Polyoxometalates in solution: speciation under spotlight

Nadiia I. Gumerova; Annette Rompel

doi:10.1039/d0cs00392a

journal article Open Access Jan 01, 2020

Polyoxometalates in solution: speciation under spotlight

Nadiia I. Gumerova

Annette Rompel

Chemical Society Reviews Vol. 49 No. 21 pp. 7568-7601 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/d0cs00392a

Abstract

The review covers stability and transformations of classical polyoxometalates in aqueous solutions and provides their ion-distribution diagrams over a wide pH range.

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References

265

[1]

M. T. Pope , Heteropoly and Isopoly Oxometalates , Springer-Verlag , New York , 1983 10.1007/978-3-662-12004-0

[2]

Pope Angew. Chem., Int. Ed. Engl. (1991) 10.1002/anie.199100341

[3]

Long Chem. Soc. Rev. (2007) 10.1039/b502666k

[4]

Knöpnadel Angew. Chem., Int. Ed. Engl. (1974) 10.1002/anie.197408231

[5]

Kreusler Z. Naturforsch., B: J. Chem. Sci. (1980) 10.1515/znb-1980-0223

[6]

Cruywagen Inorg. Chim. Acta (2002) 10.1016/s0020-1693(02)00700-4

[7]

Recent Advances in Polyoxometalate-Catalyzed Reactions

Shilong Wang, Guo-Yu Yang

Chemical Reviews 2015 10.1021/cr500390v

[8]

Bijelic Acc. Chem. Res. (2017) 10.1021/acs.accounts.7b00109

[9]

Bijelic ChemTexts (2018) 10.1007/s40828-018-0064-1

[10]

Bijelic Chem. Commun. (2018) 10.1039/c7cc07549a

[11]

A. Bijelic , M.Aureliano and A.Rompel , Angew. Chem., Int. Ed. 2019 , 58 , 2980–2999 ( Angew. Chem. , 2019 , 131 , 3008–3029), 10.1002/anie.201803868 , ( 10.1002/ange.201803868 ) 10.1002/anie.201803868

[12]

Kiss Bull. Chem. Soc. Jpn. (2007) 10.1246/bcsj.80.1691

[13]

Crans Coord. Chem. Rev. (2017) 10.1016/j.ccr.2017.11.008

[14]

Templeton Pure Appl. Chem. (2000) 10.1351/pac200072081453

[15]

Kiss Coord. Chem. Rev. (2017) 10.1016/j.ccr.2016.12.016

[16]

I. Ali and H. Y.Aboul-Enein , Instrumental methods in metal ion speciation , Taylor & Francis , Boca Raton , 2006 10.1201/9781420019407 10.1201/9781420019407

[17]

Gumerova J. Solution Chem. (2016) 10.1007/s10953-016-0471-0

[18]

Maksimovskaya Inorg. Chem. (2007) 10.1021/ic061549n

[19]

Fan RSC Adv. (2015) 10.1039/c5ra18059g

[20]

Crans Inorg. Chem. (2013) 10.1021/ic4007873

[21]

Yamase Chem. Rev. (1998) 10.1021/cr9604043

[22]

So Inorg. Chem. (1972) 10.1021/ic50112a061

[23]

Varga Jr Inorg. Chem. (1970) 10.1021/ic50085a045

[24]

Yang Inorg. Chem. (2016) 10.1021/acs.inorgchem.5b02189

[25]

Holclajtner-Antunović Can. J. Chem. (2008) 10.1139/v08-138

[26]

Häufe Fresenius' Z. Anal. Chem. (1982) 10.1007/bf00483010

[27]

Cabrera J. Solid State Chem. (2012) 10.1016/j.jssc.2011.12.005

[28]

A. F. Redkin and G. V.Bondarenko , J. Solution Chem. , 2010 , 39 , 15491561 , 10.1007/s10953-010-9595-9 10.1007/s10953-010-9595-9

[29]

Aureliano Dalton Trans. (2016) 10.1039/c5dt04176g

[30]

W. G. Klemperer and W.Shum , J. Am. Chem. Soc. , 1976 , 98 , 82918293 , 10.1021/ja00441a083 10.1021/ja00441a083

[31]

Fedotov J. Struct. Chem. (2006) 10.1007/s10947-006-0413-6

[32]

Chen Coord. Chem. Rev. (2004) 10.1016/j.cct.2003.11.003

[33]

A. S. Tracey , G. R.Willsky and E. S.Takeuchi , Vanadium: Chemistry, Biochemistry, Pharmacology and Practical Applications , CRC Press , 2007 , p. 200 10.1201/9781420046144

[34]

Crans Adv. Chem. (1996) 10.1021/ba-1995-0246.ch011

[35]

Pope J. Chem. Soc., Chem. Commun. (1966) 10.1039/c19660000653

[36]

Filowitz Inorg. Chem. (1979) 10.1021/ic50191a021

[37]

Ohlin Annu. Rep. NMR Spectrosc. (2018) 10.1016/bs.arnmr.2018.01.001

[38]

Maksimovskaya Coord. Chem. Rev. (2019) 10.1016/j.ccr.2019.01.014

[39]

Maksimovskaya Inorg. Chem. (2011) 10.1021/ic101996f

[40]

Bugnola Eur. J. Inorg. Chem. (2019) 10.1002/ejic.201800552

[41]

Cowan Inorg. Chem. (2001) 10.1021/ic0106120

[42]

Klonowski Inorg. Chem. (2014) 10.1021/ic502617k

[43]

Misra Angew. Chem., Int. Ed. (2020) 10.1002/anie.201905600

[44]

Xie Inorg. Chem. (2018) 10.1021/acs.inorgchem.8b00474

[45]

Nyman Angew. Chem., Int. Ed. (2004) 10.1002/anie.200353410

[46]

Sures Phys. Chem. Chem. Phys. (2017) 10.1039/c6cp08454k

[47]

Miras Chem. Commun. (2009) 10.1039/b819534j

[48]

Truebenbach J. Mass Spectrom. (2000) 10.1002/1096-9888(200009)35:9<1121::aid-jms40>3.0.co;2-7

[49]

Ohlin Chem. – Asian J. (2012) 10.1002/asia.201100763

[50]

Nyman Coord. Chem. Rev. (2017) 10.1016/j.ccr.2016.11.014

Showing 50 of 265 references

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Citations

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References

Details

Published: Jan 01, 2020
Vol/Issue: 49(21)
Pages: 7568-7601
License: View

Authors

N

Nadiia I. Gumerova

Universität Wien; Fakultät für Chemie; Institut für Biophysikalische Chemie; 1090 Vienna; Austria

A

Annette Rompel

Universität Wien; Fakultät für Chemie; Institut für Biophysikalische Chemie; 1090 Vienna; Austria

Funding

Austrian Science Fund Award: M2203

Cite This Article

Nadiia I. Gumerova, Annette Rompel (2020). Polyoxometalates in solution: speciation under spotlight. Chemical Society Reviews, 49(21), 7568-7601. https://doi.org/10.1039/d0cs00392a

Polyoxometalates in solution: speciation under spotlight

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