Incorporation of Mn into the vacant T-atom sites of a BEA zeolite as isolated, mononuclear Mn: FTIR, XPS, EPR and DR UV-Vis studies

R. Baran; L. Valentin; S. Dzwigaj

doi:10.1039/c6cp01713d

journal article Jan 01, 2016

Incorporation of Mn into the vacant T-atom sites of a BEA zeolite as isolated, mononuclear Mn: FTIR, XPS, EPR and DR UV-Vis studies

R. Baran L. Valentin

S. Dzwigaj

Physical Chemistry Chemical Physics Vol. 18 No. 17 pp. 12050-12057 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/c6cp01713d

Abstract

A MnSiBEA zeolite has been prepared via a two-step postsynthesis procedure which consisted, in the first step, of the treatment of a tetraethylammonium BEA zeolite with nitric acid for the formation of vacant T-atom sites and then, in the second step, of the incorporation of Mn ions into the framework, resulting in a SiBEA zeolite, through their reaction with the silanol group of the vacant T-atom sites.

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References

Details

Published: Jan 01, 2016
Vol/Issue: 18(17)
Pages: 12050-12057

Authors

R

R. Baran

AGH University of Science and Technology; 30-059 Krakow; Poland; Sorbonne Universités; UPMC Univ Paris 06

L

L. Valentin

Sorbonne Universités; UPMC Univ Paris 06; UMR 7197; Laboratoire de Réactivité de Surface; Paris

S

S. Dzwigaj

Sorbonne Universités; UPMC Univ Paris 06; UMR 7197; Laboratoire de Réactivité de Surface; Paris

Cite This Article

R. Baran, L. Valentin, S. Dzwigaj (2016). Incorporation of Mn into the vacant T-atom sites of a BEA zeolite as isolated, mononuclear Mn: FTIR, XPS, EPR and DR UV-Vis studies. Physical Chemistry Chemical Physics, 18(17), 12050-12057. https://doi.org/10.1039/c6cp01713d

Incorporation of Mn into the vacant T-atom sites of a BEA zeolite as isolated, mononuclear Mn: FTIR, XPS, EPR and DR UV-Vis studies

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