Enzyme-catalysed enantioselective oxidation of alcohols by air exploiting fast electrochemical nicotinamide cycling in electrode nanopores

Lei Wan; Rachel S. Heath; Bhavin Siritanaratkul; Clare F. Megarity; Adam J. Sills; Matthew P. Thompson; Nicholas J. Turner; F. A. Armstrong

doi:10.1039/c9gc01534e

journal article Open Access Jan 01, 2019

Enzyme-catalysed enantioselective oxidation of alcohols by air exploiting fast electrochemical nicotinamide cycling in electrode nanopores

Lei Wan

Rachel S. Heath Bhavin Siritanaratkul

Clare F. Megarity

Adam J. Sills Matthew P. Thompson Nicholas J. Turner

F. A. Armstrong

Green Chem. Vol. 21 No. 18 pp. 4958-4963 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/c9gc01534e

Abstract

Enantioselective conversion of alcohols to ketones using air as the oxidant is achieved with high rates and efficiency using an indium tin oxide electrode in which an alcohol dehydrogenase and a NADPH recycling enzyme are confined within nanopores.

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References

Details

Published: Jan 01, 2019
Vol/Issue: 21(18)
Pages: 4958-4963
License: View

Authors

L

Lei Wan

Department of Chemistry; University of Oxford; Oxford; UK

R

Rachel S. Heath

School of Chemistry; University of Manchester; Manchester Institute of Biotechnology; Manchester M1 7DN; UK

B

Bhavin Siritanaratkul

Department of Chemistry; University of Oxford; Oxford; UK

C

Clare F. Megarity

Department of Chemistry; University of Oxford; Oxford; UK

A

Adam J. Sills

Department of Chemistry; University of Oxford; Oxford; UK

M

Matthew P. Thompson

School of Chemistry; University of Manchester; Manchester Institute of Biotechnology; Manchester M1 7DN; UK

N

Nicholas J. Turner

School of Chemistry; University of Manchester; Manchester Institute of Biotechnology; Manchester M1 7DN; UK

F

F. A. Armstrong

Department of Chemistry; University of Oxford; Oxford; UK

Funding

Biotechnology and Biological Sciences Research Council Award: BB/P023797/1

European Research Council Award: 742987

China Scholarship Council

SCG Chemicals

Cite This Article

Lei Wan, Rachel S. Heath, Bhavin Siritanaratkul, et al. (2019). Enzyme-catalysed enantioselective oxidation of alcohols by air exploiting fast electrochemical nicotinamide cycling in electrode nanopores. Green Chem., 21(18), 4958-4963. https://doi.org/10.1039/c9gc01534e

Enzyme-catalysed enantioselective oxidation of alcohols by air exploiting fast electrochemical nicotinamide cycling in electrode nanopores

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