Rational design of ZSM-5 zeolite containing a high concentration of single Fe sites capable of catalyzing the partial oxidation of methane with high turnover frequency

Akira Oda; Koshiro Aono; Naoya Murata; Kazumasa Murata; Masazumi Yasumoto; Nao Tsunoji; Kyoichi Sawabe; Atsushi Satsuma

doi:10.1039/d1cy01987b

journal article Jan 01, 2022

Rational design of ZSM-5 zeolite containing a high concentration of single Fe sites capable of catalyzing the partial oxidation of methane with high turnover frequency

Akira Oda

Koshiro Aono Naoya Murata Kazumasa Murata

Masazumi Yasumoto Nao Tsunoji

Kyoichi Sawabe Atsushi Satsuma

Catalysis Science & Technology Vol. 12 No. 2 pp. 542-550 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/d1cy01987b

Abstract

We successfully synthesized a Fe/ZSM-5 catalyst enabling conversion of methane to C1 oxygenates in record yields, and demonstrated that the fraction of the single Fe cation, as well as the Al distribution, are the powerful activity descriptors.

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Details

Published: Jan 01, 2022
Vol/Issue: 12(2)
Pages: 542-550
License: View

Authors

A

Akira Oda

Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan; Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Kyoto 615-8520, Japan

K

Koshiro Aono

Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan

N

Naoya Murata

Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan

K

Kazumasa Murata

Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan

M

Masazumi Yasumoto

Graduate School of Advanced Science and Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan

N

Nao Tsunoji

Graduate School of Advanced Science and Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan

K

Kyoichi Sawabe

Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan; Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Kyoto 615-8520, Japan

A

Atsushi Satsuma

Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan; Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Kyoto 615-8520, Japan

Funding

Japan Society for the Promotion of Science Award: 20K15297

Cite This Article

Akira Oda, Koshiro Aono, Naoya Murata, et al. (2022). Rational design of ZSM-5 zeolite containing a high concentration of single Fe sites capable of catalyzing the partial oxidation of methane with high turnover frequency. Catalysis Science & Technology, 12(2), 542-550. https://doi.org/10.1039/d1cy01987b

Rational design of ZSM-5 zeolite containing a high concentration of single Fe sites capable of catalyzing the partial oxidation of methane with high turnover frequency

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