A new perspective on the electron transfer: recovering the Butler–Volmer equation in non-equilibrium thermodynamics

Wolfgang Dreyer; Clemens Guhlke; Rüdiger Müller

doi:10.1039/c6cp04142f

journal article Jan 01, 2016

A new perspective on the electron transfer: recovering the Butler–Volmer equation in non-equilibrium thermodynamics

Wolfgang Dreyer Clemens Guhlke Rüdiger Müller

Physical Chemistry Chemical Physics Vol. 18 No. 36 pp. 24966-24983 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/c6cp04142f

Abstract

Butler–Volmer equations can be recovered from a complete non-equilibrium thermodynamic model by application of asymptotic analysis. Thereby we gain insight into the coupling of different physical phenomena and can derive Butler–Volmer equations for very different materials and electrochemical systems.

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References

49

[1]

Tafel Z. Phys. Chem. (1905) 10.1515/zpch-1905-5043

[2]

A. Bard and L.Faulkner, Electrochemical methods: fundamentals and applications, Wiley, New York, 2nd edn, 2001

[3]

J. Bockris , A.Reddy and M.Gamboa-Aldeco, Modern Electrochemistry, Kluwer Academic Publishers, 2nd edn, 2002, vol. 2A: Fundamentals of Electrodics

[4]

J. Newman and K.Thomas-Alyea, Electrochemical Systems, Wiley, 2004

[5]

K. Vetter , Elektrochemische Kinetik, Springer-Verlag, 1961 10.1007/978-3-642-86547-3

[6]

On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. I

R. A. Marcus

The Journal of Chemical Physics 1956 10.1063/1.1742723

[7]

Marcus J. Chem. Phys. (1965) 10.1063/1.1696792

[8]

Marcus Rev. Mod. Phys. (1993) 10.1103/revmodphys.65.599

[9]

Hush J. Chem. Phys. (1958) 10.1063/1.1744305

[10]

Hush J. Electroanal. Chem. (1999) 10.1016/s0022-0728(99)00168-0

[11]

Biesheuvel Electrochim. Acta (2009) 10.1016/j.electacta.2009.03.073

[12]

Latz J. Power Sources (2011) 10.1016/j.jpowsour.2010.11.088

[13]

Latz Electrochim. Acta (2013) 10.1016/j.electacta.2013.06.043

[14]

Butler Trans. Faraday Soc. (1924) 10.1039/tf9241900729

[15]

Erdey-Grúz Z. Phys. Chem. A (1930) 10.1515/zpch-1930-15020

[16]

Kjelstrup Ratkje J. Electrochem. Soc. (1996) 10.1149/1.1836538

[17]

Kjelstrup J. Phys. Chem. B (2003) 10.1021/jp030572g

[18]

Bedeaux J. Chem. Phys. (2014) 10.1063/1.4894759

[19]

Bazant Acc. Chem. Res. (2013) 10.1021/ar300145c

[20]

Dreyer Phys. Chem. Chem. Phys. (2015) 10.1039/c5cp03836g

[21]

J. Meixner and H. G.Reik, Thermodynamik der irreversiblen Prozesse, Springer, Berlin, 1959, vol. 3, pp. 413–523

[22]

S. R. deGroot and P.Mazur, Non-equilibrium Thermodynamics, Courier Corporation, 1984

[23]

I. Müller , Thermodynamics, Interaction of Mechanics and Mathematics Series, Pitman Advanced Publishing Program, Boston, 1985

[24]

Guidelli Pure Appl. Chem. (2014) 10.1515/pac-2014-5026

[25]

Dreyer Electrochem. Commun. (2014) 10.1016/j.elecom.2014.03.015

[26]

Landstorfer Electrochim. Acta (2016) 10.1016/j.electacta.2016.03.013

[27]

Dreyer Phys. Chem. Chem. Phys. (2013) 10.1039/c3cp44390f

[28]

Padhi J. Electrochem. Soc. (1997) 10.1149/1.1837571

[29]

Han Electrochim. Acta (2004) 10.1016/j.electacta.2004.05.024

[30]

Dreyer Nat. Mater. (2010) 10.1038/nmat2730

[31]

Moskon J. Power Sources (2007) 10.1016/j.jpowsour.2007.06.239

[32]

Weichert J. Am. Chem. Soc. (2012) 10.1021/ja207124a

[33]

Li Adv. Mater. (2015) 10.1002/adma.201502276

[34]

Zeng SIAM J. Appl. Math. (2014) 10.1137/130937548

[35]

Bai Nano Lett. (2011) 10.1021/nl202764f

[36]

Dreyer Continuum Mech. Thermodyn. (2011) 10.1007/s00161-010-0178-1

[37]

Morzilli Electrochim. Acta (1987) 10.1016/0013-4686(87)87090-1

[38]

CRC Handbook of Chemistry and Physics, ed. D. R. Lide, CRC PRESS, 86th edn, 2005

[39]

Bockris Trans. Faraday Soc. (1959) 10.1039/tf9595501586

[40]

Bayly SIAM J. Appl. Math. (2005) 10.1137/040609938

[41]

Savéant J. Electroanal. Chem. Interfacial Electrochem. (1975) 10.1016/0368-1874(75)85105-7

[42]

Feldberg Anal. Chem. (2010) 10.1021/ac1004162

[43]

Fletcher Phys. Chem. Chem. Phys. (2011) 10.1039/c0cp02471f

[44]

Laborda Chem. Phys. Lett. (2011) 10.1016/j.cplett.2011.07.008

[45]

Henstridge Chem. Phys. Lett. (2011) 10.1016/j.cplett.2011.10.004

[46]

Henstridge Electrochim. Acta (2012) 10.1016/j.electacta.2011.10.026

[47]

Frumkin Z. Phys. Chem. A (1933) 10.1515/zpch-1933-16411

[48]

W. Schmickler and E.Santos, Interfacial electrochemistry, Springer Science & Business Media, 2010 10.1007/978-3-642-04937-8

[49]

Itskovich Phys. Status Solidi A (1977) 10.1002/pssa.2210390126

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Details

Published: Jan 01, 2016
Vol/Issue: 18(36)
Pages: 24966-24983

Authors

W

Wolfgang Dreyer

Weierstrass-Institute; 10117 Berlin; Germany

C

Clemens Guhlke

Weierstrass-Institute; 10117 Berlin; Germany

R

Rüdiger Müller

Weierstrass-Institute; 10117 Berlin; Germany

Cite This Article

Wolfgang Dreyer, Clemens Guhlke, Rüdiger Müller (2016). A new perspective on the electron transfer: recovering the Butler–Volmer equation in non-equilibrium thermodynamics. Physical Chemistry Chemical Physics, 18(36), 24966-24983. https://doi.org/10.1039/c6cp04142f

A new perspective on the electron transfer: recovering the Butler–Volmer equation in non-equilibrium thermodynamics

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