On the location of Lewis acidic aluminum in zeolite mordenite and the role of framework-associated aluminum in mediating the switch between Brønsted and Lewis acidity

Manoj Ravi; Vitaly L. Sushkevich; Jeroen A. van Bokhoven

doi:10.1039/d0sc06130a

journal article Open Access Jan 01, 2021

On the location of Lewis acidic aluminum in zeolite mordenite and the role of framework-associated aluminum in mediating the switch between Brønsted and Lewis acidity

Manoj Ravi

Vitaly L. Sushkevich

Jeroen A. van Bokhoven

Chemical Science Vol. 12 No. 11 pp. 4094-4103 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/d0sc06130a

Abstract

Framework-associated aluminum is demonstrated to facilitate a reversible switch between Lewis and Brønsted acidity in zeolites with the Lewis acid sites preferentially populating the side-pockets in the case of mordenite.

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References

Details

Published: Jan 01, 2021
Vol/Issue: 12(11)
Pages: 4094-4103
License: View

Authors

M

Manoj Ravi

Institute for Chemical and Bioengineering; Department of Chemistry and Applied Biosciences; ETH Zurich; 8093 Zurich; Switzerland

V

Vitaly L. Sushkevich

Laboratory for Catalysis and Sustainable Chemistry; Paul Scherrer Institute; Switzerland

J

Jeroen A. van Bokhoven

Institute for Chemical and Bioengineering; Department of Chemistry and Applied Biosciences; ETH Zurich; 8093 Zurich; Switzerland

Funding

Eidgenössische Technische Hochschule Zürich

Cite This Article

Manoj Ravi, Vitaly L. Sushkevich, Jeroen A. van Bokhoven (2021). On the location of Lewis acidic aluminum in zeolite mordenite and the role of framework-associated aluminum in mediating the switch between Brønsted and Lewis acidity. Chemical Science, 12(11), 4094-4103. https://doi.org/10.1039/d0sc06130a

On the location of Lewis acidic aluminum in zeolite mordenite and the role of framework-associated aluminum in mediating the switch between Brønsted and Lewis acidity

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