First observation of [Pu6(OH)4O4]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect

Manon Cot-Auriol; Matthieu Virot; Thomas Dumas; Olivier Diat; Denis Menut; Philippe Moisy; Sergey I. Nikitenko

doi:10.1039/d2cc04990b

journal article Open Access Jan 01, 2022

First observation of [Pu6(OH)4O4]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect

Manon Cot-Auriol Matthieu Virot

Chemical Communications Vol. 58 No. 94 pp. 13147-13150 · Royal Society of Chemistry (RSC)

View at Publisher Save 10.1039/d2cc04990b

Abstract

New insights are provided about the formation mechanism of PuO2 nanoparticles (NPs) by investigating an unprecedented kinetic isotope effect observed during their hydrolytic synthesis in H2O or D2O media.

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Details

Published: Jan 01, 2022
Vol/Issue: 58(94)
Pages: 13147-13150
License: View

Authors

M

Manon Cot-Auriol

ICSM, Univ Montpellier, CEA, CNRS, ENSCM, Marcoule, France

M

Matthieu Virot

ICSM, Univ Montpellier, CEA, CNRS, ENSCM, Marcoule, France

T

Thomas Dumas

CEA, DES, ISEC, DMRC, Univ Montpellier, Marcoule, France

O

Olivier Diat

ICSM, Univ Montpellier, CEA, CNRS, ENSCM, Marcoule, France

D

Denis Menut

Synchrotron SOLEIL, L’Orme des Merisiers, Départementale 128, 91190 Saint Aubin, France

P

Philippe Moisy

CEA, DES, ISEC, DMRC, Univ Montpellier, Marcoule, France

S

Sergey I. Nikitenko

ICSM, Univ Montpellier, CEA, CNRS, ENSCM, Marcoule, France

Cite This Article

Manon Cot-Auriol, Matthieu Virot, Thomas Dumas, et al. (2022). First observation of [Pu6(OH)4O4]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect. Chemical Communications, 58(94), 13147-13150. https://doi.org/10.1039/d2cc04990b

First observation of [Pu6(OH)4O4]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect

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