Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x

Lee, H. Y. & Goodenough, J. B. Ideal supercapacitor behavior of amorphous V2O5nH2O in potassium chloride (KCl) aqueous solution. J. Solid State Chem. 148, 81–84 (1999). 10.1006/jssc.1999.8367

[5]

Toupin, M., Brousse, T. & Bélanger, D. Charge storage mechanism of MnO2 electrode used in aqueous electrochemical capacitor. Chem. Mater. 16, 3184–3190 (2004). 10.1021/cm049649j

[6]

Zheng, J. P., Cygan, P. J. & Jow, T. R. Hydrous ruthenium oxide as an electrode material for electrochemical capacitors. J. Electrochem. Soc. 142, 2699–2703 (1995). 10.1149/1.2050077

[7]

Brousse, T. et al. Long-term cycling behavior of asymmetric activated carbon/MnO2 aqueous electrochemical supercapacitor. J. Power Sources 173, 633–641 (2007). 10.1016/j.jpowsour.2007.04.074

[8]

Pseudocapacitive Contributions to Charge Storage in Highly Ordered Mesoporous Group V Transition Metal Oxides with Iso-Oriented Layered Nanocrystalline Domains

Kirstin Brezesinski, John Wang, Jan Haetge et al.

Journal of the American Chemical Society 2010 10.1021/ja9106385

[9]

Li, W., Cheng, F., Tao, Z. & Chen, J. Vapor-transportation preparation and reversible lithium intercalation/deintercalation of α-MoO3 microrods. J. Phys. Chem. B 110, 119–124 (2006). 10.1021/jp0553784

[10]

Tsumura, T. & Inagaki, M. Lithium insertion/extraction reaction on crystalline MoO3 . Solid State Ion. 104, 183–189 (1997). 10.1016/s0167-2738(97)00418-9

[11]

Zhou, L. et al. α-MoO3 nanobelts: a high performance cathode material for lithium ion batteries. J. Phys. Chem. C 114, 21868–21872 (2010). 10.1021/jp108778v

[12]

Lee, S. H. et al. Reversible lithium-ion insertion in molybdenum oxide nanoparticles. Adv. Mater. 20, 3627–3632 (2008). 10.1002/adma.200800999

[13]

Chernova, N. A., Roppolo, M., Dillon, A. C. & Whittingham, M. S. Layered vanadium and molybdenum oxides: batteries and electrochromics. J. Mater. Chem. 19, 2526–2552 (2009). 10.1039/b819629j

[14]

Mendoza-Sánchez, B. & Grant, P. S. Charge storage properties of a α-MoO3/carboxyl-functionalized single-walled carbon nanotube composite electrode in a Li ion electrolyte. Electrochim. Acta 98, 294–302 (2013). 10.1016/j.electacta.2013.03.072

[15]

Iriyama, Y., Abe, T., Inaba, M. & Ogumi, Z. Transmission electron microscopy (TEM) analysis of two-phase reaction in electrochemical lithium insertion within α-MoO3 . Solid State Ion. 135, 95–100 (2000). 10.1016/s0167-2738(00)00338-6

[16]

Chen, J. S., Cheah, Y. L., Madhavi, S. & Lou, X. W. Fast synthesis of α-MoO3 nanorods with controlled aspect ratios and their enhanced lithium storage capabilities. J. Phys. Chem. C 114, 8675–8678 (2010). 10.1021/jp1017482

[17]

Reddy, C. V. S., Walker, E. H., Wen, C. & Mho, S. I. Hydrothermal synthesis of MoO3 nanobelts utilizing poly(ethylene glycol). J. Power Sources 183, 330–333 (2008). 10.1016/j.jpowsour.2008.05.005

[18]

Hassan, M. F., Guo, Z. P., Chen, Z. & Liu, H. K. Carbon-coated MoO3 nanobelts as anode materials for lithium-ion batteries. J. Power Sources 195, 2372–2376 (2010). 10.1016/j.jpowsour.2009.10.065

[19]

Riley, L. A., Lee, S. H., Gedvilias, L. & Dillon, A. C. Optimization of MoO3 nanoparticles as negative-electrode material in high-energy lithium ion batteries. J. Power Sources 195, 588–592 (2010). 10.1016/j.jpowsour.2009.08.013

[20]

Kang, J. H., Paek, S. M. & Choy, J. H. In situ X-ray absorption spectroscopic study for α-MoO3 electrode upon discharge/charge reaction in lithium secondary batteries. Bull. Korean Chem. Soc. 31, 3675–3678 (2010). 10.5012/bkcs.2010.31.12.3675

[21]

Mai, L. et al. Lithiated MoO3 nanobelts with greatly improved performance for lithium batteries. Adv. Mater. 19, 3712–3716 (2007). 10.1002/adma.200700883

[22]

Wang, X.-J., Nesper, R., Villevieille, C. & Novák, P. Ammonolyzed MoO3 nanobelts as novel cathode material of rechargeable Li-ion batteries. Adv. Energy Mater. 3, 606–614 (2013). 10.1002/aenm.201200692

[23]

Mendoza-Sánchez, B. et al. An investigation of nanostructured thin film α-MoO3 based supercapacitor electrodes in an aqueous electrolyte. Electrochim. Acta 91, 253–260 (2013). 10.1016/j.electacta.2012.11.127

[24]

Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors

Torsten Brezesinski, John Wang, Sarah H. Tolbert et al.

Nature Materials 2010 10.1038/nmat2612

[25]

Balendhran, S. et al. Enhanced charge carrier mobility in two-dimensional high dielectric molybdenum oxide. Adv. Mater. 25, 109–114 (2013). 10.1002/adma.201203346

[26]

Hu, X. K. et al. Comparative study on MoO3 and HxMoO3 nanobelts: structure and electric transport. Chem. Mater. 20, 1527–1533 (2008). 10.1021/cm702942y

[27]

Dieterle, M., Weinberg, G. & Mestl, G. Raman spectroscopy of molybdenum oxides: part I. Structural characterization of oxygen defects in MoO3–x by DR UV/VIS, Raman spectroscopy and X-ray diffraction. Phys. Chem. Chem. Phys. 4, 812–821 (2002). 10.1039/b107012f

[28]

Wang, G., Ling, Y. & Li, Y. Oxygen-deficient metal oxide nanostructures for photoelectrochemical water oxidation and other applications. Nanoscale 4, 6682–6691 (2012). 10.1039/c2nr32222f

[29]

Lu, X. et al. Hydrogenated TiO2 nanotube arrays for supercapacitors. Nano Lett. 12, 1690–1696 (2012). 10.1021/nl300173j

[30]

Shin, J.-Y., Joo, J. H., Samuelis, D. & Maier, J. Oxygen-deficient TiO2−δ nanoparticles via hydrogen reduction for high rate capability lithium batteries. Chem. Mater. 24, 543–551 (2012). 10.1021/cm2031009

[31]

Xu, L. et al. 3D flowerlike α-nickel hydroxide with enhanced electrochemical activity synthesized by microwave-assisted hydrothermal method. Chem. Mater. 20, 308–316 (2008). 10.1021/cm702207w

[32]

Murugan, A. V., Muraliganth, T. & Manthiram, A. Comparison of microwave assisted solvothermal and hydrothermal syntheses of LiFePO4/C nanocomposite cathodes for lithium ion batteries. J. Phys. Chem. C 112, 14665–14671 (2008). 10.1021/jp8053058

[33]

Cook, J. B., Kim, C., Xu, L. & Cabana, J. The effect of Al substitution on the chemical and electrochemical phase stability of orthorhombic LiMnO2 . J. Electrochem. Soc. 160, A46–A52 (2013). 10.1149/2.048301jes

[34]

Li+ Ion Insertion in TiO2 (Anatase). 2. Voltammetry on Nanoporous Films

Henrik Lindström, Sven Södergren, Anita Solbrand et al.

The Journal of Physical Chemistry B 1997 10.1021/jp970490q

[35]

Wang, J., Polleux, J., Lim, J. & Dunn, B. Pseudocapacitive contributions to electrochemical energy storage in TiO2 (anatase) nanoparticles. J. Phys. Chem. C 111, 14925–14931 (2007). 10.1021/jp074464w

[36]

Pseudocapacitive oxide materials for high-rate electrochemical energy storage

Veronica Augustyn, Patrice Simon, Bruce S. Dunn

Energy Environ. Sci. 2014 10.1039/c3ee44164d

[37]

Bard, A. J. & Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications 2nd edn (Wiley, 2001).

[38]

Hashem, A. M. et al. Two-phase reaction mechanism during chemical lithium insertion into α-MoO3 . Ionics 13, 3–8 (2007). 10.1007/s11581-007-0065-3

[39]

Kim, H.-S., Cook, J. B., Tolbert, S. H. & Dunn, B. The development of pseudocapacitive properties in nanosized-MoO2 . J. Electrochem. Soc. 162, A5083–A5090 (2015). 10.1149/2.0141505jes

[40]

Augustyn, V. et al. High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat. Mater. 12, 518–522 (2013). 10.1038/nmat3601

[41]

Muller, G. A. et al. High performance pseudocapacitor based on 2D layered metal chalcogenide nanocrystals. Nano Lett. 15, 1911–1917 (2015). 10.1021/nl504764m

[42]

Generalized Gradient Approximation Made Simple

John P. Perdew, Kieron Burke, Matthias Ernzerhof

Physical Review Letters 1996 10.1103/physrevlett.77.3865

[43]

Dal Corso, A. Projector augmented wave method with spin–orbit coupling: applications to simple solids and zincblende-type semiconductors. Phys. Rev. B 86, 08135 (2012). 10.1103/physrevb.86.085135

[44]

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set

G. Kresse, J. Furthmüller

Computational Materials Science 1996 10.1016/0927-0256(96)00008-0

[45]

Dudarev, S. L. et al. Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA + U study. Phys. Rev. B 57, 1505–1509 (1998). 10.1103/physrevb.57.1505

[46]

Klimes, J., Bowler, D. R. & Michaelides, A. Van der Waals density functionals applied to solids. Phys. Rev. B 83, 195131 (2011). 10.1103/physrevb.83.195131

[47]

Ding, H. et al. Computational investigation of electron small polarons in α-MoO3 . J. Phys. Chem. C 118, 15565–15572 (2014). 10.1021/jp503065x

[48]

Ong, S. P., Chevrier, V. L. & Ceder, G. Comparison of small polaron migration and phase separation in olivine LiMnPO4 and LiFePO4 using hybrid density functional theory. Phys. Rev. B 83, 075112 (2011). 10.1103/physrevb.83.075112

[49]

Cheng, J., Sulpizi, M., VandeVondele, J. & Sprik, M. Hole localization and thermochemistry of oxidative dehydrogenation of aqueous rutile TiO2(110). ChemCatChem 4, 636–640 (2012). 10.1002/cctc.201100498

[50]

Monkhorst, H. J. & Pack, J. D. Special points for Brillouin-zone integrations. Phys. Rev. B 13, 5188–5192 (1976). 10.1103/physrevb.13.5188

Showing 50 of 53 references

Cited By

2,075

Oxygen vacancy-induced strong metal-support interaction for boosting low-temperature hydrogen production from formaldehyde over Ru/ZrO2 catalysts

Xu Yang, Qinglong Zhang · 2026

International Journal of Hydrogen E...

Unlocking Redox Activity in Confined Polyoxometalates via Atomic Nickel Activation for Aqueous Sodium‐Ion Capacitors

Yu Liang, Mengtian Huo · 2026

Chinese Journal of Chemistry

Oxygen Vacancy‐Abundant Molybdenum Dioxide Electrodes with Minimal Interfacial Charge‐Transfer Resistance for Ultrafast Filter Electrochemical Capacitors

Shuhao Zhu, Xinlei Cai · 2025

Advanced Materials

Heterodimensional Superlattice with Electron Spin-Polarization and Se-Vacancies for Superior Sodium-Ion Storage

Runze Fan, Chenyu Zhao · 2025

ACS Energy Letters

Rice husk-derived mesoporous carbons via pore-tailoring as high-performance electrode materials of zinc-ion hybrid supercapacitors

Dawei Feng, Yuming Wang · 2025

Materials Today Communications

Fe2VO4 nanoparticles embedded in CNTs with fast reaction kinetics for high-performance lithium storage

Hong Liu, Litao Han · 2025

Electrochimica Acta

Efficient transformation from boehmite into gibbsite at room temperature via strong interaction between oxygen deficiency and the single free water

Jinquan Wen, Guihua Liu · 2025

Ceramics International

Understanding the influence of crystal packing density on electrochemical energy storage materials

Wujie Dong, Fuqiang Huang · 2024

eScience

Electro-assisted photothermal synergy for removal of volatile organic compounds over Au single atoms anchored TiO2 nanotubes

Xiaoguang Wang, Xiaowen Liu · 2024

Applied Catalysis B: Environmental

Selective ozone catalyzation modulated by surface and bulk oxygen vacancies over MnO2 for superior water purification

Liying Wu, Zonglin Wang · 2024

Applied Catalysis B: Environmental

Excellent electrochemical performance of N and Mn doped NiCo2O4 functional nanostructures: an effective approach for symmetric supercapacitor application

Ananta Sasmal, Arpan Kumar Nayak · 2024

Physica Scripta

Controlled establishment of advanced local high-entropy NiCoMnFe-based layered double hydroxide for zinc batteries and low-temperature supercapacitors

Xiaohui Guan, Xinyu Fan · 2024

Journal of Colloid and Interface Sc...

Research progress on electronic and active site engineering of cobalt‐based electrocatalysts for oxygen evolution reaction

Chuansheng He, Linlin Yang · 2024

Carbon Energy

Unveiling the role of structural vacancies in Mn-based Prussian blue analogues for energy storage applications

Chongwei Gao, Ming Chen · 2024

Energy Environ. Sci.

Porous Cobalt-nickel phosphides prepared from Al-doped NiCo-LDH precursors for supercapacitor and electrocatalysis applications

Ruonan Liu, Lulu Chen · 2023

Chemical Engineering Journal

Insights into the oxygen vacancies in transition metal oxides for aqueous Zinc-Ion batteries

Qiongyao Song, Shuhao Zhou · 2023

Chemical Engineering Journal

Oxygen vacancy mediated α-MoO3 bactericidal nanocatalyst in the dark: Surface structure dependent superoxide generation and antibacterial mechanisms

Qin Gao, Zhenyu Wang · 2023

Journal of Hazardous Materials

Mobile energy storage technologies for boosting carbon neutrality

Chenyang Zhang, Xuan Liu · 2023

The Innovation

Advances in multicolor electrochromic devices based on inorganic materials

Lin Huang, Sheng Cao · 2023

Journal of Materials Chemistry C

Hierarchical porous 3D Ni3N-CoN/NC heterojunction nanosheets with nitrogen vacancies for high-performance flexible supercapacitor

Jiawei Guo, Hongbo Zhao · 2023

Nano Energy

Metrics

2,075

Citations

53

References

Details

Published: Dec 05, 2016
Vol/Issue: 16(4)
Pages: 454-460
License: View

Authors

Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States

Department of Materials Science and Engineering University of California Los Angeles, Los Angeles CA 90095 USA

Cite This Article

Hyung-Seok Kim, John B. Cook, Hao Lin, et al. (2016). Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x. Nature Materials, 16(4), 454-460. https://doi.org/10.1038/nmat4810

Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x

You May Also Like