Evaluating the solid electrolyte interphase formed on silicon electrodes: a comparison of ex situ X-ray photoelectron spectroscopy and in situ neutron reflectometry

T. M. Fears; M. Doucet; J. F. Browning; J. K. S. Baldwin; J. G. Winiarz; H. Kaiser; H. Taub; R. L. Sacci; G. M. Veith

doi:10.1039/c6cp00978f

journal article Jan 01, 2016

Evaluating the solid electrolyte interphase formed on silicon electrodes: a comparison of ex situ X-ray photoelectron spectroscopy and in situ neutron reflectometry

T. M. Fears M. Doucet J. F. Browning J. K. S. Baldwin

J. G. Winiarz H. Kaiser H. Taub R. L. Sacci

G. M. Veith

Physical Chemistry Chemical Physics Vol. 18 No. 20 pp. 13927-13940 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/c6cp00978f

Abstract

This work details the in situ characterization of the interface between a silicon electrode and an electrolyte using a linear fluorinated solvent molecule.

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References

43

[1]

Electrolytes and Interphases in Li-Ion Batteries and Beyond

Kang Xu

Chemical Reviews 2014 10.1021/cr500003w

[2]

Leifer J. Electrochem. Soc. (2011) 10.1149/1.3559551

[3]

Philippe Chem. Mater. (2012) 10.1021/cm2034195

[4]

Pham J. Electrochem. Soc. (2014) 10.1149/2.1141412jes

[5]

Verma Electrochim. Acta (2010) 10.1016/j.electacta.2010.05.072

[6]

Klavetter J. Power Sources (2013) 10.1016/j.jpowsour.2013.02.091

[7]

Chan J. Power Sources (2009) 10.1016/j.jpowsour.2009.01.007

[8]

Chen ChemSusChem (2014) 10.1002/cssc.201300770

[9]

Philippe Chem. Mater. (2013) 10.1021/cm303399v

[10]

Cresce Nano Lett. (2014) 10.1021/nl404471v

[11]

Edström J. Electrochem. Soc. (2000) 10.1149/1.1393950

[12]

Dolotko J. Power Sources (2014) 10.1016/j.jpowsour.2014.01.010

[13]

In Situ TEM of Two-Phase Lithiation of Amorphous Silicon Nanospheres

Matthew T. McDowell, Seok Woo Lee, Justin T. Harris et al.

Nano Letters 2013 10.1021/nl3044508

[14]

Zhou J. Magn. Reson. (2013) 10.1016/j.jmr.2013.05.011

[15]

Novák J. Power Sources (2005) 10.1016/j.jpowsour.2005.03.129

[16]

Bianchini J. Phys. Chem. C (2014) 10.1021/jp509027g

[17]

Bobrikov J. Power Sources (2014) 10.1016/j.jpowsour.2014.02.060

[18]

Liu J. Power Sources (2013) 10.1016/j.jpowsour.2013.04.149

[19]

Roberts J. Power Sources (2013) 10.1016/j.jpowsour.2012.10.085

[20]

Wang Sci. Rep. (2012) 10.1038/srep00747

[21]

Jerliu Phys. Chem. Chem. Phys. (2013) 10.1039/c3cp44438d

[22]

Solid Electrolyte Interphase in Li-Ion Batteries: Evolving Structures Measured In situ by Neutron Reflectometry

Jeanette E. Owejan, Jon P. Owejan, Steven C. DeCaluwe et al.

Chemistry of Materials 2012 10.1021/cm3006887

[23]

Characterization of electrode/electrolyte interface for lithium batteries using in situ synchrotron X-ray reflectometry—A new experimental technique for LiCoO2 model electrode

Masaaki Hirayama, Noriyuki SONOYAMA, Takeshi Abe et al.

Journal of Power Sources 2007 10.1016/j.jpowsour.2007.03.034

[24]

Browning ACS Appl. Mater. Interfaces (2014) 10.1021/am5032055

[25]

Veith Chem. Commun. (2014) 10.1039/c3cc49269a

[26]

Direct Determination of Solid-Electrolyte Interphase Thickness and Composition as a Function of State of Charge on a Silicon Anode

Gabriel M. Veith, Mathieu Doucet, J. Kevin Baldwin et al.

The Journal of Physical Chemistry C 2015 10.1021/acs.jpcc.5b06817

[27]

Nelson J. Appl. Cryst. (2006) 10.1107/s0021889806005073

[28]

T. Heitmann and W.Montfrooij, Practical Neutron Scattering at a Steady State Source, Mizzou Media – University BookStores, 2012

[29]

Wagemaker Physica B: Cond. Mat. (2003) 10.1016/s0921-4526(03)00280-1

[30]

Hirayama Denki Kagaku (2010)

[31]

Fears J. Power Sources (2015) 10.1016/j.jpowsour.2015.08.098

[32]

Hu J. Electrochem. Soc. (2014) 10.1149/2.0141412jes

[33]

Zhang Energy & Environmental Science (2013) 10.1039/c3ee24414h

[34]

Böttcher Prog. Solid State Chem. (2014) 10.1016/j.progsolidstchem.2014.04.013

[35]

Arnold Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment (2014) 10.1016/j.nima.2014.07.029

[36]

Chevrier J. Electrochem. Soc. (2009) 10.1149/1.3111037

[37]

Tanuma Surf. Interface Anal. (2005) 10.1002/sia.1997

[38]

Calculations of electron inelastic mean free paths. IX. Data for 41 elemental solids over the 50 eV to 30 keV range

S. Tanuma,, C. J. Powell, D. R. Penn

Surface and Interface Analysis 2011 10.1002/sia.3522

[39]

Abel ACS Nano (2012) 10.1021/nn204896n

[40]

Lu Electrochem. Commun. (2011) 10.1016/j.elecom.2011.06.026

[41]

Shi J. Am. Chem. Soc. (2012) 10.1021/ja305366r

[42]

NMR Chemical Shifts of Common Laboratory Solvents as Trace Impurities

Hugo E. Gottlieb, Vadim Kotlyar, Abraham Nudelman

The Journal of Organic Chemistry 1997 10.1021/jo971176v

[43]

Fulmer Organometallics (2010) 10.1021/om100106e

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Matter

Metrics

90

Citations

43

References

Details

Published: Jan 01, 2016
Vol/Issue: 18(20)
Pages: 13927-13940

Authors

T

T. M. Fears

Department of Chemistry; Missouri University of Science and Technology; Rolla; USA

M

M. Doucet

Neutron Data Analysis and Visualization Division; Oak Ridge National Laboratory; Oak Ridge; USA

J

J. F. Browning

Chemical and Engineering Materials Division; Oak Ridge National Laboratory; Oak Ridge; USA

J

J. K. S. Baldwin

Materials Science and Technology Division; Los Alamos National Laboratory; Los Alamos; USA

J

J. G. Winiarz

Department of Chemistry; Missouri University of Science and Technology; Rolla; USA

H

H. Kaiser

University of Missouri Research Reactor; University of Missouri; Columbia; USA

H

H. Taub

Department of Physics and Astronomy; University of Missouri; Columbia; USA

R

R. L. Sacci

Materials Science and Technology Division; Oak Ridge National Laboratory; Oak Ridge; USA

G

G. M. Veith

Materials Science and Technology Division; Oak Ridge National Laboratory; Oak Ridge; USA

Funding

Los Alamos National Laboratory

Basic Energy Sciences Award: DE-05-AC

Cite This Article

T. M. Fears, M. Doucet, J. F. Browning, et al. (2016). Evaluating the solid electrolyte interphase formed on silicon electrodes: a comparison of ex situ X-ray photoelectron spectroscopy and in situ neutron reflectometry. Physical Chemistry Chemical Physics, 18(20), 13927-13940. https://doi.org/10.1039/c6cp00978f

Evaluating the solid electrolyte interphase formed on silicon electrodes: a comparison of ex situ X-ray photoelectron spectroscopy and in situ neutron reflectometry

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