Palladium-catalyzed dehydrogenative coupling of cyclic enones with thiophenes: a rapid access to β-heteroarylated cyclic enones

Zhen-Kang Wen; Ting-Ting Song; Yu-Fang Liu; Jian-Bin Chao

doi:10.1039/c8cc01059e

journal article Jan 01, 2018

Palladium-catalyzed dehydrogenative coupling of cyclic enones with thiophenes: a rapid access to β-heteroarylated cyclic enones

Zhen-Kang Wen

Ting-Ting Song Yu-Fang Liu Jian-Bin Chao

Chemical Communications Vol. 54 No. 29 pp. 3668-3671 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/c8cc01059e

Abstract

A dehydrogenative coupling reaction of cyclic enones with thiophenes through palladium-catalyzed C–H functionalization is reported herein. Further molecular transformations of the coupling products to synthetically useful meta-heteroarylated phenols are also demonstrated.

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Details

Published: Jan 01, 2018
Vol/Issue: 54(29)
Pages: 3668-3671
License: View

Authors

Z

Zhen-Kang Wen

School of Chemistry and Chemical Engineering; Shanxi University; Taiyuan 030006; China

T

Ting-Ting Song

School of Chemistry and Chemical Engineering; Shanxi University; Taiyuan 030006; China

Y

Yu-Fang Liu

School of Chemistry and Chemical Engineering; Shanxi University; Taiyuan 030006; China

J

Jian-Bin Chao

Scientific Instrument Center; Shanxi University; Taiyuan 030006; China

Funding

National Natural Science Foundation of China Award: 21502106

Natural Science Foundation of Shanxi Province Award: 201701D221028

Cite This Article

Zhen-Kang Wen, Ting-Ting Song, Yu-Fang Liu, et al. (2018). Palladium-catalyzed dehydrogenative coupling of cyclic enones with thiophenes: a rapid access to β-heteroarylated cyclic enones. Chemical Communications, 54(29), 3668-3671. https://doi.org/10.1039/c8cc01059e

Palladium-catalyzed dehydrogenative coupling of cyclic enones with thiophenes: a rapid access to β-heteroarylated cyclic enones

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