Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals

Sophia L. Shevick; Conner V. Wilson; Simona Kotesova; Dongyoung Kim; Patrick L. Holland; Ryan A. Shenvi

doi:10.1039/d0sc04112b

journal article Open Access Jan 01, 2020

Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals

Sophia L. Shevick

Conner V. Wilson Simona Kotesova Dongyoung Kim

Patrick L. Holland

Ryan A. Shenvi

Chemical Science Vol. 11 No. 46 pp. 12401-12422 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/d0sc04112b

Abstract

Hydrogen atom transfer from metal hydrides to alkenes appears to underlie widely used catalytic methods – the mechanistic implications are fascinating.

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Metrics

309

Citations

143

References

Details

Published: Jan 01, 2020
Vol/Issue: 11(46)
Pages: 12401-12422
License: View

Authors

S

Sophia L. Shevick

Department of Chemistry; Scripps Research; La Jolla; USA

C

Conner V. Wilson

Department of Chemistry; Yale University; New Haven; USA

S

Simona Kotesova

Department of Chemistry; Scripps Research; La Jolla; USA

D

Dongyoung Kim

Department of Chemistry; Yale University; New Haven; USA

P

Patrick L. Holland

Department of Chemistry; Yale University; New Haven; USA

R

Ryan A. Shenvi

Department of Chemistry; Scripps Research; La Jolla; USA

Funding

National Institute of General Medical Sciences Award: GM122606

Division of Chemistry Award: CHE 1955922

National Center for Advancing Translational Sciences Award: TL1 TR002551

Cite This Article

Sophia L. Shevick, Conner V. Wilson, Simona Kotesova, et al. (2020). Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals. Chemical Science, 11(46), 12401-12422. https://doi.org/10.1039/d0sc04112b

Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals

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