Abstract
AbstractMare volcanics on the Moon are the key record of thermo-chemical evolution throughout most of lunar history1–3. Young mare basalts—mainly distributed in a region rich in potassium, rare-earth elements and phosphorus (KREEP) in Oceanus Procellarum, called the Procellarum KREEP Terrane (PKT)4—were thought to be formed from KREEP-rich sources at depth5–7. However, this hypothesis has not been tested with young basalts from the PKT. Here we present a petrological and geochemical study of the basalt clasts from the PKT returned by the Chang’e-5 mission8. These two-billion-year-old basalts are the youngest lunar samples reported so far9. Bulk rock compositions have moderate titanium and high iron contents  with KREEP-like rare-earth-element and high thorium concentrations. However, strontium–neodymium isotopes indicate that these basalts were derived from a non-KREEP mantle source. To produce the high abundances of rare-earth elements and thorium, low-degree partial melting and extensive fractional crystallization are required. Our results indicate that the KREEP association may not be a prerequisite for young mare volcanism. Absolving the need to invoke heat-producing elements in their source implies a more sustained cooling history of the lunar interior to generate the Moon’s youngest melts.
Topics

No keywords indexed for this article. Browse by subject →

References
60
[1]
Shearer, C. K. et al. Thermal and magmatic evolution of the Moon. Rev. Mineral. Geochem. 60, 365–518 (2006). 10.2138/rmg.2006.60.4
[2]
Ziethe, R., Seiferlin, K. & Hiesinger, H. Duration and extent of lunar volcanism: comparison of 3D convection models to mare basalt ages. Planet. Space Sci. 57, 784–796 (2009). 10.1016/j.pss.2009.02.002
[3]
Laneuville, M., Taylor, J. & Wieczorek, M. A. Distribution of radioactive heat sources and thermal history of the Moon. J. Geophys. Res. Planets 123, 3144–3166 (2018). 10.1029/2018je005742
[4]
Jolliff, B. L., Gillis, J. J., Haskin, L. A., Korotev, R. L. & Wieczorek, M. A. Major lunar crustal terranes: surface expressions and crust-mantle origins. J. Geophys. Res. Planets 105, 4197–4216 (2000). 10.1029/1999je001103
[5]
Haskin, L. A., Gillis, J. J., Korotev, R. L. & Jolliff, B. L. The materials of the lunar Procellarum KREEP Terrane: a synthesis of data from geomorphological mapping, remote sensing, and sample analyses. J. Geophys. Res. Planets 105, 20403–20415 (2000). 10.1029/1999je001128
[6]
The “Procellarum KREEP Terrane”: Implications for mare volcanism and lunar evolution

Mark A. Wieczorek, Roger J. Phillips

Journal of Geophysical Research: Oceans 2000 10.1029/1999je001092
[7]
Borg, L. E., Shearer, C. K., Asmerom, Y. & Papike, J. J. Prolonged KREEP magmatism on the Moon indicated by the youngest dated lunar igneous rock. Nature 432, 209–211 (2004). 10.1038/nature03070
[8]
Yang, W. & Lin, Y. New lunar samples returned by Chang’e-5: opportunities for new discoveries and international collaboration. The Innovation 2, 100070 (2021). 10.1016/j.xinn.2020.100070
[9]
Two-billion-year-old volcanism on the Moon from Chang’e-5 basalts

Qiu-Li Li, Qin Zhou, Yu Liu et al.

Nature 10.1038/s41586-021-04100-2
[10]
Qian, Y. et al. China’s Chang’e-5 landing site: geology, stratigraphy, and provenance of materials. Earth Planet. Sci. Lett. 561, 116855 (2021). 10.1016/j.epsl.2021.116855
[11]
Bence, A. & Papike, J. Pyroxenes as recorders of lunar basalt petrogenesis: chemical trends due to crystal-liquid interaction. Proc. Lunar Planet. Sci. 3, 431–469 (1972).
[12]
Shearer, C. K., Papike, J. J., Simon, S. B. & Shimizu, N. An ion microprobe study of the intra-crystalline behavior of REE and selected trace elements in pyroxene from mare basalts with different cooling and crystallization histories. Geochim. Cosmochim. Acta 53, 1041–1054 (1989). 10.1016/0016-7037(89)90209-3
[13]
Fagan, T. J. et al. Northwest Africa 032: product of lunar volcanism. Meteorit. Planet. Sci. 37, 371–394 (2002). 10.1111/j.1945-5100.2002.tb00822.x
[14]
Petrogenesis of mare basalts: A record of lunar volcanism

Clive R Neal, Lawrence A Taylor

Geochimica et Cosmochimica Acta 1992 10.1016/0016-7037(92)90184-k
[15]
Prettyman, T. H. et al. Elemental composition of the lunar surface: analysis of gamma ray spectroscopy data from Lunar Prospector. J. Geophys. Res. Planets 111, E12007 (2006). 10.1029/2005je002656
[16]
Lawrence, D. J. et al. Global spatial deconvolution of Lunar Prospector Th abundances. Geophys. Res. Lett. 34, L03201 (2007). 10.1029/2006gl028530
[17]
Sun, L. & Lucey, P. Mineralogy and Mg# of the Chang’e 5 landing region. Proc. Lunar Planet. Sci. 52, 1796 (2021).
[18]
Hiesinger, H. et al. in Recent Advances and Current Research Issues in Lunar Stratigraphy (eds Ambrose, W. A. & Williams, D. A.) Vol. 477, 1–51 (Geological Society of America, 2011).
[19]
Hallis, L. J., Anand, M. & Strekopytov, S. Trace-element modelling of mare basalt parental melts: implications for a heterogeneous lunar mantle. Geochim. Cosmochim. Acta 134, 289–316 (2014). 10.1016/j.gca.2014.01.012
[20]
Mechanisms for incompatible-element enrichment on the Moon deduced from the lunar basaltic meteorite Northwest Africa 032

Lars E. Borg, Amy M. Gaffney, Charles K. Shearer et al.

Geochimica et Cosmochimica Acta 2009 10.1016/j.gca.2009.03.039
[21]
Elardo, S. M. et al. The origin of young mare basalts inferred from lunar meteorites Northwest Africa 4734, 032, and LaPaz Icefield 02205. Meteorit. Planet. Sci. 49, 261–291 (2014). 10.1111/maps.12239
[22]
Snyder, G. A., Taylor, L. A. & Neal, C. R. A chemical model for generating the sources of mare basalts: combined equilibrium and fractional crystallization of the lunar magmasphere. Geochim. Cosmochim. Acta 56, 3809–3823 (1992). 10.1016/0016-7037(92)90172-f
[23]
Lunar mare TiO 2 abundances estimated from UV/Vis reflectance

Hiroyuki Sato, Mark S. Robinson, Samuel J. Lawrence et al.

Icarus 2017 10.1016/j.icarus.2017.06.013
[24]
Zhang, J., Head, J., Liu, J. & Potter, R. Analysis of thorium concentration anomalys on the lunar surface. Proc. Lunar Planet. Sci. 52, 1744 (2021).
[25]
Warren, P. H., Haack, H. & Rasmussen, K. L. Megaregolith insulation and the duration of cooling to isotopic closure within differentiated asteroids and the Moon. J. Geophys. Res. Solid Earth 96, 5909-5923 (1991). 10.1029/90jb02333
[26]
Wilson, L. & Head, J. W. Generation, ascent and eruption of magma on the Moon: new insights into source depths, magma supply, intrusions and effusive/explosive eruptions (part 1: theory). Icarus 283, 146-175 (2017). 10.1016/j.icarus.2015.12.039
[27]
Wieczorek, M. A. et al. The crust of the Moon as seen by GRAIL. Science 339, 671-675 (2013). 10.1126/science.1231530
[28]
Mighani, S. et al. The end of the lunar dynamo. Sci. Adv. 6, eaax0883 (2020). 10.1126/sciadv.aax0883
[29]
Scheinberg, A., Soderlund, K. M. & Schubert, G. Magnetic field generation in the lunar core: the role of inner core growth. Icarus 254, 62-71 (2015). 10.1016/j.icarus.2015.03.013
[30]
Snape, J. F. et al. The timing of basaltic volcanism at the Apollo landing sites. Geochim. Cosmochim. Acta 266, 29-53 (2019). 10.1016/j.gca.2019.07.042
[31]
Warren, P. H. & Taylor, G. J. in Treatise on Geochemistry (ed. Turekian, K. K.) 213–250 (Elsevier, 2014). 10.1016/b978-0-08-095975-7.00124-8
[32]
Wieczorek, M. A. The constitution and structure of the lunar interior. Rev. Mineral. Geochem. 60, 221-364 (2006). 10.2138/rmg.2006.60.3
[33]
Lindsley, D. H. & Andersen, D. J. A two-pyroxene thermometer. J. Geophys. Res. Solid Earth 88, A887-A906 (1983). 10.1029/jb088is02p0a887
[34]
Lunar Mare Volcanism: Where Did the Magmas Come From?

T. L. Grove, M. J. Krawczynski

Elements 2009 10.2113/gselements.5.1.29
[35]
Snape, J. F., Joy, K. H., Crawford, I. A. & Alexander, L. Basaltic diversity at the Apollo 12 landing site: inferences from petrologic examinations of the soil sample 12003. Meteorit. Planet. Sci. 49, 842-871 (2014). 10.1111/maps.12285
[36]
Anand, M., Taylor, L. A., Misra, K. C., Demidova, S. I. & Nazarov, M. A. KREEPy lunar meteorite Dhofar 287A: a new lunar mare basalt. Meteorit. Planet. Sci. 38, 485-499 (2003). 10.1111/j.1945-5100.2003.tb00022.x
[37]
Nyquist, L. et al. Rb–Sr systematics for chemically defined Apollo 15 and 16 materials. Proc. Lunar Planet. Sci. 4, 1823 (1973).
[38]
Nyquist, L. Lunar Rb–Sr chronology. Phys. Chem. Earth 10, 103-142 (1977).
[39]
Neal, C. & Taylor, L. Neal, C. & Taylor, L. Modeling of lunar basalt petrogenesis-SR isotope evidence from Apollo 14 high-alumina basalts. Proc. Lunar Planet. Sci. 20, 101-108 (1990).
[40]
The isotopic record of lunar volcanism

L.E Nyquist, C.-Y Shih

Geochimica et Cosmochimica Acta 1992 10.1016/0016-7037(92)90185-l
[41]
Nyquist, L. E. et al. 146Sm–142Nd formation interval for the lunar mantle. Geochim. Cosmochim. Acta 59, 2817-2837 (1995). 10.1016/0016-7037(95)00175-y
[42]
Neal, C. R. & Kramer, G. Y. The petrogenesis of the Apollo 14 high-Al mare basalts. Am. Mineral. 91, 1521-1535 (2006). 10.2138/am.2006.2147
[43]
Abundances of the elements: Meteoritic and solar

Edward Anders, Nicolas Grevesse

Geochimica et Cosmochimica Acta 1989 10.1016/0016-7037(89)90286-x
[44]
Wu, S., Karius, V., Schmidt, B. C., Simon, K. & Wörner, G. Comparison of ultrafine powder pellet and flux-free fusion glass for bulk analysis of granitoids by laser ablation-inductively coupled plasma-mass spectrometry. Geostand. Geoanal. Res. 42, 575–591 (2018). 10.1111/ggr.12230
[45]
Jochum, K. P. et al. Determination of reference values for NIST SRM 610–617 glasses following ISO guidelines. Geostand. Geoanal. Res. 35, 397-429 (2011). 10.1111/j.1751-908x.2011.00120.x
[46]
Wu, S. et al. The preparation and preliminary characterisation of three synthetic andesite reference glass materials (ARM-1, ARM-2, ARM-3) for in situ microanalysis. Geostand. Geoanal. Res. 43, 567–584 (2019). 10.1111/ggr.12301
[47]
Jochum, K. P., Willbold, M., Raczek, I., Stoll, B. & Herwig, K. Chemical characterisation of the USGS reference glasses GSA-1G, GSC-1G, GSD-1G, GSE-1G, BCR-2G, BHVO-2G and BIR-1G using EPMA, ID–TIMS, ID–ICP–MS and LA–ICP–MS. Geostand. Geoanal. Res. 29, 285–sss302 (2005). 10.1111/j.1751-908x.2005.tb00901.x
[48]
Wu, S.-T., Huang, C., Xie, L.-W., Yang, Y.-H. & Yang, J.-H. Iolite based bulk normalization as 100% (m/m) quantification strategy for reduction of laser ablation-inductively coupled plasma-mass spectrometry transient signal. Chin. J. Anal. Chem. 46, 1628–1636 (2018). 10.1016/s1872-2040(18)61118-1
[49]
Yang, Y.-H., Wu, F.-Y., Xie, L.-W., Yang, J.-H. & Zhang, Y.-B. In-situ Sr isotopic measurement of natural geological samples by LA–MC–ICP–MS. Acta Petrol. Sin. 25, 3431–3441 (2009).
[50]
Yang, Y.-H. et al. Sr and Nd isotopic compositions of apatite reference materials used in U–Th–Pb geochronology. Chem. Geol. 385, 35–55 (2014). 10.1016/j.chemgeo.2014.07.012

Showing 50 of 60 references

Metrics
252
Citations
60
References
Details
Published
Oct 19, 2021
Vol/Issue
600(7887)
Pages
59-63
License
View
Cite This Article
Heng-Ci Tian, Haitao Wang, Yi Chen, et al. (2021). Non-KREEP origin for Chang’e-5 basalts in the Procellarum KREEP Terrane. Nature, 600(7887), 59-63. https://doi.org/10.1038/s41586-021-04119-5
Related

You May Also Like

Deep learning

Yann LeCun, Yoshua Bengio · 2015

78,982 citations

Highly accurate protein structure prediction with AlphaFold

John Jumper, Richard Evans · 2021

42,787 citations

Helical microtubules of graphitic carbon

Sumio Iijima · 1991

38,201 citations

Collective dynamics of ‘small-world’ networks

Duncan J. Watts, Steven H. Strogatz · 1998

33,426 citations