Iridium-catalysed 3,5-bis-borylation of phthalonitrile enables access to a family of C4h octaarylphthalocyanines

Katie D. Mulholland; Sangbin Yoon; Christopher C. Rennie; Eleanor K. Sitch; Alasdair I. McKay; Katharina Edkins; Robert M. Edkins

doi:10.1039/d0cc03161e

journal article Open Access Jan 01, 2020

Iridium-catalysed 3,5-bis-borylation of phthalonitrile enables access to a family of C4h octaarylphthalocyanines

Katie D. Mulholland Sangbin Yoon

Christopher C. Rennie

Eleanor K. Sitch Alasdair I. McKay

Katharina Edkins

Robert M. Edkins

Chemical Communications Vol. 56 No. 60 pp. 8452-8455 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/d0cc03161e

Abstract

3,5-Bis(Bpin)phthalonitrile is a divergent intermediate of regioregular C4h 1,3,8,10,15,17,22,24-octaarylphthalocyanines that can be synthesised by Ir-catalysed C–H bis-borylation of phthalonitrile.

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Details

Published: Jan 01, 2020
Vol/Issue: 56(60)
Pages: 8452-8455
License: View

Authors

K

Katie D. Mulholland

Chemistry Research Laboratory; University of Oxford; Oxford OX1 3TA; UK

S

Sangbin Yoon

Chemistry Research Laboratory; University of Oxford; Oxford OX1 3TA; UK

C

Christopher C. Rennie

WestCHEM Department of Pure and Applied Chemistry; University of Strathclyde; Glasgow G1 1XL; UK

E

Eleanor K. Sitch

Chemistry Research Laboratory; University of Oxford; Oxford OX1 3TA; UK

A

Alasdair I. McKay

School of Chemistry; Monash University; Clayton; Australia

K

Katharina Edkins

Division of Pharmacy and Optometry; University of Manchester; Manchester M13 9PT; UK

R

Robert M. Edkins

WestCHEM Department of Pure and Applied Chemistry; University of Strathclyde; Glasgow G1 1XL; UK

Funding

John Fell Fund, University of Oxford

Royal Commission for the Exhibition of 1851

Cite This Article

Katie D. Mulholland, Sangbin Yoon, Christopher C. Rennie, et al. (2020). Iridium-catalysed 3,5-bis-borylation of phthalonitrile enables access to a family of C4h octaarylphthalocyanines. Chemical Communications, 56(60), 8452-8455. https://doi.org/10.1039/d0cc03161e

Iridium-catalysed 3,5-bis-borylation of phthalonitrile enables access to a family of C4h octaarylphthalocyanines

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