enables the use of fluorine-free ether electrolytes in high-voltage lithium metal batteries

Ai-Min Li, Oleg Borodin · 2024

Nature Chemistry

Operando monitoring of dendrite formation in lithium metal batteries via ultrasensitive tilted fiber Bragg grating sensors

Xile Han, Hai Zhong · 2024

Light: Science & Applications

Understanding and Mitigating Lattice Collapse Degradation in Layered Oxide Materials for Sodium-Ion Battery Anode

Lixun Cheng, Xiaonan Luo · 2024

ACS Applied Materials & Interfa...

High‐efficiency Lithium Metal Stabilization and Polysulfide Suppression in Li‐S Battery Enabled by Weakly Solvating Solvent

Thuy Duong Pham, Abdullah Bin Faheem · 2024

Small

Advances in All-Solid-State Lithium–Sulfur Batteries for Commercialization

Birhanu Bayissa Gicha, Lemma Teshome Tufa · 2024

Nano-Micro Letters

Fluorine Chemistry in Rechargeable Batteries: Challenges, Progress, and Perspectives

Yao Wang, Xu Yang · 2024

Chemical Reviews

Metrics

2,171

Citations

60

References

Details

Published: Feb 12, 2013
Vol/Issue: 4(1)
License: View

Authors

Key Laboratory for Renewable Energy, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Qingdao University

Zhejiang Chinese Medical University

Cite This Article

Liumin Suo, Yong-Sheng Hu, Hong Li, et al. (2013). A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries. Nature Communications, 4(1). https://doi.org/10.1038/ncomms2513

A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries

You May Also Like