Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles

Xiulian Pan; Zhongli Fan; Wei Chen; Yunjie Ding; Hongyuan Luo; Xinhe Bao

doi:10.1038/nmat1916

journal article May 21, 2007

Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles

Xiulian Pan

Zhongli Fan Wei Chen

Yunjie Ding

Hongyuan Luo Xinhe Bao

Nature Materials Vol. 6 No. 7 pp. 507-511 · Springer Science and Business Media LLC

View at Publisher Save 10.1038/nmat1916

Topics

No keywords indexed for this article. Browse by subject →

References

32

[1]

Dai, H. Carbon nanotubes: Synthesis, integration, and properties. Acc. Chem. Res. 35, 1035–1044 (2002). 10.1021/ar0101640

[2]

Ajayan, P. M. et al. Opening carbon nanotubes with oxygen and implications for filling. Nature 362, 522–525 (1993). 10.1038/362522a0

[3]

Seraphin, S., Zhou, D., Jiao, J., Withers, J. C. & Loutfy, R. Yttrium carbide in nanotubes. Nature 362, 503 (1993). 10.1038/362503a0

[4]

Tsang, S. C., Chen, Y. K., Harris, P. J. F. & Green, M. L. H. A simple chemical method of opening and filling carbon nanotubes. Nature 372, 159–162 (1994). 10.1038/372159a0

[5]

Guerret-Plécourt, C., Bouar, Y. L., Loiseau, A. & Pascard, H. Relation between metal electronic structure and morphology of metal compounds inside carbon nanotubes. Nature 372, 761–765 (1994). 10.1038/372761a0

[6]

Formation of ordered ice nanotubes inside carbon nanotubes

Kenichiro Koga, G. T. Gao, Hideki Tanaka et al.

Nature 2001 10.1038/35090532

[7]

Sloan, J. et al. Metastable one-dimensional AgCl1−xIx solid-solution wurzite tunnel crystals formed within single-walled carbon nanotubes. J. Am. Chem. Soc. 124, 2116–2117 (2002). 10.1021/ja0173270

[8]

Mühl, T. et al. Magnetic properties of aligned Fe-filled carbon nanotubes. J. Appl. Phys. 93, 7894–7896 (2003). 10.1063/1.1557824

[9]

Farrell, A. E. et al. Ethanol can contribute to energy and environmental goals. Science 311, 506–508 (2006). 10.1126/science.1121416

[10]

Deluca, T. H. Looking at biofuels and bioenergy. Science 312, 1743–1744 (2006).

[11]

Bhasin, M. M. & O’Connor, G. L. Procede de preparation selective de derives hydrocarbones oxygenes a deux atomes de carbone. Belgian Patent 824822 (1975).

[12]

Planeix, J. M. et al. Application of carbon nanotubes as supports in heterogeneous catalysis. J. Am. Chem. Soc. 116, 7935–7936 (1994). 10.1021/ja00096a076

[13]

Yoon, B. & Wai, C. M. Microemulsion-templated synthesis of carbon nanotube-supported Pd and Rh nanoparticles for catalytic applications. J. Am. Chem. Soc. 127, 17174–17175 (2005). 10.1021/ja055530f

[14]

Girishkumar, G., Hall, T. D., Vinodgopal, K. & Kamat, P. V. Single wall carbon nanotube supports for portable direct methanol fuel cells. J. Phys. Chem. B 110, 107–114 (2006). 10.1021/jp054764i

[15]

Zhang, A. M., Dong, J. L., Xu, Q. H., Rhee, H. K. & Li, X. L. Palladium cluster filled in inner of carbon nanotubes and their catalytic properties in liquid phase benzene hydrogenation. Catal. Today 93–95, 347–352 (2004). 10.1016/j.cattod.2004.06.122

[16]

Tessonnier, J., Pesant, L., Ehret, G., Ledoux, M. J. & Pham-Huu, C. Pd nanoparticles introduced inside multi-walled carbon nanotubes for selective hydrogenation of cinnamaldehyde into hydrocinnamaldehyde. Appl. Catal. A 288, 203–210 (2005). 10.1016/j.apcata.2005.04.034

[17]

Chen, W., Pan, X., Willinger, M., Su, D. & Bao, X. Facile autoreduction of iron oxide/carbon nanotube encapsulates. J. Am. Chem. Soc. 128, 3136–3137 (2006). 10.1021/ja056721l

[18]

Chen, W., Pan, X. & Bao, X. Tuning of redox properties of iron and iron oxides via encapsulation within carbon nanotubes. J. Am. Chem. Soc. (2007, in the press, doi:10.1021/ja0713072). 10.1021/ja0713072

[19]

Cao, F. et al. Reducing reaction of Fe3O4 in nanoscopic reactors of a-CNTs. J. Phys. Chem. B 111, 1724–1728 (2007). 10.1021/jp0661037

[20]

Dujardin, E., Ebbesen, T. W., Hiura, H. & Tanigaki, K. Capillarity and wetting of carbon nanotubes. Science 265, 1850–1852 (1994). 10.1126/science.265.5180.1850

[21]

Yin, H. et al. Influence of iron promoter on catalytic properties of Rh–Mn–Li/SiO2 for CO hydrogenation. Appl. Catal. A 243, 155 (2003). 10.1016/s0926-860x(02)00560-4

[22]

Hanaoka, T. et al. Ethylene hydroformylation and carbon monoxide hydrogenation over modified and unmodified silica supported rhodium catalysts. Catal. Today 58, 271–280 (2000). 10.1016/s0920-5861(00)00261-3

[23]

de Jong, K. P., Glezer, J. H. E., Kuipers, H. P. C. E., Knoester, A. & Emeis, C. A. Highly dispersed Rh/SiO2 and Rh/MnO/SiO2 catalysts: 1. Synthesis, characterization, and CO hydrogenation activity. J. Catal. 124, 520–529 (1990). 10.1016/0021-9517(90)90198-s

[24]

Trevino, H., Lei, G. & Sachtler, W. M. H. CO hydrogenation to higher oxygenates over promoted rhodium: Nature of the metal-promoter interaction in RhMn/NaY. J. Catal. 154, 245–252 (1995). 10.1006/jcat.1995.1166

[25]

Ichikawa, M. & Fukushima, T. Infrared studies of metal additive effects on CO chemisorption modes on SiO2-supported Rh-Mn, -Ti, and–Fe catalysts. J. Phys. Chem. 89, 1564–1567 (1985). 10.1021/j100255a003

[26]

Moigno, D., Callejas-Gaspar, B., Gil-Rubio, J., Werner, H. & Kiefer, W. The metal-carbon bond in vinylidene, carbonyl, isocyanide and ethylene complexes. J. Organometal. Chem. 661, 181–190 (2002). 10.1016/s0022-328x(02)01851-x

[27]

von Ahsen, B. et al. Cationic carbonyl complexes of rhodium (I) and rhodium (III): Synthesis, vibrational spectra, NMR studies, and molecular structures of tetrakis(carbonyl) rhodium(I) heptachlorodialuminate and–gallate, [Rh(CO)4][Al2Cl7] and [Rh(CO)4][Ga2Cl7]. Inorg. Chem. 42, 3801–3814 (2003). 10.1021/ic0206903

[28]

Kapteijn, F. et al. Alumina-supported manganese oxide catalysts: I. characterization: effect of precursor and loading. J. Catal. 150, 94 (1994). 10.1006/jcat.1994.1325

[29]

Haddon, R. C. Chemistry of the fullerenes: The manifestation of strain in a class of continuous aromatic molecules. Science 261, 1545–1550 (1993). 10.1126/science.261.5128.1545

[30]

Ugarte, D., Chatelain, A. & de Heer, W. A. Nanocapillarity and chemistry in carbon nanotubes. Science 274, 1897–1899 (1996). 10.1126/science.274.5294.1897

[31]

Santiso, E. E. et al. Adsorption and catalysis: The effect of confinement on chemical reactions. Appl. Surf. Sci. 252, 766–777 (2005). 10.1016/j.apsusc.2005.02.101

[32]

Dong, X., Zhang, H., Lin, G., Yuan, Y. & Tsai, K. R. Highly active CNT-promoted Cu–ZnO–Al2O3 catalyst for methanol synthesis from H2/CO/CO2 . Catal. Lett. 85, 237–246 (2003). 10.1023/a:1022158116871

Cited By

920

Anisotropic Growth of One-Dimensional Carbides in Single-Walled Carbon Nanotubes with Strong Interaction for Catalysis

Kun Wang, Guang-Jie Xia · 2023

Journal of the American Chemical So...

Ti‐doped CeO2 Stabilized Single‐Atom Rhodium Catalyst for Selective and Stable CO2 Hydrogenation to Ethanol

Ke Zheng, Yufeng Li · 2022

Angewandte Chemie International Edi...

Direct CO2 hydrogenation to ethanol over supported Co2C catalysts: Studies on support effects and mechanism

Shunan Zhang, Xiaofang Liu · 2020

Journal of Catalysis

The ONIOM Method and Its Applications

Lung Wa Chung, W. M. C. Sameera · 2015

Chemical Reviews

Stabilizing metal nanoparticles for heterogeneous catalysis

Anmin Cao, Rongwen Lu · 2010

Physical Chemistry Chemical Physics

Metrics

920

Citations

32

References

Details

Published: May 21, 2007
Vol/Issue: 6(7)
Pages: 507-511
License: View

Authors

Yuncheng University

State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China; Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Cite This Article

Xiulian Pan, Zhongli Fan, Wei Chen, et al. (2007). Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles. Nature Materials, 6(7), 507-511. https://doi.org/10.1038/nmat1916

Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles

You May Also Like