Direct quantitative identification of the “surface trans-effect”

Peter S. Deimel; Reda M. Bababrik; Bin Wang; Phil J. Blowey; Luke A. Rochford; Pardeep K. Thakur; Marie-Laure Bocquet; Johannes V. Barth; D. Phil Woodruff; David A. Duncan; Francesco Allegretti

doi:10.1039/c6sc01677d

journal article Jan 01, 2016

Direct quantitative identification of the “surface trans-effect”

Peter S. Deimel Reda M. Bababrik Bin Wang

Phil J. Blowey Luke A. Rochford Pardeep K. Thakur

Marie-Laure Bocquet

Johannes V. Barth

D. Phil Woodruff David A. Duncan

Francesco Allegretti

Chemical Science Vol. 7 No. 9 pp. 5647-5656 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/c6sc01677d

Abstract

Quantification of the surfacetrans-effect: delocalised surface, rather than atomic, electrons acting as if a ligand in a traditionaltrans-effect.

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Details

Published: Jan 01, 2016
Vol/Issue: 7(9)
Pages: 5647-5656

Authors

P

Peter S. Deimel

Physics Department E20; Technical University of Munich; 85748 Garching; Germany

R

Reda M. Bababrik

Center for Interfacial Reaction Engineering; School of Chemical, Biological and Materials Engineering; The University of Oklahoma; Norman; USA

B

Bin Wang

Center for Interfacial Reaction Engineering; School of Chemical, Biological and Materials Engineering; The University of Oklahoma; Norman; USA

P

Phil J. Blowey

Diamond Light Source; Harwell Science and Innovation Campus; Didcot; UK; Department of Physics

L

Luke A. Rochford

Department of Chemistry; University of Warwick; Coventry; UK

P

Pardeep K. Thakur

Diamond Light Source; Harwell Science and Innovation Campus; Didcot; UK

M

Marie-Laure Bocquet

ENS – Department of Chemistry; PSL Research University; CNRS UMR 8640 PASTEUR; 75005 Paris; France

J

Johannes V. Barth

Physics Department E20; Technical University of Munich; 85748 Garching; Germany

D

D. Phil Woodruff

Department of Physics; University of Warwick; Coventry; UK

D

David A. Duncan

Physics Department E20; Technical University of Munich; 85748 Garching; Germany; Diamond Light Source

F

Francesco Allegretti

Physics Department E20; Technical University of Munich; 85748 Garching; Germany

Funding

European Research Council Award: MolArt – 247299

Engineering and Physical Sciences Research Council Award: EP/H021388/1

Alexander von Humboldt Foundation

U.S. Department of Energy Award: DESC0004600

Munich-Centre for Advanced Photonics

Cite This Article

Peter S. Deimel, Reda M. Bababrik, Bin Wang, et al. (2016). Direct quantitative identification of the “surface trans-effect”. Chemical Science, 7(9), 5647-5656. https://doi.org/10.1039/c6sc01677d

Direct quantitative identification of the “surface trans-effect”

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